Zn alloy particles for high corrosion resistance rust protection paint, method of production of particles, high corrosion resitance rust protection paint conatining particles, high corrosion resistance steel material coated with paint, and steel structure having steel material

ABSTRACT

Zn alloy particles for high corrosion resistance rust prevention paint containing, by mass %, Mg: 0.01 to 30% and having a balance of Zn and unavoidable impurities, having physical fracture facets and/or cracks of a length of 0.01 μm or more or cracks of a depth of 0.01 μm or more, having an average particle size of 0.05 to 200 μm, and having an aspect ratio of maximum size and minimum size (maximum size/minimum size) of an average value of 1 to 1.5. Also, a high corrosion resistance rust prevention paint containing these Zn alloy particles and a high corrosion resistance steel material and steel structure coated with that paint.

TECHNICAL FIELD

The present invention relates to Zn alloy particles for high corrosion resistance rust protection paint having physical fracture facets and/or cracks and imparting remarkably superior high corrosion resistance and rust protection, a method of production of said Zn alloy particles, a high corrosion resistance rust protection paint containing said Zn alloy particles, a high corrosion resistance steel material coated with said paint, and a steel structure having said steel material.

BACKGROUND ART

As a countermeasure to corrosion of ferrous metal materials, much use has been made of zinc-rich paints made using a zinc powder containing unavoidable impurities as a pigment and organic materials and/or inorganic materials as a vehicle (liquid binder ingredient).

Zinc-rich paints are mainly used as primers for heavy duty corrosion protection paint. The corrosion protection mechanism features the sacrificial corrosion protection of the zinc powder contained in a coat.

Further, the corrosion protection of a coat of a zinc-rich paint is strongly dependent on the extent of the sacrificial corrosion protection of the zinc powder, so depending on the usage environment, the rate of consumption of the zinc sometimes becomes larger and the corrosion protection on the ferrous metal material will not last long.

Therefore, in the past, the practice has been to increase the content of the zinc powder in the coat or increase the coat thickness, but as a result a drop in the adhesion with the surface of the steel material, cracking or sagging of the coat, etc. easily occur.

In the end, it is difficult to realize both the corrosion protection performance of the coat and the physical properties or coating ability. Measures increasing the content of the zinc powder in the coat are not perfect.

In view of this situation, development of a high performance zinc-rich paint able to maintain the advantages of conventional zinc-rich paints and furthermore exhibit a sacrificial corrosion protection over a long period of time has been hoped for. Up until now, various proposals have been made.

For example, Japanese Patent Publication (A) No. 59-52645 and Japanese Patent Publication (A) No. 59-167249 propose an organic-based zinc-rich paint containing not only a zinc powder, but also a Zn—Mg alloy powder, while Japanese Patent Publication (A) No. 59-198142 proposes an organic-based zinc-rich paint containing not only a zinc powder, but also a Zn—Mg alloy powder and Mn powder.

Furthermore, Japanese Patent Publication (A) No. 1-311178 discloses the long lasting corrosion protection performance of a Zn-(5 to 15%)Mg alloy powder in an organic paint, while Japanese Patent Publication (A) No. 2-73932 discloses the long lasting corrosion protection performance of an organic coat containing an Zn—Mg alloy powder with a metal structure comprised of Zn and MgZn₂.

Further, Japanese Patent Publication (A) No. 11-343422 proposes a rust protection pigment for an organic-based corrosion resistant paint containing flake-shaped particles of Zn alloy containing Al, Mg, etc.

In addition to the above, Japanese Patent Publication (A) No. 2001-164194 proposes an organic-based zinc-rich paint obtained by crushing an ingot of Zn—Al—Mg-based alloy powder where over 50% of the alloy powder is an Al/Zn/Zn₂Mg eutectic structure, while Japanese Patent Publication (A) No. 2005-314501 proposes an organic-based paint for improving the corrosion resistance of cut parts of a high corrosion resistance galvannealed steel material containing a powder of a Zn—Al alloy containing Mg or Si, having a spherical or oval shape, and having a value of the ratio of maximum size and minimum size (maximum size/minimum size) of 1 to 1.5.

The above proposals try to improve the corrosion protection performance of an organic-based paint and the corrosion resistance by the combination of a new alloy powder.

However, a general organic-based paint has the secondary problems of deteriorating in a composite environment of UV rays, moisture, oxygen, etc. and requiring maintenance in relatively short cycles.

In such a situation, several proposals have been made up to now for the purpose of improving the corrosion protection performance of inorganic-based paints not having such defects of organic-based paints.

For example, while different in object from the present invention, Japanese Patent Publication (A) No. 61-213270 proposes a paint composition containing a mixture of a zinc powder and Mg or Mg alloy for the purpose of inhibiting paint deterioration at the time of welding and cutting.

On the other hand, Japanese Patent Publication (A) No. 2000-80309 proposes a corrosion resistant paint having three types of phases, a Zn phase, Zn—Mg alloy phase, and Zn and Mg solid solution phase, as main ingredients and having these mixed in inorganic-based paint as powder particles and a corrosion resistant ferrous metal material coated with this paint.

The proposal of Japanese Patent Publication (A) No. 2000-80309 is noteworthy as being a fundamental means for improving corrosion resistance, but according to studies of the inventors, there are actually both cases where the corrosion resistance is improved and cases where the improvement in the corrosion resistance is not clear. There are questions as to the stability of the effect of improvement of the corrosion resistance.

Further, Japanese Patent Publication (A) No. 2002-285102 and Japanese Patent Publication (A) No. 2005-336431 propose an inorganic-based corrosion resistant paint containing flake-shaped particles of a Zn alloy containing Mg etc. and a corrosion resistant ferrous metal material coated with that paint.

However, including the proposal of Japanese Patent Publication (A) No. 11-343422, in the above proposals, the particles have flake shapes, so the new problem is caused that spray coating is difficult.

DISCLOSURE OF THE INVENTION

The present invention has as its object the provision of Zn alloy particles for high corrosion resistance rust protection paint having coatability and economy able to impart unprecedented, long lasting superior corrosion resistance and rust prevention to a ferrous metal material etc., a method of production of said Zn alloy particles, a high corrosion resistance rust prevention paint containing said Zn alloy particles, and a high corrosion resistance ferrous metal material and steel structure coated with that paint and as a result greatly extended in maintenance cycles.

The inventors engages in various studies and as a result newly discovered that non-flake-shaped particles comprised of Mg in 0.01 mass % to 30 mass % and a balance of Zn containing unavoidable impurities and having physical fracture facets and/or cracks exhibit remarkably superior corrosion resistance, rust protection, and coatability. This discovery is a discovery forming the basis of the present invention.

Furthermore, the inventors studied in detail the possibility of further improvement of the corrosion resistance and rust protection of said particles having physical fracture facets and/or cracks and as a result discovered that if the Zn alloy particles having physical fracture facets and/or cracks contain, by mass %, one or both of Al: 0.01 to 30% and Si: 0.01 to 3%, a more superior rust protection is exhibited and, further, that by arranging one or more of MgZn₂, _(MgZn) ₁₁, Mg₂Zn₃, MgZn, and Mg₇Zn₃ at the fracture facets and/or cracks, a more superior corrosion resistance is exhibited.

The inventors also simultaneously studied the shapes of particles after fracture and as a result discovered that when the number of facets of an aspherical polyhedron after fracture is two facets or more, the self dissolution can be further reduced without impairing the rust protection performance, that is, the sacrificial corrosion protection effect.

Further, the inventors studied the size of cracks and as a result discovered that if the length is 0.01 μm or more or the depth is 0.01 μm or more, the corrosion protection is remarkably improved.

The mechanism of improvement of the corrosion resistance when the particles have surface cracks is not clear.

The fact that if there are cracks in the particle surfaces, the surface areas of the Zn alloy particles become larger and an Mg solid solution phase and intermetallic compounds easily form at the crack surfaces and, further, that the activity of the Zn alloy particles themselves is improved are believed to be part of the reasons for the improvement of the corrosion resistance, but effects beyond what is expected to be caused by these are exhibited. In the final analysis, the details are unclear.

Further, the inventors studied means for obtaining particles having fracture facets and/or cracks.

As a result, the inventors discovered that rather than obtaining fractured pieces by a ball mill, beads mill, or other means used as general fracture methods in the past, making the primary particles impact each other or making particles impact with a solid so as to obtain particles having physical fracture facets and/or cracks with more superior corrosion resistance and rust prevention and, furthermore, making the primary particles disperse in a solvent to obtain a slurry and make them impact and fracture, particles having physical fracture facets and/or cracks can be obtained with a good work efficiency without impairing the superior corrosion resistance and rust protection.

The Zn alloy particles having fracture facets and/or cracks give a superior corrosion resistance and rust protection even if used as is as a pigment for a paint, but the inventors engaged in further studies and as a result discovered that if using these mixed together with the Zn particle pigment generally used as a pigment in the past, a remarkably superior corrosion resistance and rust protection are given compared with a pigment using Zn particles alone.

Furthermore, the inventors discovered that when using Zn alloy particles having fracture facets and/or cracks to make a paint, if mixing the particles of the present invention as a pigment in an organic paint, an unprecedented superior corrosion resistance and rust protection are imparted even under a harsh composite environment of UV rays, moisture, oxygen, etc.

The present invention is based on the above discovery and has as its gist the following:

(1) Zn alloy particles for high corrosion resistance rust prevention paint containing, by mass %, Mg: 0.01 to 30% and having a balance of Zn and unavoidable impurities, having physical fracture facets and/or cracks of a length of 0.01 μm or more or cracks of a depth of 0.01 μm or more, having an average particle size of 0.05 to 200 μm, and having an aspect ratio of maximum size and minimum size (maximum size/minimum size) of an average value of 1 to 1.5.

(2) Zn alloy particles for high corrosion resistance rust prevention paint as set forth in (1), characterized in that said Zn alloy particles further contain, by mass %, one or both of Al: 0.01 to 30% and Si: 0.01 to 3%

(3) Zn alloy particles for high corrosion resistance rust prevention paint as set forth in (1) or (2), characterized by having an Mg solid solution phase and Zn—Mg intermetallic compounds on the surface of said Zn alloy particles.

(4) Zn alloy particles for high corrosion resistance rust prevention paint as set forth in (3), characterized in that said Zn—Mg intermetallic compounds include at least one type of compound of MgZn₂, Mg₂Zn₁₁, Mg₂Zn₃, MgZn, and Mg₇Zn₃.

(5) Zn alloy particles for high corrosion resistance rust prevention paint as set forth in any one of (1) to (4), characterized in that said Zn alloy particles are shaped as aspherical polyhedrons with two or more facets.

(6) A method of production of Zn alloy particles for high corrosion resistance rust prevention paint as set forth in any one of (1) to (5), said method of production of Zn alloy particles for high corrosion resistance rust prevention paint characterized by making primary particles comprised of the composition of ingredients as described in (1) or (2) and having an average particle size of 0.05 to 1000 μm impact each other or making said primary particles impact a solid to fracture said primary particles to produce Zn alloy particles having physical fracture facets and/or cracks.

(7) A method of production of Zn alloy particles for high corrosion resistance rust prevention paint as set forth in (6) characterized by making said primary particles disperse in an organic solvent to make a slurry, then making the slurry impact itself or making said slurry impact a solid to fracture the primary particles.

(8) A high corrosion resistance rust prevention paint characterized by containing Zn alloy particles for high corrosion resistance rust prevention paint as set forth in any of (1) to (5) in 30 mass % or more converted to dry coat.

(9) A high corrosion resistance rust prevention paint as set forth in (8) characterized by comprising a high corrosion resistance rust prevention paint containing, in addition to said Zn alloy particles, Zn metal particles having an average particle size of 0.05 to 50 μm comprised of Zn and unavoidable impurities and by having an x of 300.0 or less when defining, by mass %, (mass % of said Zn alloy particles):(mass % of said Zn metal particles) as 1/x.

(10) A high corrosion resistance rust prevention paint as set forth in (8) or (9) characterized by having, by mass %, a content of Mg of 0.01 to less than 30% when the total of said Zn alloy particles and said Zn metal particles is defined as 100%.

(11) A high corrosion resistance rust prevention paint as set forth in any one of (8) to (10) characterized in that a binder of said high corrosion resistance rust prevention paint is an inorganic binder or organic binder.

(12) A ferrous metal material coated with a high corrosion resistance rust prevention paint as set forth in any one of (8) to (10) on its surface, said high corrosion resistance ferrous metal material characterized in that a coating thickness is 2 to 700 μm and in that Zn alloy particles, or Zn alloy particles and Zn metal particles, are dispersed in the coat.

(13) A steel structure characterized by being provided with a high corrosion resistance ferrous metal material as set forth in (12) as part or all of the same.

If coating a high corrosion resistance rust prevention paint containing Zn alloy particles having physical fracture facets and/or cracks of the present invention, it is possible to give ferrous metal material etc. unprecedented long-lasting superior corrosion resistance and rust prevention without impairing the coatability and economy. Further, as a result, it is possible to provide a high corrosion resistance ferrous metal material and steel structure able to greatly extend the maintenance cycles.

BEST MODE FOR CARRYING OUT THE INVENTION

The high corrosion resistance Zn alloy particles of the present invention contain Mg: 0.01 to 30% and have a balance of Zn and unavoidable impurities, have physical fracture facets and/or cracks, have an average particle size of 0.05 to 200 μm, and have an aspect ratio of the maximum size and minimum size (maximum size/minimum size) of 1 to 1.5.

In the Zn alloy particles of the present invention, Mg has to be 0.01 to 30%.

When having physical fracture facets and having an average particle size of 0.05 to 200 μm, even if Mg is less than 0.01%, a significant improvement is recognized in the corrosion resistance and corrosion protection compared with Zn alloy particles not having physical fracture facets and containing the same amount of Mg, but the remarkable effect of improvement of the corrosion resistance and corrosion protection expected due to the combination with the physical fracture facets and/or cracks is not obtained.

That is, the remarkable effect of improvement of the corrosion resistance and rust prevention due to the Zn alloy particles having physical fracture facets and/or cracks and containing Mg in 0.01% or more, that is, the remarkable effect of improvement of the corrosion resistance and rust prevention due to the synergistic effect of the physical fracture facets and/or cracks and the 0.01% or more Mg, is the basic technical idea of the present invention.

If Mg is contained over 30%, not only is the effect of improvement saturated, but also the economy and production efficiency are impaired, so the Mg was made 0.01% to 30%.

Here, the optimum value of the amount of Mg changes depending on the average particle size. In general, in the case of an average particle size of 0.2 to 30 μm considered optimum in spray coating, making the lower limit 0.1% and the upper limit 20% is preferable from the viewpoint of the effect of improvement of the corrosion resistance and corrosion protection and economy.

Furthermore, if considering the production stability, economy, and corrosion resistance, the amount of Mg is preferably 0.2 to 15%.

The “physical fracture facets” referred to in the present invention mean facets of shapes formed by parts of the spherical particles being removed. By the Zn alloy particles having physical fracture facets, as explained later, the effect of improvement of the corrosion resistance and corrosion protection is remarkably obtained.

Further, the “cracks” referred to in the present invention means cracks present on the spherical particle surface having a length of 0.01 μm or more or a depth from the surface of 0.01 μm or more. When the cracks have a length or depth of less than 0.01 μm, a sufficient corrosion resistance improvement effect is not obtained. A length or depth of 0.01 μm or more is required.

The average particle size of the Zn alloy particles is made 0.05 μm or more to secure the adhesiveness required at the time of spray coating and is made 200 μm or less to secure the work stability at the time of brush coating. If considering the coating stability, 0.2 to 50 μm is preferable. Further, if considering the coat adhesion, 0.2 to 30 μm is preferable.

The aspect ratio (maximum size/minimum size) of the particles was made an average value of 1 to 1.5 to secure coatability.

When predicated on spray coating, if the aspect ratio of the particles is over 2, the particle spraying and flight stability falls and the coat thickness and particle distribution stability in the coat falls.

If there are physical fracture facets and/or cracks on the particles, their stability falls somewhat, so considering this, the aspect ratio of the particles was made an average value of 1 to 1.5.

Therefore, even if particles with an aspect ratio exceeding 1.5 are partially present, they do not pose a problem.

Furthermore, the above range of the aspect ratio defines the Zn alloy particles in the material state and does not define the shape of Zn alloy particles in the case of absorbing the moisture etc. in the air and coagulating and coalescing before actually being used mixed in the paint or Zn alloy particles in the case of coalescence of particles cured on the steel material as a coat.

Further, at the time of production or storage, small relief shapes form at the Zn alloy powder surface, but the changes in shape due to these are not out of the range of spherical or oval shapes with an average value of the aspect ratio of 1 to 1.5.

Furthermore, the particles of the above constitution of the present invention may contain one or both of Al: 0.01 to 30% and Si: 0.01 to 3%.

If adding Al to the particles having physical fracture facets and/or cracks in an amount of 0.01% or more, the rust protection is further improved.

If making the amount of Al 0.01% or more, in addition to the rust protection, the corrosion resistance against self corrosion of the particles is remarkably improved, but even if added over 30%, not only does the effect become saturated, but also it becomes difficult to form physical fracture facets and/or cracks in the metal particles, so the amount of Al was made 0.01 to 30%.

Furthermore, from the viewpoint of production stability and corrosion resistance, the amount of Al is preferably 0.5 to 20%. Furthermore, if considering economy, 1.0 to 10% is preferable.

Si similarly improves the rust prevention if added in an amount of 0.01% or more to the particles having physical fracture facets and/or cracks. However, if adding Si over 3%, the rust prevention conversely deteriorates, so the amount of Si was made 0.01 to 3%.

From the viewpoint of production stability and corrosion resistance, the amount of Si is preferably 0.5 to 3%. Furthermore, if considering economy, 1.0 to 1.5% is preferable.

In the Zn alloy particles having physical fracture facets and/or cracks of the present invention, by giving the surfaces of the particles including the fractured parts and/or cracks an Mg solid solution phase and Zn—Mg intermetallic compounds, the corrosion resistance and the rust prevention are further improved.

The reason why the exposure of the Mg solid solution phase and Zn—Mg intermetallic compounds at the particle surfaces causes an improvement in the corrosion resistance and rust prevention is not clear, but the inventors confirm experimentally that if one or both of these phases coexist at the fracture facets and/or cracks, the chemical properties of these phases change to ones more preferable for improvement of the corrosion resistance and rust prevention and the corrosion resistance and rust prevention are stably improved.

The Mg solid solution phase and Zn—Mg intermetallic compounds can be identified by analyzing the ratio of composition of Mg and Zn of the surfaces of the physical fracture facets or cracks by observation by the X-ray diffraction method or a scanning electron microscopy equipped with an energy dispersion type X-ray analyzer.

In the present invention, by including, as said intermetallic compound phase, at least one type of compound of MgZn₂, Mg₂Zn₁₁, Mg₂Zn₃, MgZn, and Mg₇Zn₃, the corrosion resistance and the rust prevention are improved more.

MgZn₂, Mg₂Zn₁₁, Mg₂Zn₃, MgZn, and Mg₇Zn₃ can be identified by analyzing the ratio of composition of Mg and Zn of the surfaces of the physical fracture facets or cracks by observation by the X-ray diffraction method or a scanning electron microscopy equipped with an energy dispersion type X-ray analyzer.

In the above way, the Zn alloy particles having physical fracture facets and/or cracks of the present invention can improve the corrosion resistance and rust prevention to an unprecedented extent by imparting at least one physical fracture facet and/or cracks and simultaneously controlling the chemical composition of the metal particles.

Further, the Zn alloy particles having physical fracture facets and/or cracks of the present invention can simultaneously give a more superior corrosion resistance, rust prevention, and coatability by making the shape of the particles having fracture facets a polyhedron close to a nonflat shape (cracks not included at the surface) having two or more facets.

From the viewpoint of the improvement of the corrosion resistance and rust prevention, the greater the number of physical fracture facets, the better, but with just one or no fracture facet, while the reason is not clear at the present point of time, the effect of improvement of the effect greatly varies.

Further, when the average aspect ratio is more than 2 and the shape is extremely flat, the work efficiency at the time of coating falls, so this is not preferred.

Therefore, the shapes of the particles are defined as being polyhedrons close to non-flat spheres (average value of aspect ratio of 1 to 1.5) having two or more facets.

This range of shapes defines the Zn alloy particles in the material state and does not define the shape of Zn alloy particles in the case of Zn alloy particles absorbing the moisture etc. in the air and coagulating and coalescing before actually being used mixed in paints or in the case of curing and coalescing on the steel material as a coat.

At the time of production or storage, small relief shapes form at the Zn alloy powder surface, but the changes in shape due to these are not out of the range of spherical or oval shapes with an average value of the aspect ratio of 1 to 1.5.

Next, the method of production of the Zn alloy particles of the present invention will be explained.

When producing the Zn alloy particles having physical fracture facets and/or cracks of the present invention, if using the ball mill or beads mill generally used in the past to try to impact physical fracture facets and/or cracks to the particles, the Zn alloy particles greatly deform.

That is, even among the fracture facets and/or cracks, a rolling force and shearing force greatly act. It is extremely difficult to satisfy the value of the aspect ratio of the present invention and obtain Zn alloy particles having physical fracture facets and/or cracks.

When producing the Zn alloy particles having physical fracture facets and/or cracks of the present invention, first primary particles comprised of the chemical composition defined in claim 1 or 2 are produced, then the primary particles are made to impact each other or impact a solid to fracture the primary particles and form physical fracture facets and/or cracks on the primary particles of the Zn alloy particles.

When using impact to obtain physical fracture facets and/or cracks, a large individual mass enables the kinetic energy contributing to physical surface fractures and/or cracks at the time of impact to be secured, but experimentally, if the average particle size of the primary particles is over 1000 μm, the work time for obtaining the maximum average particle size of 200 μm aimed at by the present invention remarkably increases.

On the other hand, Zn alloy particles having physical fracture facets and/or cracks and having a minimum average particle size of 0.05 μm can be obtained by using primary particles having an average particle size of 0.05 μm or more and increasing the number of times of impact.

Due to the above reasons, in the present invention, the average particle size of the primary particles is made 0.05 to 1000 μm.

The average particle size of the primary particles, to improve the corrosion resistance and rust protection, is preferably 0.05 to 100 μm. Furthermore, to reliably improve the corrosion resistance and rust protection, it is preferably 0.05 to 30 μm.

Here, the “primary particles” mean Zn alloy particles before said impact or fractures. When obtaining the primary particles, the mist method, atomization method, ingot method, or any other method can be used.

Further, as the solid used for impacting said primary particles, in addition to a solid having a flat surface and/or curved surface, it is possible to use solid particles formed with a curved surface or solid particles formed with only flat surfaces.

Here, the material of the solid and solid particles has to be higher in hardness compared with the primary particles. Further, it preferably does not have reactivity when in contact under a water environment. As solids satisfying this requirement, a metal, sintered body, etc. may be mentioned.

In the production of Zn alloy particles by making primary particles impact each other or a solid and forming physical fracture facets and/or cracks on Zn alloy particles, it is possible to use a solvent as the medium for conveying the primary particles and more efficiently produce the Zn alloy particles having physical fracture facets and/or cracks targeted with a good efficiency.

The solvent is not limited in type so long as having a larger specific gravity compared with various gases including air. However, primary particles and Zn alloy particles given fracture facets and/or cracks are high in reaction activity, so the solvent has to be one with a low reaction activity with a metal having the chemical composition of the present invention.

When the solvent is particularly high in reaction activity and contains water as an impurity, the water has to be limited to 0.3 wt % or less.

In the present invention, the solvent is not limited, but toluene, xylene, or another organic solvent is suitable.

When utilizing the Zn alloy particles having fracture facets and/or cracks of the present invention, it is necessary to include 30% or more in the coat. If less than 30 mass %, the effect of the corrosion resistance etc. is not obtained.

The upper limit of the content is not particularly limited, but if over 85%, the resin ingredient becomes smaller and defects easily occur in the coat, so the upper limit is preferably 85% or less.

Note that the resin ingredient in the coat is preferably at least 15% so as to secure coating formability.

Furthermore, if the content of said Zn alloy particles is 30% or more, it is also possible to add other powder particles. For example, for the purpose of aesthetic design, it is also possible to add Al, stainless steel, or another metal powder, titanium oxide, zinc oxide, or another oxide powder, talc, stone powder, or another body pigment.

Furthermore, when utilizing Zn alloy particles having fracture facets and/or cracks of the present invention, it is possible to mix Zn metal particles having an average particle size of 0.05 to 50 μm into the Zn alloy particles in a range of x: 300.0 or less when the ratio, by mass %, of the amount of Zn alloy particles and the amount of Zn metal particles is 1/x.

The Zn metal particles referred to here mean particles comprised of Zn and unavoidable impurities.

Further, by mixing said Zn metal particles and Zn alloy particles having fracture facets and/or cracks for use for a paint pigment, it is possible to obtain remarkably superior corrosion resistance and rust prevention compared with a pigment using Zn metal particles alone like in the past.

However, when the ratio of mass % of the amount of Zn alloy particles and amount of Zn metal particles is 1/x, if x is over 300.0, the effect of the Zn alloy particles on the improvement of the corrosion resistance and rust protection is not sufficiently exhibited. Therefore, x was made 300.0 or less. If considering corrosion resistance and economy, x is preferably 1 to 120. Furthermore, if considering the mixing stability, x is preferably 1 to 30.

In the present invention, the average particle size of the Zn metal particles used for the mixing is made 0.05 to 50 μm. The effect of improvement of the corrosion resistance in the present invention is recognized in a range of average particle size of the Zn metal particles mixed of 0.05 to 300 μm, but considering industrial stability and the inexpensively available average particle sizes, the average particle size of the Zn metal particles was made 0.05 to 50 μm.

On the other hand, the effect of mixing the Zn alloy particles having physical fracture facets and/or cracks of the present invention and Zn metal particles can be analyzed by the content of Mg contained in the total rust prevention pigment.

When the total, by mass %, of the mixed particles of the Zn alloy particles having physical fracture facets and/or cracks of the present invention and Zn metal particles is 100%, the content of Mg used may be made 0.01 to less than 30%.

The content of Mg may be suitably applied in accordance with the object, but 0.1 to 20%, where the effect of mixing Zn alloy particles having fracture facets and/or cracks and Zn metal particles becomes the most remarkable, is preferable from the viewpoint of the stability of the effect of improvement of the corrosion resistance. Further, if considering economy, 0.5 to 15% is more preferable.

Note that in the present invention, the type of the resin ingredient of the paint, that is, the base resin, is not particularly limited. Either an inorganic-based or organic-based binder may be utilized.

The present invention is not particularly limited, but when inorganically based, alkali silicate, alkyl silicate, etc. may be suitably used, while when organically based, an epoxy-based resin, modified epoxy resin, acryl-based resin, urethane-based resin, polyester resin, etc. may be suitably used.

Further, regarding the type of formulation of the curing agent as well, the single-liquid curing type, the two-liquid curing type, or other types using the effects of several liquids may be suitably used in accordance with the object.

Regarding the curing method as well, ordinary temperature curing, heated curing, UV curing, electron beam curing, water curing, etc. may be suitably used in accordance with the object.

The steel material and steel structure coated with the high corrosion resistance rust prevention paint of the present invention are not particularly limited, but to coat the paint of the present invention on the surface of a steel material or steel structure to obtain corrosion resistance or corrosion protection, the coat thickness has to be 2 μm or more.

Further, the ferrous metal materials and steel structures covered by the present invention are materials and structures coated with the high corrosion resistance rust prevention paint of the present invention to a thickness of 2 μm to 700 μm and are not limited by chemical composition of the steel material, shape, or structure. Further, they include ones with surfaces on which other corrosion protection means are jointly used.

Note that if considering economy and painting work efficiency, the thickness of the high corrosion resistance rust prevention paint of the present invention is preferably 2 to 300 μm.

While not limiting the present invention to this, as the painted objects, cast iron, carbon steel, specialty steel, stainless steel, corrosion resistant steel, welded joints, etc. may be mentioned. As shapes, thick-gauge steel plate, thin-gauge steel plate, steel pipe, steel rods, etc. and shapes obtained by working these may be mentioned.

Further, as structures, structures used under (1) car, ship, and other internal engine exhaust systems, boiler exhaust systems, low temperature heat exchangers, incinerator beds, and other high temperature moist corrosive environments, (2) bridges, support columns, interior and exterior building materials, roofing materials, doors and windows, kitchen members, various types of hand rails, guard rails, various types of hooks, roof drains, railroad cars, and other atmospheric corrosive environments, (3) various types of water storage tanks, support columns, piles, sheet piles, and other soil corrosive environments, (4) can containers, various types of containers, low temperature heat exchangers, bathroom members, automobile structural members, and other condensation corrosive environments (including composite refrigerated, moist, and dry corrosive environments), (5) water storage tanks, cold water pipes, hot water pipes, can containers, various types of containers, eating utensils, cooking utensils, bathtubs, pools, sinks, and other tap water corrosive environments, (6) various types of containers, eating utensils, cooking utensils, and other drinking water corrosive environments, (7) various types of steel reinforced structures, support columns, and other concrete corrosive environments, (8) ships, bridges, piles, sheet piles, marine structures, and other seawater corrosive environments, etc. may be mentioned.

Note that in the present invention, as other corrosion protection means able to be jointly used with, there are plating, painting, galvanic corrosion prevention, etc.

EXAMPLES Example 1

Below, examples will be used to explain the present invention.

Under the conditions shown in Tables 1 to 14, painting test pieces were prepared. Primary particles of Zn alloy particles were prepared using the gas atomization method.

Furthermore, Zn alloy particles were made to impact each other or Zn alloy particles were made to impact a solid to prepare secondary particles or Zn alloy particles were added to toluene or xylene with a moisture content of 0.3% or less to make a slurry and the method of making the particles impact each other or impact a solid was used to prepare secondary particles so as to produce Zn alloy particles having physical fracture facets and/or cracks.

Zn alloy particles without physical fracture facets and/or cracks were produced by a beads mill or ball mill. The average particle size was measured by the laser diffraction scattering method. Therefore, the particle size was evaluated as the sphere equivalent diameter.

Further, the average value of the aspect ratio was measured by observation of 50 to 100 randomly extracted particles by a scan type electron microscope.

Paints were prepared by the general method. For the base resin, that is, the binder, a commercially available alkali silicate or alkyl silicate resin inorganic binder or four types of commercially available organic binders were used.

The prepared paints were applied to steel plates by brushing or spraying. As an evaluation test, a salt water spray test shown in JIS K5600 (5% NaCl sprayed at 35 degrees Celsius) was performed.

As painting test pieces, 150×70×3.2 mm test pieces were used. At the bottom of the test pieces, cross-cuts were made by a cutter.

The corrosion resistance was evaluated by the time for formation of red rust from the test piece surface. Formation at 900 hours or less was evaluated as “poor”, formation at 900 to 2000 hours as “good”, and formation at 2000 hours or more as “very good”.

From Tables 1 to 14, it is learned that the painting test pieces using the Zn alloy particles of the present invention exhibit superior corrosion resistance both with inorganic-based binders and organic-based binders.

TABLE 1 Zn-Alloy Particle Properties Coat Properties Fracture Mean Average Value Ratio of Metal Coat Result of Mg Facet &/or Size of Aspect Particle in Dry Thickness Coating Corrosion (mass %) Cracks (*1) (μm) Ratio Coat (mass %) Base Resin (μm) Method Test Inv. Example 1 12.3 F 0.02 1.05 30 alkali silicate 2 Brushing good Inv. Example 2 0.8 F 27.89 1.12 34 alkyl silicate 70 Brushing very good Inv. Example 3 1 F 0.32 1.23 42 alkali silicate 2 Spraying good Inv. Example 4 2.3 F 11.44 1.36 51 alkyl silicate 20 Spraying very good Inv. Example 5 15.6 F 1.05 1.11 33 alkali silicate 3 Brushing good Inv. Example 6 6.7 F 36.47 1.07 64 alkyl silicate 80 Brushing very good Inv. Example 7 7.5 F 5.07 1.42 74 alkali silicate 24 Brushing very good Inv. Example 8 8.4 F 7.72 1.38 82 alkyl silicate 25 Spraying very good Inv. Example 9 9.3 F 8.32 1.22 37 alkali silicate 14 Spraying very good Inv. Example 10 10.4 F 10.05 1.14 42 alkyl silicate 17 Spraying very good Inv. Example 11 11.2 F 6.08 1.13 66 alkali silicate 15 Spraying very good Inv. Example 12 11.7 F 17.89 1.02 48 alkyl silicate 40 Brushing very good Inv. Example 13 21.5 F 19.54 1.06 33 alkali silicate 30 Brushing very good Inv. Example 14 13.4 F 21.08 1.05 75 alkyl silicate 35 Brushing very good Inv. Example 15 14.6 F 23.04 1.24 77 alkali silicate 42 Brushing very good Inv. Example 16 25.8 F 9.21 1.33 68 alkyl silicate 17 Spraying very good Inv. Example 17 16.7 F 0.12 1.27 61 alkali silicate 2 Spraying good Inv. Example 18 17.3 F 29.24 1.37 59 alkyl silicate 57 Brushing very good Inv. Example 19 18.5 F 128.74 1.10 39 alkali silicate 150 Brushing very good Inv. Example 20 19.3 F 33.57 1.04 42 alkyl silicate 67 Brushing very good Inv. Example 21 3.5 F 3.04 1.02 48 alkali silicate 15 Spraying very good Inv. Example 22 22.5 F 7.54 1.01 44 alkyl silicate 20 Spraying very good Inv. Example 23 23.7 F 6.81 1.08 47 alkali silicate 15 Spraying very good Inv. Example 24 24.2 F 5.25 1.14 52 alkyl silicate 13 Spraying very good Inv. Example 25 0.2 F 194.23 1.23 55 alkali silicate 200 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 2 Zn-Alloy Particle Properties Coat Properties Fracture Average Value Ratio of Metal Coat Result of Mg Facet &/or Mean Size of Aspect Particle in Dry Thickness Coating Corrosion (mass %) Cracks (*1) (μm) Ratio Coat (mass %) Base Resin (μm) Method Test Inv. Example 26 27.1 F 28.74 1.33 69 alkyl silicate 37 Brushing very good Inv. Example 27 29.3 F 13.57 1.37 78 alkali silicate 27 Brushing very good Inv. Example 28 0.5 F 0.65 1.44 42 alkyl silicate 2 Brushing good Inv. Example 29 2.7 F 4.12 1.21 32 alkali silicate 15 Spraying very good Inv. Example 30 28.4 F 0.72 1.22 66 alkyl silicate 2 Spraying good Inv. Example 31 8.7 F 117.54 1.23 67 alkali silicate 130 Brushing very good Inv. Example 32 9.2 F 7.81 1.47 45 alkyl silicate 15 Brushing very good Inv. Example 33 17.8 F 80.25 1.01 48 alkali silicate 100 Brushing very good Inv. Example 34 20.2 F 8.47 1.04 68 alkyl silicate 17 Spraying very good Inv. Example 35 0.4 F 0.87 1.05 35 alkali silicate 2 Spraying good Inv. Example 36 13.7 F 25.78 1.12 37 alkyl silicate 36 Spraying very good Inv. Example 37 14.7 F 93.45 1.05 38 alkali silicate 100 Brushing very good Inv. Example 38 2.4 F 0.97 1.08 41 alkyl silicate 2 Brushing good Inv. Example 39 4.5 F 54.89 1.47 54 alkali silicate 60 Brushing very good Inv. Example 40 0.1 F 10.81 1.50 57 alkyl silicate 18 Brushing very good Inv. Example 41 30.0 F 18.24 1.13 59 epoxy-based resin 25 Brushing very good Inv. Example 42 24.5 F 114.78 1.04 64 acryl-based resin 120 Brushing very good Inv. Example 43 27.6 F 3.87 1.02 66 urethane-based resin 7 Spraying good Inv. Example 44 4.1 F 11.94 1.08 67 polyester resin 19 Spraying very good Inv. Example 45 3.2 F 142.58 1.15 75 epoxy-based resin 150 Brushing very good Inv. Example 46 2.7 F 12.5 1.34 74 acryl-based resin 19 Brushing very good Inv. Example 47 0.12 F 31.24 1.25 77 urethane-based resin 40 Brushing very good Inv. Example 48 0.22 F 152.46 1.19 41 polyester resin 160 Brushing very good Inv. Example 49 0.37 F 13.4 1.18 35 epoxy-based resin 22 Spraying very good Inv. Example 50 1.4 F 160.57 1.24 58 acryl-based resin 170 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 3 Zn-Alloy Particle Properties Coat Properties Fracture Average Value Ratio of Metal Coat Result of Mg Facet &/or Mean Size of Aspect Particle in Dry Thickness Coating Corrosion (mass %) Cracks (*1) (μm) Ratio Coat (mass %) Base Resin (μm) Method Test Inv. Example 51 4.2 F 14.1 1.11 78 urethane-based resin 27 Brushing very good Inv. Example 52 4.8 F 167.55 1.27 66 polyester resin 180 Brushing very good Inv. Example 53 8.1 F 1.45 1.31 37 epoxy-based resin 5 Spraying good Inv. Example 54 7.6 F 0.15 1.26 66 acryl-based resin 2 Spraying good Inv. Example 55 9.9 F 13.1 1.14 80 urethane-based resin 29 Spraying very good Inv. Example 56 14.8 F 15.5 1.34 45 polyester resin 30 Spraying very good Inv. Example 57 16.7 F 0.67 1.16 47 epoxy-based resin 2 Spraying good Inv. Example 58 17.9 F 137.89 1.47 39 acryl-based resin 150 Brushing very good Inv. Example 59 19.5 F 16.3 1.48 55 urethane-based resin 27 Brushing very good Inv. Example 60 22.4 F 110.38 1.49 74 polyester resin 130 Brushing very good Inv. Example 61 0.17 F 12.4 1.34 68 epoxy-based resin 25 Spraying very good Inv. Example 62 8.3 F 17.2 1.29 35 acryl-based resin 28 Spraying very good Inv. Example 63 6.5 F 105.23 1.18 40 urethane-based resin 130 Brushing very good Inv. Example 64 9.7 F 177.89 1.23 47 polyester resin 200 Brushing very good Inv. Example 65 11.4 F 12.2 1.27 41 epoxy-based resin 17 Spraying very good Inv. Example 66 22.5 F 1.84 1.17 38 acryl-based resin 4 Spraying very good Inv. Example 67 25.7 F 16.02 1.16 66 urethane-based resin 29 Spraying very good Inv. Example 68 17.8 F 1.75 1.49 64 polyester resin 5 Spraying very good Inv. Example 69 0.14 F 198.78 1.34 57 epoxy-based resin 200 Brushing very good Comp. Example 1 0.01 F 0.4 1.24 58 acryl-based resin 5 Spraying poor Comp. Example 2 0.8 F 3.2 2.54 64 urethane-based resin 2 Spraying poor Comp. Example 3 8.47 NO 0.67 1.25 54 polyester resin 12 Brushing poor Comp. Example 4 24.5 NO 2.5 1.05 32 epoxy-based resin 15 Brushing poor Comp. Example 5 0.01 F 0.4 1.24 57 alkali silicate 2 Spraying poor Comp. Example 6 0.8 F 0.2 1.78 70 alkyl silicate 5 Spraying poor (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 4 Zn-Alloy Particle Properties Coat Properties Fracture Average Value Ratio of Metal Coat Result of Mg Facet &/or Mean Size of Aspect Particle in Dry Thickness Coating Corrosion (mass %) Cracks (*1) (μm) Ratio Coat (mass %) Base Resin (μm) Method Test Comp. Example 7 8.47 NO 0.67 1.25 64 alkali silicate 12 Brushing poor Comp. Example 8 24.5 NO 2.5 1.05 42 alkyl silicate 15 Brushing poor Comp. Example 9 4.05 NO 0.02 1.23 38 alkali silicate 13 Brushing poor Comp. Example 10 6.78 NO 12.5 1.35 44 alkyl silicate 22 Spraying poor Comp. Example 11 15.8 NO 23.3 1.14 56 alkali silicate 34 Spraying poor Comp. Example 12 4.5 F 3.5 2.84 76 alkyl silicate 15 Brushing poor Comp. Example 13 3.2 F 6.7 1.75 65 alkyl silicate 15 Spraying poor Inv. Example 381 0.15 FC 0.02 1.05 35 alkali silicate 2 Spraying very good Inv. Example 382 0.19 FC 10.5 1.12 77 alkyl silicate 37 Spraying very good Inv. Example 383 0.18 FC 12.5 1.23 43 alkali silicate 2 Spraying good Inv. Example 384 0.11 FC 18.5 1.36 52 alkyl silicate 160 Brushing very good Inv. Example 385 0.15 FC 11.5 1.11 66 alkali silicate 5 Brushing very good Inv. Example 386 0.24 FC 9.6 1.07 72 alkyl silicate 56 Brushing very good Inv. Example 387 0.18 FC 8.5 1.42 40 alkali silicate 2 Spraying very good Inv. Example 388 0.12 FC 7.72 1.38 36 alkyl silicate 18 Spraying very good Inv. Example 389 0.19 FC 8.32 1.22 32 alkyl silicate 23 Spraying very good Inv. Example 390 0.18 FC 10.05 1.14 53 epoxy-based resin 30 Brushing very good Inv. Example 391 0.21 FC 10.6 1.13 67 acryl-based resin 77 Brushing very good Inv. Example 392 0.76 FC 5.7 1.02 72 urethane-based resin 54 Brushing very good Inv. Example 393 0.11 FC 6.4 1.06 77 polyester resin 47 Spraying very good Inv. Example 394 0.14 FC 3.2 1.05 34 epoxy-based resin 43 Spraying very good Inv. Example 395 15 FC 4.5 1.24 43 acryl-based resin 52 Brushing very good Inv. Example 396 14.5 FC 5.2 1.33 53 urethane-based resin 20 Brushing very good Inv. Example 397 18.5 FC 1.9 1.27 60 polyester resin 200 Brushing very good Inv. Example 398 15.1 FC 0.02 1.05 35 alkali silicate 22 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 5 Zn-Alloy Particle Properties Coat Properties Fracture Average Value Ratio of Metal Coat Result of Mg Facet &/or Mean Size of Aspect Particle in Dry Thickness Coating Corrosion (mass %) Cracks (*1) (μm) Ratio Coat (mass %) Base Resin (μm) Method Test Inv. Example 399 15.6 FC 10.5 1.12 77 alkyl silicate 25 Spraying very good Inv. Example 400 12.5 FC 12.5 1.23 43 alkali silicate 14 Spraying very good Inv. Example 401 18.7 FC 18.5 1.36 52 urethane-based resin 112 Spraying very good Inv. Example 402 14.5 FC 11.5 1.11 66 alkali silicate 24 Spraying very good Inv. Example 403 7.5 FC 9.6 1.07 72 urethane-based resin 150 Spraying very good Inv. Example 404 4.5 FC 8.5 1.42 40 alkali silicate 18 Spraying very good Inv. Example 405 1.5 FC 7.72 1.38 36 alkyl silicate 19 Brushing very good Inv. Example 406 4.8 FC 8.32 1.22 32 alkyl silicate 24 Spraying very good Inv. Example 407 9.6 FC 10.05 1.14 53 urethane-based resin 99 Spraying very good Inv. Example 408 11.5 FC 10.6 1.13 67 alkyl silicate 7 Spraying very good Inv. Example 409 9.8 FC 5.7 1.02 72 epoxy-based resin 100 Spraying very good Inv. Example 410 7.6 FC 6.4 1.06 77 alkyl silicate 27 Brushing very good Inv. Example 411 3.2 FC 3.2 1.05 34 alkali silicate 15 Spraying very good Inv. Example 412 1.9 FC 4.5 1.24 43 alkyl silicate 14 Spraying very good Inv. Example 413 11.5 FC 5.2 1.33 53 urethane-based resin 55 Spraying very good Inv. Example 414 8.7 FC 1.9 1.27 35 alkyl silicate 8 Spraying very good Inv. Example 415 9.6 FC 0.02 1.05 77 urethane-based resin 122 Brushing very good Inv. Example 416 9.4 FC 10.5 1.12 43 alkyl silicate 54 Spraying very good Inv. Example 417 10.5 FC 12.5 1.23 52 alkali silicate 19 Spraying very good Inv. Example 418 12.6 FC 18.5 1.36 66 alkyl silicate 25 Brushing very good Inv. Example 419 29.5 FC 11.5 1.11 72 alkyl silicate 58 Spraying very good Inv. Example 420 29.4 FC 9.6 1.07 40 alkyl silicate 21 Spraying very good Inv. Example 421 27.5 FC 8.5 1.42 36 alkali silicate 19 Brushing very good Inv. Example 422 0.8 FC 7.72 1.38 32 urethane-based resin 56 Spraying very good Inv. Example 423 1.6 FC 8.32 1.22 53 alkyl silicate 77 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 6 Zn-Alloy Particle Properties Coat Properties Fracture Average Value Ratio of Metal Coat Result of Mg Facet &/or Mean Size of Aspect Particle in Dry Thickness Coating Corrosion (mass %) Cracks (*1) (μm) Ratio Coat (mass %) Base Resin (μm) Method Test Inv. Example 424 22.9 FC 10.05 1.14 67 alkyl silicate 54 Spraying very good Inv. Example 425 28.5 FC 10.6 1.13 72 alkyl silicate 64 Spraying very good Inv. Example 426 29.5 FC 5.7 1.02 77 alkyl silicate 34 Brushing very good Inv. Example 427 18.7 FC 6.4 1.06 34 alkali silicate 28 Spraying very good Inv. Example 428 19.5 FC 3.2 1.05 43 urethane-based resin 109 Brushing very good Inv. Example 429 20.4 FC 4.5 1.24 53 alkyl silicate 15 Spraying very good Inv. Example 430 0.6 FC 5.2 1.33 72 alkyl silicate 14 Spraying very good Inv. Example 431 0.8 FC 1.9 1.27 77 alkyl silicate 18 Spraying very good Inv. Example 432 22.5 FC 0.02 1.05 35 alkali silicate 2 Spraying very good Inv. Example 433 20.6 FC 10.5 1.12 77 alkyl silicate 37 Spraying very good Inv. Example 434 21.6 FC 12.5 1.23 43 alkali silicate 2 Spraying good Inv. Example 435 20.8 FC 7.72 1.38 52 alkyl silicate 160 Brushing very good Inv. Example 436 23.6 FC 8.32 1.22 66 alkali silicate 5 Brushing very good Inv. Example 437 24.5 FC 10.05 1.14 72 alkyl silicate 56 Brushing very good Inv. Example 438 18.6 FC 10.6 1.13 40 alkali silicate 2 Spraying very good Inv. Example 439 17.8 FC 5.2 1.33 36 alkyl silicate 18 Spraying very good Inv. Example 440 16.5 FC 1.9 1.27 32 alkyl silicate 23 Spraying very good Inv. Example 441 14.5 FC 0.02 1.05 53 epoxy-based resin 30 Brushing very good Inv. Example 442 19 FC 10.5 1.12 67 acryl-based resin 77 Brushing very good Inv. Example 443 15 FC 12.5 1.23 72 urethane-based resin 54 Brushing very good Inv. Example 444 16.4 FC 18.5 1.36 77 polyester resin 47 Spraying very good Inv. Example 445 13.5 FC 11.5 1.11 34 epoxy-based resin 43 Spraying very good Inv. Example 446 10.6 FC 11.5 1.11 43 acryl-based resin 52 Brushing very good Inv. Example 447 10.7 FC 9.6 1.07 53 urethane-based resin 20 Brushing very good Inv. Example 448 10.9 FC 8.5 1.42 60 polyester resin 200 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 7 Zn-Alloy Particle Properties Coat Properties Fracture Mean Average Value Ratio of Metal Coat Mg Facet &/or Size of Aspect Particle in Dry Thickness Coating Result of (mass %) Cracks (*1) (μm) Ratio Coat (mass %) Base Resin (μm) Method Corrosion Test Inv. Example 449 11.6 FC 7.72 1.38 35 alkali silicate 22 Spraying very good Inv. Example 450 14.7 FC 8.32 1.22 77 alkyl silicate 25 Spraying very good Inv. Example 451 19.5 FC 10.05 1.14 43 alkali silicate 14 Spraying very good Inv. Example 452 10.2 FC 10.6 1.13 52 urethane-based resin 112 Spraying very good Inv. Example 453 4 FC 5.7 1.02 66 alkali silicate 24 Spraying very good Inv. Example 454 7.2 FC 6.4 1.06 72 urethane-based resin 150 Spraying very good Inv. Example 455 3.6 FC 3.2 1.05 40 alkali silicate 18 Spraying very good Inv. Example 456 26.9 FC 4.5 1.24 36 alkyl silicate 19 Brushing very good Inv. Example 457 27.9 FC 5.2 1.33 32 alkyl silicate 24 Spraying very good Inv. Example 458 28.9 FC 1.9 1.27 53 urethane-based resin 99 Spraying very good Inv. Example 459 23.8 FC 0.02 1.05 67 alkyl silicate 7 Spraying very good Inv. Example 460 26.8 FC 10.5 1.12 72 epoxy-based resin 100 Spraying very good Inv. Example 461 25.6 FC 12.5 1.23 77 alkyl silicate 27 Brushing very good Inv. Example 462 29.8 FC 18.5 1.36 34 alkali silicate 15 Spraying very good Inv. Example 463 18.9 FC 11.5 1.11 43 alkyl silicate 14 Spraying very good Inv. Example 464 5.6 FC 9.6 1.07 53 urethane-based resin 55 Spraying very good Inv. Example 465 4.7 FC 8.5 1.42 35 alkyl silicate 8 Spraying very good Inv. Example 466 6.8 FC 7.72 1.38 77 urethane-based resin 122 Brushing very good Inv. Example 467 9 FC 8.32 1.22 43 alkyl silicate 54 Spraying very good Inv. Example 468 2.1 FC 10.05 1.14 52 alkali silicate 19 Spraying very good Inv. Example 469 4.8 FC 10.6 1.13 66 alkyl silicate 25 Brushing very good Inv. Example 470 4.2 FC 5.7 1.02 72 alkyl silicate 58 Spraying very good Inv. Example 471 4.3 FC 6.4 1.06 40 alkyl silicate 21 Spraying very good Inv. Example 472 4 FC 3.2 1.05 36 alkali silicate 19 Brushing very good Inv. Example 473 3.7 FC 4.5 1.24 32 urethane-based resin 56 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 8 Zn-Alloy Particle Properties Coat Properties Fracture Average Value Ratio of Metal Coat Result of Mg Facet &/or Mean Size of Aspect Particle in Dry Thickness Coating Corrosion (mass %) Cracks (*1) (μm) Ratio Coat (mass %) Base Resin (μm) Method Test Inv. Example 474 6.4 FC 5.2 1.33 53 alkyl silicate 77 Spraying very good Inv. Example 475 6.9 FC 1.9 1.27 67 alkyl silicate 54 Spraying very good Inv. Example 476 16.9 FC 0.02 1.05 72 alkyl silicate 64 Spraying very good Inv. Example 477 18.7 FC 10.5 1.12 77 alkyl silicate 34 Brushing very good Inv. Example 478 24.4 FC 12.5 1.23 34 alkali silicate 28 Spraying very good Inv. Example 479 10.6 FC 18.5 1.36 43 urethane-based resin 109 Brushing very good Inv. Example 480 15.8 FC 11.5 1.11 53 alkyl silicate 15 Spraying very good Inv. Example 481 19.5 FC 9.6 1.07 72 alkyl silicate 14 Spraying very good Inv. Example 482 7.8 FC 8.5 1.42 77 alkyl silicate 18 Spraying very good Inv. Example 483 4.9 FC 7.72 1.38 77 urethane-based resin 122 Brushing very good Inv. Example 484 10.8 FC 8.32 1.22 43 alkyl silicate 54 Spraying very good Inv. Example 485 3.8 FC 10.05 1.14 52 alkali silicate 19 Spraying very good Inv. Example 486 22.6 FC 10.6 1.13 66 alkyl silicate 25 Brushing very good Inv. Example 487 27.9 FC 5.7 1.02 72 alkyl silicate 58 Spraying very good Inv. Example 488 24.8 FC 6.4 1.06 40 alkyl silicate 21 Spraying very good Inv. Example 489 26.8 FC 3.2 1.05 36 alkali silicate 19 Brushing very good Inv. Example 490 25.9 FC 4.5 1.24 32 urethane-based resin 56 Spraying very good Inv. Example 491 9.8 FC 5.2 1.33 53 alkyl silicate 77 Spraying very good Inv. Example 492 5.6 FC 1.9 1.27 67 alkyl silicate 54 Spraying very good Inv. Example 493 12.3 FC 0.02 1.05 52 alkali silicate 2 Spraying very good Inv. Example 494 0.8 FC 27.89 1.12 55 alkali silicate 20 Spraying very good Inv. Example 495 1 FC 0.32 1.23 69 alkali silicate 5 Spraying very good Inv. Example 496 2.3 FC 11.44 1.36 78 alkyl silicate 20 Spraying very good Inv. Example 497 15.6 FC 1.05 1.11 42 alkali silicate 15 Brushing very good Inv. Example 498 6.7 FC 36.47 1.07 32 alkyl silicate 57 Brushing very good Inv. Example 499 7.5 FC 5.07 1.42 66 alkali silicate 13 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 9 Zn-Alloy Particle Properties Coat Properties Fracture Mean Average Value Ratio of Metal Coat Result of Mg Facet &/or Size of Aspect Particle in Dry Thickness Coating Corrosion (mass %) Cracks (*1) (μm) Ratio Coat (mass %) Base Resin (μm) Method Test Inv. Example 500 8.4 FC 7.72 1.38 67 alkyl silicate 22 Brushing very good Inv. Example 501 9.3 FC 8.32 1.22 64 alkali silicate 20 Spraying very good Inv. Example 502 10.4 FC 10.05 1.14 74 alkyl silicate 27 Spraying very good Inv. Example 503 11.2 FC 6.08 1.13 82 alkali silicate 15 Spraying very good Inv. Example 504 11.7 FC 17.89 1.02 37 alkyl silicate 35 Spraying very good Inv. Example 505 21.5 FC 19.54 1.06 42 alkali silicate 34 Brushing very good Inv. Example 506 13.4 FC 21.08 1.05 66 alkyl silicate 45 Brushing very good Inv. Example 507 14.6 FC 23.04 1.24 48 alkali silicate 52 Brushing very good Inv. Example 508 25.8 FC 9.21 1.33 33 alkyl silicate 23 Brushing very good Inv. Example 509 16.7 FC 0.12 1.27 75 alkali silicate 5 Spraying very good Inv. Example 510 17.3 FC 29.24 1.37 77 alkyl silicate 52 Brushing very good Inv. Example 511 18.5 FC 128.74 1.10 66 alkali silicate 150 Brushing very good Inv. Example 512 19.3 FC 33.57 1.04 67 alkyl silicate 60 Brushing very good Inv. Example 513 3.5 FC 3.04 1.02 45 alkali silicate 15 Spraying very good Inv. Example 514 22.5 FC 7.54 1.01 48 alkyl silicate 24 Spraying very good Inv. Example 515 23.7 FC 6.81 1.08 68 alkali silicate 34 Spraying very good Inv. Example 516 24.2 FC 5.25 1.14 35 alkyl silicate 20 Brushing very good Inv. Example 517 0.2 FC 194.23 1.23 37 alkali silicate 200 Brushing very good Inv. Example 518 27.1 FC 28.74 1.33 38 alkyl silicate 56 Brushing very good Inv. Example 519 29.3 FC 13.57 1.37 41 alkali silicate 34 Spraying very good Inv. Example 520 0.5 FC 0.65 1.44 54 alkyl silicate 2 Spraying very good Inv. Example 521 2.7 FC 4.12 1.21 57 alkali silicate 15 Spraying very good Inv. Example 522 28.4 FC 0.72 1.22 59 alkali silicate 10 Spraying very good Inv. Example 523 8.7 FC 117.54 1.23 64 alkyl silicate 125 Brushing very good Inv. Example 524 9.2 FC 7.81 1.47 66 alkali silicate 24 Brushing very good Inv. Example 525 17.8 FC 80.25 1.01 67 alkyl silicate 110 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 10 Zn-Alloy Particle Properties Coat Properties Fracture Average Value Ratio of Metal Coat Result of Mg Facet &/or Mean Size of Aspect Particle in Dry Thickness Coating Corrosion (mass %) Cracks (*1) (μm) Ratio Coat (mass %) Base Resin (μm) Method Test Inv. Example 526 20.2 FC 8.47 1.04 34 alkali silicate 24 Brushing very good Inv. Example 527 0.4 FC 0.87 1.05 54 alkyl silicate 2 Spraying very good Inv. Example 528 13.7 FC 25.78 1.12 62 alkali silicate 37 Spraying very good Inv. Example 529 14.7 FC 93.45 1.11 66 alkyl silicate 113 Brushing very good Inv. Example 530 2.4 FC 0.97 1.08 67 alkali silicate 2 Spraying very good Inv. Example 531 4.5 FC 54.89 1.47 68 alkyl silicate 75 Brushing very good Inv. Example 532 0.1 FC 10.81 1.50 33 alkali silicate 30 Brushing very good Inv. Example 533 30.0 FC 18.24 1.13 35 alkyl silicate 34 Brushing very good Inv. Example 534 24.5 FC 114.78 1.04 43 epoxy-based resin 124 Brushing very good Inv. Example 535 27.6 FC 3.87 1.02 44 acryl-based resin 15 Spraying very good Inv. Example 536 4.1 FC 11.94 1.08 43 urethane-based resin 23 Spraying very good Inv. Example 537 3.2 FC 142.58 1.15 44 polyester resin 157 Brushing very good Inv. Example 538 2.7 FC 12.5 1.34 54 epoxy-based resin 26 Spraying very good Inv. Example 539 0.12 FC 31.24 1.25 79 acryl-based resin 38 Spraying very good Inv. Example 540 0.22 FC 152.46 1.19 73 urethane-based resin 160 Brushing very good Inv. Example 541 0.37 FC 13.4 1.18 69 polyester resin 27 Brushing very good Inv. Example 542 1.4 FC 160.57 1.24 63 epoxy-based resin 180 Brushing very good Inv. Example 543 4.2 FC 14.1 1.11 35 acryl-based resin 26 Spraying very good Inv. Example 544 4.8 FC 167.55 1.27 35 urethane-based resin 180 Brushing very good Inv. Example 545 8.1 FC 1.45 1.31 66 polyester resin 15 Spraying very good Inv. Example 546 7.6 FC 0.15 1.26 67 epoxy-based resin 2 Spraying very good Inv. Example 547 9.9 FC 13.1 1.14 68 acryl-based resin 28 Spraying very good Inv. Example 548 14.8 FC 15.5 1.34 33 urethane-based resin 30 Spraying very good Inv. Example 549 16.7 FC 0.67 1.16 35 polyester resin 2 Spraying very good Inv. Example 550 17.9 FC 137.89 1.47 43 epoxy-based resin 157 Brushing very good Inv. Example 551 19.5 FC 16.3 1.48 44 acryl-based resin 28 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 11 Zn-Alloy Particle Properties Coat Properties Fracture Average Value Ratio of Metal Coat Result of Mg Facet &/or Mean Size of Aspect Particle in Dry Thickness Coating Corrosion (mass %) Cracks (*1) (μm) Ratio Coat (mass %) Base Resin (μm) Method Test Inv. Example 552 22.4 FC 110.38 1.49 42 urethane-based resin 130 Brushing very good Inv. Example 553 0.17 FC 12.4 1.34 33 polyester resin 29 Brushing very good Inv. Example 554 8.3 FC 17.2 1.29 30 epoxy-based resin 30 Brushing very good Inv. Example 555 6.5 FC 105.23 1.18 35 acryl-based resin 120 Brushing very good Inv. Example 556 9.7 FC 177.89 1.23 37 urethane-based resin 187 Brushing very good Inv. Example 557 11.4 FC 12.2 1.27 77 polyester resin 28 Spraying very good Inv. Example 558 22.5 FC 1.84 1.17 41 epoxy-based resin 5 Spraying very good Inv. Example 559 25.7 FC 16.02 1.16 35 acryl-based resin 35 Spraying very good Inv. Example 560 17.8 FC 1.75 1.49 58 urethane-based resin 5 Spraying very good Inv. Example 561 0.14 FC 198.78 1.34 37 polyester resin 200 Brushing very good Inv. Example 562 6.7 FC 13.1 1.16 68 alkali silicate 25 Spraying very good Inv. Example 563 7.5 FC 15.5 1.47 55 alkali silicate 15 Spraying very good Inv. Example 564 8.4 FC 0.67 1.48 77 alkyl silicate 20 Spraying very good Inv. Example 565 9.3 FC 12.2 1.49 43 alkali silicate 18 Spraying very good Inv. Example 566 1.4 FC 1.84 1.34 45 alkyl silicate 22 Spraying very good Inv. Example 567 4.2 FC 16.02 1.29 66 alkali silicate 19 Spraying very good Inv. Example 568 4.8 FC 1.75 1.18 33 alkyl silicate 29 Spraying very good Inv. Example 569 8.1 FC 12.4 1.23 66 alkali silicate 23 Spraying very good Inv. Example 570 7.6 FC 17.2 1.27 55 alkyl silicate 21 Spraying very good Inv. Example 571 9.9 FC 13.1 1.17 49 alkali silicate 19 Spraying very good Inv. Example 572 0.4 FC 29.9 1.16 77 alkyl silicate 15 Spraying very good Inv. Example 573 10.5 FC 0.21 1.27 41 alkali silicate 18 Spraying very good Inv. Example 574 0.4 FC 0.22 1.17 64 alkyl silicate 22 Spraying very good Inv. Example 575 10.5 FC 29.5 1.27 58 alkyl silicate 21 Spraying very good Inv. Example 576 0.51 FC 29.9 1.18 33 alkyl silicate 29 Spraying very good Inv. Example 577 9.8 FC 0.21 1.23 66 alkali silicate 23 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 12 Zn-Alloy Particle Properties Coat Properties Fracture Mean Average Value Ratio of Metal Coat Mg Facet &/or Size of Aspect Particle in Dry Thickness Coating Result of (mass %) Cracks (*1) (μm) Ratio Coat (mass %) Base Resin (μm) Method Corrosion Test Inv. Example 578 0.52 FC 0.22 1.27 55 alkyl silicate 21 Spraying very good Inv. Example 579 9.9 FC 29.5 1.17 49 alkali silicate 19 Spraying very good Inv. Example 580 14.8 FC 16.02 1.48 77 alkyl silicate 21 Spraying very good Inv. Example 581 16.7 FC 1.75 1.49 43 alkali silicate 19 Spraying very good Inv. Example 582 17.9 FC 12.4 1.34 45 alkyl silicate 15 Spraying very good Inv. Example 583 19.5 FC 17.2 1.29 66 alkali silicate 18 Spraying very good Comp. Example 14 2.3 FC 205.6 1.23 75 alkyl silicate 25 Spraying poor Comp. Example 15 2.3 FC 0.005 1.23 75 alkyl silicate 25 Spraying poor Comp. Example 16 2.3 FC 205.6 1.23 75 alkyl silicate 105 Brushing poor Comp. Example 17 2.3 FC 0.005 1.23 75 alkyl silicate 165 Spraying poor Inv. Example 2005 0.05 FC 2.5 1.05 38 alkali silicate 19 Spraying very good Inv. Example 2006 0.07 FC 0.09 1.12 49 alkyl silicate 11 Spraying very good Inv. Example 2007 2.64 FC 5.5 1.22 43 alkyl silicate 16 Spraying very good Inv. Example 2008 0.08 FC 5.6 1.36 66 alkyl silicate 16 Brushing very good Inv. Example 2009 0.09 FC 11.5 1.11 67 alkali silicate 33 Brushing very good Inv. Example 2010 0.05 FC 19.5 1.07 54 alkyl silicate 8 Brushing good Inv. Example 2011 1.59 FC 6.7 1.14 76 alkyl silicate 5 Spraying very good Inv. Example 2012 2.58 FC 8.9 1.13 49 alkyl silicate 22 Spraying very good Inv. Example 2013 0.06 FC 8.32 1.22 32 alkyl silicate 23 Spraying very good Inv. Example 2014 0.18 FC 10.05 1.14 53 epoxy-based resin 30 Spraying very good Inv. Example 2015 7.55 FC 2.15 1.14 75 alkyl silicate 18 Spraying very good Inv. Example 2016 0.01 FC 0.06 1.23 75 alkali silicate 5 Spraying good Inv. Example 2017 8.01 FC 2.54 1.13 73 alkyl silicate 16 Spraying very good Inv. Example 2018 1.06 FC 3.4 1.38 49 alkyl silicate 8 Spraying very good Inv. Example 2019 0.04 FC 8.5 1.42 40 alkali silicate 2 Spraying very good Inv. Example 2020 0.06 FC 7.72 1.38 36 alkyl silicate 18 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 13 Zn-Alloy Particle Properties Coat Properties Fracture Mean Average Value Ratio of Metal Coat Mg Facet &/or Size of Aspect Particle in Dry Thickness Coating Result of (mass %) Cracks (*1) (μm) Ratio Coat (mass %) Base Resin (μm) Method Corrosion Test Inv. Example 2021 9.51 FC 2.77 1.38 55 alkyl silicate 5 Spraying very good Inv. Example 2022 10.01 FC 3.68 1.22 48 alkyl silicate 22 Spraying very good Inv. Example 2023 0.05 FC 10.6 1.13 67 acryl-based resin 77 Brushing very good Inv. Example 2024 0.07 FC 5.7 1.02 72 urethane-based resin 54 Brushing very good Inv. Example 2025 3.54 FC 5.5 1.22 78 alkyl silicate 18 Spraying very good Inv. Example 2026 0.08 FC 3.2 1.05 34 epoxy-based resin 43 Spraying very good Inv. Example 2027 0.09 FC 4.5 1.24 43 acryl-based resin 52 Brushing very good Inv. Example 2028 5.22 FC 2.54 1.14 45 alkyl silicate 19 Spraying very good Inv. Example 2029 4.05 FC 2.06 1.13 52 alkyl silicate 8 Spraying very good Inv. Example 2030 8.57 FC 4.99 1.02 61 alkyl silicate 16 Spraying very good Inv. Example 2031 0.01 FC 6.4 1.06 77 polyester resin 47 Spraying very good Inv. Example 2032 4.59 FC 3.09 1.07 49 alkyl silicate 22 Spraying very good Inv. Example 2033 9.88 FC 4.66 1.42 79 alkyl silicate 18 Spraying very good Inv. Example 2034 4.55 FC 4.09 1.38 76 alkyl silicate 18 Spraying very good Inv. Example 2035 2.36 FC 3.99 1.22 80 alkyl silicate 21 Spraying very good Inv. Example 2036 0.05 FC 7.72 1.38 36 alkyl silicate 19 Brushing very good Inv. Example 2037 0.04 FC 8.32 1.22 32 alkyl silicate 24 Spraying very good Inv. Example 2038 2.64 FC 4.55 1.11 43 alkyl silicate 5 Spraying very good Inv. Example 2039 0.06 FC 10.6 1.13 67 alkyl silicate 7 Spraying very good Inv. Example 2040 0.18 FC 5.7 1.02 72 epoxy-based resin 100 Spraying very good Inv. Example 2041 6.31 FC 3.52 1.27 51 alkyl silicate 21 Spraying very good Inv. Example 2042 5..22 FC 3.55 1.12 55 alkyl silicate 19 Spraying very good Inv. Example 2043 4.01 FC 2.64 1.23 40 alkyl silicate 8 Spraying very good Inv. Example 2044 3.52 FC 3.15 1.36 51 alkyl silicate 16 Spraying very good Inv. Example 2045 0.05 FC 5.2 1.33 53 urethane-based resin 20 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 14 Zn-Alloy Particle Properties Coat Properties Fracture Average Value Ratio of Metal Coat Result of Mg Facet &/or Mean Size of Aspect Particle in Dry Thickness Coating Corrosion (mass %) Cracks (*1) (μm) Ratio Coat (mass %) Base Resin (μm) Method Test Inv. Example 2046 0.04 FC 1.9 1.27 60 polyester resin 200 Brushing very good Inv. Example 2047 0.06 FC 10.5 1.12 77 alkyl silicate 25 Spraying very good Inv. Example 2048 0.05 FC 12.5 1.23 43 alkali silicate 14 Spraying very good Inv. Example 2049 0.07 FC 18.5 1.36 52 urethane-based resin 112 Spraying very good Inv. Example 2050 0.01 FC 11.5 1.11 66 alkali silicate 24 Spraying very good Inv. Example 2051 0.08 FC 9.6 1.07 72 urethane-based resin 150 Spraying very good Inv. Example 2052 0.09 FC 8.5 1.42 40 alkali silicate 18 Spraying very good Inv. Example 2053 4.25 FC 2.36 1.33 44 alkyl silicate 18 Spraying very good Inv. Example 2054 0.04 FC 23.5 1.42 44 alkali silicate 38 Spraying very good Inv. Example 2055 0.06 FC 101.5 1.38 36 alkyl silicate 18 Spraying very good Inv. Example 2056 0.06 FC 55.4 1.38 76 alkyl silicate 10 Spraying very good Inv. Example 2057 0.07 FC 10.5 1.12 77 alkyl silicate 37 Spraying very good Inv. Example 2058 0.01 FC 12.5 1.23 43 alkali silicate 2 Spraying good Inv. Example 2059 0.08 FC 18.5 1.36 52 alkyl silicate 160 Brushing very good Inv. Example 2060 0.09 FC 11.5 1.11 66 alkali silicate 5 Brushing very good Inv. Example 2061 0.05 FC 9.6 1.07 72 alkyl silicate 56 Brushing very good Inv. Example 2062 0.06 FC 10.05 1.14 53 urethane-based resin 99 Spraying very good Inv. Example 2063 29.9 FC 10.5 1.36 55 urethane-based resin 700 Spraying very good Inv. Example 2064 16.5 FC 7.5 1.11 47 alkyl silicate 554 Spraying very good Inv. Example 2065 12.5 FC 2.6 1.07 79 urethane-based resin 688 Brushing very good Inv. Example 2066 9.8 FC 3.5 1.42 42 urethane-based resin 421 Spraying very good Inv. Example 2067 9.6 FC 4.5 1.33 36 urethane-based resin 651 Spraying very good Inv. Example 2068 7.5 FC 1.6 1.42 53 urethane-based resin 402 Brushing very good Inv. Example 2069 4.6 FC 2.5 1.12 55 alkali silicate 354 Spraying very good Inv. Example 2070 3.8 FC 23.5 1.23 42 urethane-based resin 504 Brushing very good Inv. Example 2071 0.05 FC 9.8 1.27 76 urethane-based resin 666 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

Example 2

Zn alloy particles further containing one or both of Al and Si were produced as shown by the chemical ingredients in Tables 15 to 26. The rest is the same as Example 1.

From Tables 15 to 26, it is learned that the painting test pieces using the Zn alloy particles of the present invention exhibit superior corrosion resistance both with inorganic-based binders and organic-based binders.

TABLE 15 Zn-Alloy Particle Properties Coat Properties Fracture Average Ratio of Metal Mg Facet &/or Mean Value of Al Si Particle in Coat Result of (mass Cracks Size Aspect (mass (mass Dry Coat Thickness Coating Corrosion %) (*1) (μm) Ratio %) %) (mass %) Base Resin (μm) Method Test Inv. Example 70 12.3 F 0.02 1.05 0.1 0.07 35 alkali silicate 2 Spraying very good Inv. Example 71 0.8 F 27.89 1.12 0.04 0.1 77 alkyl silicate 37 Spraying very good Inv. Example 72 1.0 F 0.32 1.23 30.0 0.01 43 alkali silicate 2 Spraying good Inv. Example 73 2.3 F 158.96 1.36 0.02 3 52 alkyl silicate 160 Brushing very good Inv. Example 74 15.6 F 1.05 1.11 8.02 2.04 66 alkali silicate 5 Brushing very good Inv. Example 75 6.7 F 36.47 1.07 15.6 1.27 72 alkyl silicate 56 Brushing very good Inv. Example 76 7.5 F 0.51 1.42 10.4 0.57 40 alkali silicate 2 Spraying very good Inv. Example 77 8.4 F 7.72 1.38 4.65 2.67 36 alkyl silicate 18 Spraying very good Inv. Example 78 9.3 F 8.32 1.22 24.8 2.4 32 alkyl silicate 23 Spraying very good Inv. Example 79 10.4 F 10.05 1.14 4.52 0.57 53 epoxy-based resin 30 Brushing very good Inv. Example 80 11.2 F 60.08 1.13 17.5 2.45 67 acryl-based resin 77 Brushing very good Inv. Example 81 11.7 F 17.89 1.02 745 1.75 72 urethane-based resin 54 Brushing very good Inv. Example 82 21.5 F 19.54 1.06 11.05 0.23 77 polyester resin 47 Spraying very good Inv. Example 83 13.4 F 21.08 1.05 2.65 0.74 34 epoxy-based resin 43 Spraying very good Inv. Example 84 14.6 F 23.04 1.24 6.45 2.14 43 acryl-based resin 52 Brushing very good Inv. Example 85 25.8 F 9.02 1.33 27.6 2.4 53 urethane-based resin 20 Brushing very good Inv. Example 86 16.7 F 194.23 1.27 4.32 1.07 60 polyester resin 200 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 16 Zn-Alloy Particle Properties Coat Properties Average Ratio of Metal Mg Fracture Mean Value of Al Si Particle in Coat Result of (mass Facet &/or Size Aspect (mass (mass Dry Coat Thickness Coating Corrosion %) Cracks (*1) (μm) Ratio %) %) (mass %) Base Resin (μm) Method Test Inv. Example 584 0.15 FC 0.02 1.05 0.1 0.07 35 alkali silicate 2 Spraying very good Inv. Example 585 0.19 FC 10.5 1.12 0.04 0.1 77 alkyl silicate 37 Spraying very good Inv. Example 586 0.18 FC 12.5 1.23 30.0 0.01 43 alkali silicate 2 Spraying good Inv. Example 587 0.11 FC 18.5 1.36 0.02 3 52 alkyl silicate 160 Brushing very good Inv. Example 588 0.15 FC 11.5 1.11 0 0 66 alkali silicate 5 Brushing very good Inv. Example 589 0.24 FC 9.6 1.07 0 0 72 alkyl silicate 56 Brushing very good Inv. Example 590 0.18 FC 8.5 1.42 10.4 0.57 40 alkali silicate 2 Spraying very good Inv. Example 591 0.12 FC 7.72 1.38 4.65 2.67 36 alkyl silicate 18 Spraying very good Inv. Example 592 0.19 FC 8.32 1.22 24.8 2.4 32 alkyl silicate 23 Spraying very good Inv. Example 593 0.18 FC 10.05 1.14 4.52 0.57 53 epoxy-based resin 30 Brushing very good Inv. Example 594 0.21 FC 10.6 1.13 17.5 2.45 67 acryl-based resin 77 Brushing very good Inv. Example 595 0.76 FC 5.7 1.02 0 0 72 urethane-based resin 54 Brushing very good Inv. Example 596 0.11 FC 6.4 1.06 11.05 0.23 77 polyester resin 47 Spraying very good Inv. Example 597 0.14 FC 3.2 1.05 2.65 0.74 34 epoxy-based resin 43 Spraying very good Inv. Example 598 15 FC 4.5 1.24 6.45 2.14 43 acryl-based resin 52 Brushing very good Inv. Example 599 14.5 FC 5.2 1.33 0 0 53 urethane-based resin 20 Brushing very good Inv. Example 600 18.5 FC 1.9 1.27 0 0 60 polyester resin 200 Brushing very good Inv. Example 601 15.1 FC 0.02 1.05 0.05 0.03 35 alkali silicate 22 Spraying very good Inv. Example 602 15.6 FC 10.5 1.12 0 0.08 77 alkyl silicate 25 Spraying very good Inv. Example 603 12.5 FC 12.5 1.23 0.05 0 43 alkali silicate 14 Spraying very good Inv. Example 604 18.7 FC 18.5 1.36 0.44 0.07 52 urethane-based resin 112 Spraying very good Inv. Example 605 14.5 FC 11.5 1.11 0.08 0.07 66 alkali silicate 24 Spraying very good Inv. Example 606 7.5 FC 9.6 1.07 0.1 0.2 72 urethane-based resin 150 Spraying very good Inv. Example 607 4.5 FC 8.5 1.42 0 0 40 alkali silicate 18 Spraying very good Inv. Example 608 1.5 FC 7.72 1.38 0 0 36 alkyl silicate 19 Brushing very good Inv. Example 609 4.8 FC 8.32 1.22 0 0.07 32 alkyl silicate 24 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 17 Zn-Alloy Particle Properties Coat Properties Average Ratio of Metal Mg Fracture Mean Value of Al Si Particle in Coat Result of (mass Facet &/or Size Aspect (mass (mass Dry Coat Thickness Coating Corrosion %) Cracks (*1) (μm) Ratio %) %) (mass %) Base Resin (μm) Method Test Inv. Example 610 9.6 FC 10.05 1.14 0 0.02 53 urethane-based resin 99 Spraying very good Inv. Example 611 11.5 FC 10.6 1.13 25.8 0.05 67 alkyl silicate 7 Spraying very good Inv. Example 612 9.8 FC 5.7 1.02 22.1 0 72 epoxy-based resin 100 Spraying very good Inv. Example 613 7.6 FC 6.4 1.06 21.5 0.05 77 alkyl silicate 27 Brushing very good Inv. Example 614 3.2 FC 3.2 1.05 0.05 2.29 34 alkali silicate 15 Spraying very good Inv. Example 615 1.9 FC 4.5 1.24 0.05 0.03 43 alkyl silicate 14 Spraying very good Inv. Example 616 11.5 FC 5.2 1.33 0 0.08 53 urethane-based resin 55 Spraying very good Inv. Example 617 8.7 FC 1.9 1.27 0 0 35 alkyl silicate 8 Spraying very good Inv. Example 618 9.6 FC 0.02 1.05 0 0 77 urethane-based resin 122 Brushing very good Inv. Example 619 9.4 FC 10.5 1.12 0.08 0.07 43 alkyl silicate 54 Spraying very good Inv. Example 620 10.5 FC 12.5 1.23 0.1 0.2 52 alkali silicate 19 Spraying very good Inv. Example 621 12.6 FC 18.5 1.36 0.05 0.2 66 alkyl silicate 25 Brushing very good Inv. Example 622 29.5 FC 11.5 1.11 0.07 0 72 alkyl silicate 58 Spraying very good Inv. Example 623 29.4 FC 9.6 1.07 0 0.07 40 alkyl silicate 21 Spraying very good Inv. Example 624 27.5 FC 8.5 1.42 0 0.02 36 alkali silicate 19 Brushing very good Inv. Example 625 0.8 FC 7.72 1.38 25.8 0.05 32 urethane-based resin 56 Spraying very good Inv. Example 626 1.6 FC 8.32 1.22 22.1 0 53 alkyl silicate 77 Spraying very good Inv. Example 627 22.9 FC 10.05 1.14 21.5 0.05 67 alkyl silicate 54 Spraying very good Inv. Example 628 28.5 FC 10.6 1.13 0.05 2.29 72 alkyl silicate 64 Spraying very good Inv. Example 629 29.5 FC 5.7 1.02 0.1 0.2 77 alkyl silicate 34 Brushing very good Inv. Example 630 18.7 FC 6.4 1.06 0.05 0.2 34 alkali silicate 28 Spraying very good Inv. Example 631 19.5 FC 3.2 1.05 0.07 0 43 urethane-based resin 109 Brushing very good Inv. Example 632 20.4 FC 4.5 1.24 0 0.07 53 alkyl silicate 15 Spraying very good Inv. Example 633 0.6 FC 5.2 1.33 0 0.02 72 alkyl silicate 14 Spraying very good Inv. Example 634 0.8 FC 1.9 1.27 22.1 0 77 alkyl silicate 18 Spraying very good Inv. Example 635 22.5 FC 0.02 1.05 0.1 0.07 35 alkali silicate 2 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 18 Zn-Alloy Particle Properties Coat Properties Average Ratio of Metal Mg Fracture Mean Value of Al Si Particle in Coat Result of (mass Facet &/or Size Aspect (mass (mass Dry Coat Thickness Coating Corrosion %) Cracks (*1) (μm) Ratio %) %) (mass %) Base Resin (μm) Method Test Inv. Example 636 20.6 FC 10.5 1.12 0.04 0.1 77 alkyl silicate 37 Spraying very good Inv. Example 637 21.6 FC 12.5 1.23 30.0 0.01 43 alkali silicate 2 Spraying good Inv. Example 638 20.8 FC 7.72 1.38 0 0 52 alkyl silicate 160 Brushing very good Inv. Example 639 23.6 FC 8.32 1.22 0 0 66 alkali silicate 5 Brushing very good Inv. Example 640 24.5 FC 10.05 1.14 4.52 0.57 72 alkyl silicate 56 Brushing very good Inv. Example 641 18.6 FC 10.6 1.13 17.5 2.45 40 alkali silicate 2 Spraying very good Inv. Example 642 17.8 FC 5.2 1.33 27.6 2.4 36 alkyl silicate 18 Spraying very good Inv. Example 643 16.5 FC 1.9 1.27 4.32 1.07 32 alkyl silicate 23 Spraying very good Inv. Example 644 14.5 FC 0.02 1.05 0.05 0.03 53 epoxy-based resin 30 Brushing very good Inv. Example 645 19 FC 10.5 1.12 0 0.08 67 acryl-based resin 77 Brushing very good Inv. Example 646 15 FC 12.5 1.23 0.05 0 72 urethane-based resin 54 Brushing very good Inv. Example 647 16.4 FC 18.5 1.36 0.44 0.07 77 polyester resin 47 Spraying very good Inv. Example 648 13.5 FC 11.5 1.11 0.08 0.07 34 epoxy-based resin 43 Spraying very good Inv. Example 649 10.6 FC 11.5 1.11 8.02 2.04 43 acryl-based resin 52 Brushing very good Inv. Example 650 10.7 FC 9.6 1.07 15.6 1.27 53 urethane-based resin 20 Brushing very good Inv. Example 651 10.9 FC 8.5 1.42 10.4 0.57 60 polyester resin 200 Brushing very good Inv. Example 652 11.6 FC 7.72 1.38 4.65 2.67 35 alkali silicate 22 Spraying very good Inv. Example 653 14.7 FC 8.32 1.22 24.8 2.4 77 alkyl silicate 25 Spraying very good Inv. Example 654 19.5 FC 10.05 1.14 4.52 0.57 43 alkali silicate 14 Spraying very good Inv. Example 655 10.2 FC 10.6 1.13 0 0 52 urethane-based resin 112 Spraying very good Inv. Example 656 4 FC 5.7 1.02 0 0 66 alkali silicate 24 Spraying very good Inv. Example 657 7.2 FC 6.4 1.06 11.05 0.23 72 urethane-based resin 150 Spraying very good Inv. Example 658 3.6 FC 3.2 1.05 2.65 0.74 40 alkali silicate 18 Spraying very good Inv. Example 659 26.9 FC 4.5 1.24 6.45 2.14 36 alkyl silicate 19 Brushing very good Inv. Example 660 27.9 FC 5.2 1.33 27.6 2.4 32 alkyl silicate 24 Spraying very good Inv. Example 661 28.9 FC 1.9 1.27 4.32 1.07 53 urethane-based resin 99 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 19 Zn-Alloy Particle Properties Coat Properties Average Ratio of Metal Mg Fracture Mean Value of Al Si Particle in Coat Result of (mass Facet &/or Size Aspect (mass (mass Dry Coat Thickness Coating Corrosion %) Cracks (*1) (μm) Ratio %) %) (mass %) Base Resin (μm) Method Test Inv. Example 662 23.8 FC 0.02 1.05 0.05 0.03 67 alkyl silicate 7 Spraying very good Inv. Example 663 26.8 FC 10.5 1.12 0 0.08 72 epoxy-based resin 100 Spraying very good Inv. Example 664 25.6 FC 12.5 1.23 0.05 0 77 alkyl silicate 27 Brushing very good Inv. Example 665 29.8 FC 18.5 1.36 0.44 0.07 34 alkali silicate 15 Spraying very good Inv. Example 666 18.9 FC 11.5 1.11 0.08 0.07 43 alkyl silicate 14 Spraying very good Inv. Example 667 5.6 FC 9.6 1.07 0.1 0.2 53 urethane-based resin 55 Spraying very good Inv. Example 668 4.7 FC 8.5 1.42 0.05 0.2 35 alkyl silicate 8 Spraying very good Inv. Example 669 6.8 FC 7.72 1.38 0.07 0 77 urethane-based resin 122 Brushing very good Inv. Example 670 9 FC 8.32 1.22 0 0.07 43 alkyl silicate 54 Spraying very good Inv. Example 671 2.1 FC 10.05 1.14 0 0.02 52 alkali silicate 19 Spraying very good Inv. Example 672 4.8 FC 10.6 1.13 0 0 66 alkyl silicate 25 Brushing very good Inv. Example 673 4.2 FC 5.7 1.02 0 0 72 alkyl silicate 58 Spraying very good Inv. Example 674 4.3 FC 6.4 1.06 21.5 0.05 40 alkyl silicate 21 Spraying very good Inv. Example 675 4 FC 3.2 1.05 0.05 2.29 36 alkali silicate 19 Brushing very good Inv. Example 676 3.7 FC 4.5 1.24 0.05 0.03 32 urethane-based resin 56 Spraying very good Inv. Example 677 6.4 FC 5.2 1.33 0 0.08 53 alkyl silicate 77 Spraying very good Inv. Example 678 6.9 FC 1.9 1.27 0.05 0 67 alkyl silicate 54 Spraying very good Inv. Example 679 16.9 FC 0.02 1.05 0.44 0.07 72 alkyl silicate 64 Spraying very good Inv. Example 680 18.7 FC 10.5 1.12 0.08 0.07 77 alkyl silicate 34 Brushing very good Inv. Example 681 24.4 FC 12.5 1.23 0.1 0.2 34 alkali silicate 28 Spraying very good Inv. Example 682 10.6 FC 18.5 1.36 0 0 43 urethane-based resin 109 Brushing very good Inv. Example 683 15.8 FC 11.5 1.11 0 0 53 alkyl silicate 15 Spraying very good Inv. Example 684 19.5 FC 9.6 1.07 0 0.07 72 alkyl silicate 14 Spraying very good Inv. Example 685 7.8 FC 8.5 1.42 0 0.02 77 alkyl silicate 18 Spraying very good Inv. Example 686 4.9 FC 7.72 1.38 25.8 0.05 77 urethane-based resin 122 Brushing very good Inv. Example 687 10.8 FC 8.32 1.22 22.1 0 43 alkyl silicate 54 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 20 Zn-Alloy Particle Properties Coat Properties Average Ratio of Metal Mg Fracture Mean Value of Al Si Particle in Coat Result of (mass Facet &/or Size Aspect (mass (mass Dry Coat Thickness Coating Corrosion %) Cracks (*1) (μm) Ratio %) %) (mass %) Base Resin (μm) Method Test Inv. Example 688 3.8 FC 10.05 1.14 21.5 0.05 52 alkali silicate 19 Spraying very good Inv. Example 689 22.6 FC 10.6 1.13 0.05 2.29 66 alkyl silicate 25 Brushing very good Inv. Example 690 27.9 FC 5.7 1.02 0 0 72 alkyl silicate 58 Spraying very good Inv. Example 691 24.8 FC 6.4 1.06 0 0 40 alkyl silicate 21 Spraying very good Inv. Example 692 26.8 FC 3.2 1.05 0.07 0 36 alkali silicate 19 Brushing very good Inv. Example 693 25.9 FC 4.5 1.24 0 0.07 32 urethane-based resin 56 Spraying very good Inv. Example 694 9.8 FC 5.2 1.33 0 0.02 53 alkyl silicate 77 Spraying very good Inv. Example 695 5.6 FC 1.9 1.27 22.1 0 67 alkyl silicate 54 Spraying very good Inv. Example 696 12.3 FC 0.02 1.05 1.24 1.8 52 alkali silicate 2 Spraying very good Inv. Example 697 0.8 FC 27.89 1.12 1.24 0.9 55 alkali silicate 20 Spraying very good Inv. Example 698 1 FC 0.32 1.23 0.8 0.7 69 alkali silicate 5 Spraying very good Inv. Example 699 2.3 FC 11.44 1.36 0 1.8 78 alkyl silicate 20 Spraying very good Inv. Example 700 15.6 FC 1.05 1.11 1.1 2.41 42 alkali silicate 15 Brushing very good Inv. Example 701 6.7 FC 36.47 1.07 1.8 0.08 32 alkyl silicate 57 Brushing very good Inv. Example 702 7.5 FC 5.07 1.42 3.8 2.23 66 alkali silicate 13 Brushing very good Inv. Example 703 8.4 FC 7.72 1.38 2.9 0.06 67 alkyl silicate 22 Brushing very good Inv. Example 704 9.3 FC 8.32 1.22 10.5 0.02 64 alkali silicate 20 Spraying very good Inv. Example 705 10.4 FC 10.05 1.14 2.9 0.02 74 alkyl silicate 27 Spraying very good Inv. Example 706 11.2 FC 6.08 1.13 16.8 1.37 82 alkali silicate 15 Spraying very good Inv. Example 707 11.7 FC 17.89 1.02 0 2.43 37 alkyl silicate 35 Spraying very good Inv. Example 708 21.5 FC 19.54 1.06 3.6 0.02 42 alkali silicate 34 Brushing very good Inv. Example 709 13.4 FC 21.08 1.05 2.1 1.5 66 alkyl silicate 45 Brushing very good Inv. Example 710 14.6 FC 23.04 1.24 0.06 1.3 48 alkali silicate 52 Brushing very good Inv. Example 711 25.8 FC 9.21 1.33 0.02 1.8 33 alkyl silicate 23 Brushing very good Inv. Example 712 16.7 FC 0.12 1.27 1.6 0.9 75 alkali silicate 5 Spraying very good Inv. Example 713 17.3 FC 29.24 1.37 3.5 0 77 alkyl silicate 52 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 21 Zn-Alloy Particle Properties Coat Properties Average Ratio of Metal Mg Fracture Mean Value of Al Si Particle in Coat Result of (mass Facet &/or Size Aspect (mass (mass Dry Coat Thickness Coating Corrosion %) Cracks (*1) (μm) Ratio %) %) (mass %) Base Resin (μm) Method Test Inv. Example 714 18.5 FC 128.74 1.10 9.8 1.8 66 alkali silicate 150 Brushing very good Inv. Example 715 19.3 FC 33.57 1.04 11.5 0.7 67 alkyl silicate 60 Brushing very good Inv. Example 716 3.5 FC 3.04 1.02 0.4 1.5 45 alkali silicate 15 Spraying very good Inv. Example 717 22.5 FC 7.54 1.01 0.6 1.3 48 alkyl silicate 24 Spraying very good Inv. Example 718 23.7 FC 6.81 1.08 10.6 1.8 68 alkali silicate 34 Spraying very good Inv. Example 719 24.2 FC 5.25 1.14 9.5 0 35 alkyl silicate 20 Brushing very good Inv. Example 720 0.2 FC 194.23 1.23 11.04 0.7 37 alkali silicate 200 Brushing very good Inv. Example 721 27.1 FC 28.74 1.33 0.01 1.8 38 alkyl silicate 56 Brushing very good Inv. Example 722 29.3 FC 13.57 1.37 0.07 0.7 41 alkali silicate 34 Spraying very good Inv. Example 723 0.5 FC 0.65 1.44 1.8 1.5 54 alkyl silicate 2 Spraying very good Inv. Example 724 2.7 FC 4.12 1.21 0 1.3 57 alkali silicate 15 Spraying very good Inv. Example 725 28.4 FC 0.72 1.22 2.9 1.8 59 alkali silicate 10 Spraying very good Inv. Example 726 8.7 FC 117.54 1.23 10.5 0.9 64 alkyl silicate 125 Brushing very good Inv. Example 727 9.2 FC 7.81 1.47 2.9 0.7 66 alkali silicate 24 Brushing very good Inv. Example 728 17.8 FC 80.25 1.01 16.8 1.8 67 alkyl silicate 110 Brushing very good Inv. Example 729 20.2 FC 8.47 1.04 2.7 0.7 34 alkali silicate 24 Brushing very good Inv. Example 730 0.4 FC 0.87 1.05 0.04 0.7 54 alkyl silicate 2 Spraying very good Inv. Example 731 13.7 FC 25.78 1.12 0 0.04 62 alkali silicate 37 Spraying very good Inv. Example 732 14.7 FC 93.45 1.11 1.24 0.05 66 alkyl silicate 113 Brushing very good Inv. Example 733 2.4 FC 0.97 1.08 0.05 1.24 67 alkali silicate 2 Spraying very good Inv. Example 734 4.5 FC 54.89 1.47 1.24 0.06 68 alkyl silicate 75 Brushing very good Inv. Example 735 0.1 FC 10.81 1.50 1.24 0.07 33 alkali silicate 30 Brushing very good Inv. Example 736 30.0 FC 18.24 1.13 0 0.75 35 alkyl silicate 34 Brushing very good Inv. Example 737 24.5 FC 114.78 1.04 0.9 1.5 43 epoxy-based resin 124 Brushing very good Inv. Example 738 27.6 FC 3.87 1.02 0.03 1.3 44 acryl-based resin 15 Spraying very good Inv. Example 739 4.1 FC 11.94 1.08 10.5 1.8 43 urethane-based resin 23 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 22 Zn-Alloy Particle Properties Coat Properties Fracture Average Ratio of Metal Mg Facet &/or Mean Value of Al Si Particle in Coat Result of (mass Cracks Size Aspect (mass (mass Dry Coat Thickness Coating Corrosion %) (*1) (μm) Ratio %) %) (mass %) Base Resin (μm) Method Test Inv. Example 740 3.2 FC 142.58 1.15 2.9 0.9 44 polyester resin 157 Brushing very good Inv. Example 741 2.7 FC 12.5 1.34 16.8 0.7 54 epoxy-based resin 26 Spraying very good Inv. Example 742 0.12 FC 31.24 1.25 2.7 1.8 79 acryl-based resin 38 Spraying very good Inv. Example 743 0.22 FC 152.46 1.19 0.02 0.7 73 urethane-based resin 160 Brushing very good Inv. Example 744 0.37 FC 13.4 1.18 0 1.5 69 polyester resin 27 Brushing very good Inv. Example 745 1.4 FC 160.57 1.24 7.42 1.3 63 epoxy-based resin 180 Brushing very good Inv. Example 746 4.2 FC 14.1 1.11 0.02 1.8 35 acryl-based resin 26 Spraying very good Inv. Example 747 4.8 FC 167.55 1.27 0.04 0.9 35 urethane-based resin 180 Brushing very good Inv. Example 748 8.1 FC 1.45 1.31 17.5 0 66 polyester resin 15 Spraying very good Inv. Example 749 7.6 FC 0.15 1.26 0.01 1.8 67 epoxy-based resin 2 Spraying very good Inv. Example 750 9.9 FC 13.1 1.14 0.02 0.7 68 acryl-based resin 28 Spraying very good Inv. Example 751 14.8 FC 15.5 1.34 3.8 0 33 urethane-based resin 30 Spraying very good Inv. Example 752 16.7 FC 0.67 1.16 2.9 0 35 polyester resin 2 Spraying very good Inv. Example 753 17.9 FC 137.89 1.47 10.5 1.8 43 epoxy-based resin 157 Brushing very good Inv. Example 754 19.5 FC 16.3 1.48 2.9 0.9 44 acryl-based resin 28 Brushing very good Inv. Example 755 22.4 FC 110.38 1.49 16.8 0.7 42 urethane-based resin 130 Brushing very good Inv. Example 756 0.17 FC 12.4 1.34 2.7 1.8 33 polyester resin 29 Brushing very good Inv. Example 757 8.3 FC 17.2 1.29 0.02 0.7 30 epoxy-based resin 30 Brushing very good Inv. Example 758 6.5 FC 105.23 1.18 0.02 0.7 35 acryl-based resin 120 Brushing very good Inv. Example 759 9.7 FC 177.89 1.23 0.04 0.02 37 urethane-based resin 187 Brushing very good Inv. Example 760 11.4 FC 12.2 1.27 0.05 0.02 77 polyester resin 28 Spraying very good Inv. Example 761 22.5 FC 1.84 1.17 1.24 1.37 41 epoxy-based resin 5 Spraying very good Inv. Example 762 25.7 FC 16.02 1.16 0.05 0.02 35 acryl-based resin 35 Spraying very good Inv. Example 763 17.8 FC 1.75 1.49 1.24 1.37 58 urethane-based resin 5 Spraying very good Inv. Example 764 0.14 FC 198.78 1.34 1.24 1.37 37 polyester resin 200 Brushing very good Inv. Example 765 6.7 FC 13.1 1.16 0.8 1.5 68 alkali silicate 25 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 23 Zn-Alloy Particle Properties Coat Properties Fracture Average Ratio of Metal Mg Facet &/or Mean Value of Al Si Particle in Coat Result of (mass Cracks Size Aspect (mass (mass Dry Coat Thickness Coating Corrosion %) (*1) (μm) Ratio %) %) (mass %) Base Resin (μm) Method Test Inv. Example 766 7.5 FC 15.5 1.47 0.9 1.3 55 alkali silicate 15 Spraying very good Inv. Example 767 8.4 FC 0.67 1.48 1.1 1.8 77 alkyl silicate 20 Spraying very good Inv. Example 768 9.3 FC 12.2 1.49 1.8 0.9 43 alkali silicate 18 Spraying very good Inv. Example 769 1.4 FC 1.84 1.34 3.8 0.7 45 alkyl silicate 22 Spraying very good Inv. Example 770 4.2 FC 16.02 1.29 2.9 1.8 66 alkali silicate 19 Spraying very good Inv. Example 771 4.8 FC 1.75 1.18 10.5 0.7 33 alkyl silicate 29 Spraying very good Inv. Example 772 8.1 FC 12.4 1.23 2.9 1.5 66 alkali silicate 23 Spraying very good Inv. Example 773 7.6 FC 17.2 1.27 16.8 1.3 55 alkyl silicate 21 Spraying very good Inv. Example 774 9.9 FC 13.1 1.17 2.7 1.8 49 alkali silicate 19 Spraying very good Inv. Example 775 0.4 FC 29.9 1.16 3.6 0.9 77 alkyl silicate 15 Spraying very good Inv. Example 776 10.5 FC 0.21 1.27 0 0.7 41 alkali silicate 18 Spraying very good Inv. Example 777 0.4 FC 0.22 1.17 0.06 1.8 64 alkyl silicate 22 Spraying very good Inv. Example 778 10.5 FC 29.5 1.27 0.02 0.7 58 alkyl silicate 21 Spraying very good Inv. Example 779 0.51 FC 29.9 1.18 1.6 1.5 33 alkyl silicate 29 Spraying very good Inv. Example 780 9.8 FC 0.21 1.23 3.5 0 66 alkali silicate 23 Spraying very good Inv. Example 781 0.52 FC 0.22 1.27 9.8 1.8 55 alkyl silicate 21 Spraying very good Inv. Example 782 9.9 FC 29.5 1.17 11.5 0.9 49 alkali silicate 19 Spraying very good Inv. Example 783 14.8 FC 16.02 1.48 0.4 0.7 77 alkyl silicate 21 Spraying very good Inv. Example 784 16.7 FC 1.75 1.49 0.6 1.8 43 alkali silicate 19 Spraying very good Inv. Example 785 17.9 FC 12.4 1.34 10.6 0.7 45 alkyl silicate 15 Spraying very good Inv. Example 786 19.5 FC 17.2 1.29 9.5 0.7 66 alkali silicate 18 Spraying very good Comp. Example18 2.3 FC 205.6 1.23 0.07 0 75 alkyl silicate 25 Spraying poor Comp. Example19 2.3 FC 0.005 1.23 0 0.07 75 alkyl silicate 25 Spraying poor Comp. Example20 2.3 FC 205.6 1.23 0 0.02 75 alkyl silicate 105 Brushing poor Comp. Example21 2.3 FC 0.005 1.23 22.1 0 75 alkyl silicate 165 Spraying poor Comp. Example22 0.01 FC 0.4 1.24 1.2 0.5 58 acryl-based resin 5 Spraying poor (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 24 Zn-Alloy Particle Properties Coat Properties Fracture Average Ratio of Metal Mg Facet &/or Mean Value of Al Si Particle in Coat Result of (mass Cracks Size Aspect (mass (mass Dry Coat Thickness Coating Corrosion %) (*1) (μm) Ratio %) %) (mass %) Base Resin (μm) Method Test Comp. Example23 0.8 FC 3.2 2.54 0.6 0.8 64 urethane-based resin 2 Spraying poor Comp. Example24 8.47 NO 0.67 1.25 2 1.9 54 polyester resin 12 Brushing poor Comp. Example25 24.5 NO 2.5 1.05 0.8 0.9 32 epoxy-based resin 15 Brushing poor Comp. Example26 0.01 FC 0.4 1.24 0 0.02 57 alkali silicate 2 Spraying poor Comp. Example27 0.8 FC 0.2 1.78 25.8 0.05 70 alkyl silicate 5 Spraying poor Comp. Example28 8.47 NO 0.67 1.25 22.1 0 64 alkali silicate 12 Brushing poor Comp. Example29 24.5 NO 2.5 1.05 21.5 0.05 42 alkyl silicate 15 Brushing poor Comp. Example30 4.05 NO 0.02 1.23 0.05 2.29 38 alkali silicate 13 Brushing poor Comp. Example31 6.78 NO 12.5 1.35 0 0 44 alkyl silicate 22 Spraying poor Comp. Example32 15.8 NO 23.3 1.14 0 0 56 alkali silicate 34 Spraying poor Comp. Example33 4.5 FC 3.5 2.84 22.1 0 76 alkyl silicate 15 Brushing poor Comp. Example34 3.2 FC 6.7 1.75 0.05 2.29 65 alkyl silicate 15 Spraying poor Inv. Example 2072 0.05 FC 2.5 1.05 0 1.2 38 alkali silicate 19 Spraying very good Inv. Example 2073 0.07 FC 0.09 1.12 0 0.6 49 alkyl silicate 11 Spraying very good Inv. Example 2074 2.64 FC 5.5 1.22 0 0.01 43 alkyl silicate 16 Spraying very good Inv. Example 2075 0.08 FC 5.6 1.36 1.5 0 66 alkyl silicate 16 Brushing very good Inv. Example 2076 0.09 FC 11.5 1.11 5.5 1.6 67 alkali silicate 33 Brushing very good Inv. Example 2077 0.05 FC 19.5 1.07 4.5 0 54 alkyl silicate 8 Brushing good Inv. Example 2078 1.59 FC 6.7 1.14 0 0.1 76 alkyl silicate 5 Spraying very good Inv. Example 2079 2.58 FC 8.9 1.13 0.01 0 49 alkyl silicate 22 Spraying very good Inv. Example 2080 0.06 FC 8.32 1.22 3.2 0.9 32 alkyl silicate 23 Spraying very good Inv. Example 2081 0.18 FC 10.05 1.14 0 0.5 53 epoxy-based resin 30 Spraying very good Inv. Example 2082 7.55 FC 2.15 1.14 0.2 0.1 75 alkyl silicate 18 Spraying very good Inv. Example 2083 0.01 FC 0.06 1.23 1.2 0.6 75 alkali silicate 5 Spraying good Inv. Example 2084 8.01 FC 2.54 1.13 0.5 0 73 alkyl silicate 16 Spraying very good Inv. Example 2085 1.06 FC 3.4 1.38 1.5 0.9 49 alkyl silicate 8 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 25 Zn-Alloy Particle Properties Coat Properties Fracture Average Ratio of Metal Mg Facet &/or Mean Value of Al Si Particle in Coat Result of (mass Cracks Size Aspect (mass (mass Dry Coat Thickness Coating Corrosion %) (*1) (μm) Ratio %) %) (mass %) Base Resin (μm) Method Test Inv. Example 2086 0.04 FC 8.5 1.42 0 1.2 40 alkali silicate 2 Spraying very good Inv. Example 2087 0.06 FC 7.72 1.38 0 0.6 36 alkyl silicate 18 Spraying very good Inv. Example 2088 9.51 FC 2.77 1.38 0 0.01 55 alkyl silicate 5 Spraying very good Inv. Example 2089 10.01 FC 3.68 1.22 1.5 0 48 alkyl silicate 22 Spraying very good Inv. Example 2090 0.05 FC 10.6 1.13 5.5 1.6 67 acryl-based resin 77 Brushing very good Inv. Example 2091 0.07 FC 5.7 1.02 4.5 0 72 urethane-based resin 54 Brushing very good Inv. Example 2092 3.54 FC 5.5 1.22 0 0.1 78 alkyl silicate 18 Spraying very good Inv. Example 2093 0.08 FC 3.2 1.05 0.01 0 34 epoxy-based resin 43 Spraying very good Inv. Example 2094 0.09 FC 4.5 1.24 3.2 0.9 43 acryl-based resin 52 Brushing very good Inv. Example 2095 5.22 FC 2.54 1.14 0 0.5 45 alkyl silicate 19 Spraying very good Inv. Example 2096 4.05 FC 2.06 1.13 0.2 0.1 52 alkyl silicate 8 Spraying very good Inv. Example 2097 8.57 FC 4.99 1.02 1.2 0.6 61 alkyl silicate 16 Spraying very good Inv. Example 2098 0.01 FC 6.4 1.06 0.5 0 77 polyester resin 47 Spraying very good Inv. Example 2099 4.59 FC 3.09 1.07 1.5 0.9 49 alkyl silicate 22 Spraying very good Inv. Example 2100 9.88 FC 4.66 1.42 0 1.2 79 alkyl silicate 18 Spraying very good Inv. Example 2101 4.55 FC 4.09 1.38 0 0.6 76 alkyl silicate 18 Spraying very good Inv. Example 2102 2.36 FC 3.99 1.22 0 0.01 80 alkyl silicate 21 Spraying very good Inv. Example 2103 0.05 FC 7.72 1.38 1.5 0 36 alkyl silicate 19 Brushing very good Inv. Example 2104 0.04 FC 8.32 1.22 5.5 1.6 32 alkyl silicate 24 Spraying very good Inv. Example 2105 2.64 FC 4.55 1.11 4.5 0 43 alkyl silicate 5 Spraying very good Inv. Example 2106 0.06 FC 10.6 1.13 0 0.1 67 alkyl silicate 7 Spraying very good Inv. Example 2107 0.18 FC 5.7 1.02 0.01 0 72 epoxy-based resin 100 Spraying very good Inv. Example 2108 6.31 FC 3.52 1.27 3.2 0.9 51 alkyl silicate 21 Spraying very good Inv. Example 2109 5..22 FC 3.55 1.12 0 0.5 55 alkyl silicate 19 Spraying very good Inv. Example 2110 4.01 FC 2.64 1.23 0.2 0.1 40 alkyl silicate 8 Spraying very good Inv. Example 2111 3.52 FC 3.15 1.36 1.2 0.6 51 alkyl silicate 16 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 26 Zn-Alloy Particle Properties Coat Properties Fracture Average Ratio of Metal Mg Facet &/or Mean Value of Al Si Particle in Coat Result of (mass Cracks Size Aspect (mass (mass Dry Coat Thickness Coating Corrosion %) (*1) (μm) Ratio %) %) (mass %) Base Resin (μm) Method Test Inv. Example 2112 0.05 FC 5.2 1.33 0.5 0 53 urethane-based resin 20 Brushing very good Inv. Example 2113 0.04 FC 1.9 1.27 1.5 0.9 60 polyester resin 200 Brushing very good Inv. Example 2114 0.06 FC 10.5 1.12 0 1.2 77 alkyl silicate 25 Spraying very good Inv. Example 2115 0.05 FC 12.5 1.23 0 0.6 43 alkali silicate 14 Spraying very good Inv. Example 2116 0.07 FC 18.5 1.36 0 0.01 52 urethane-based resin 112 Spraying very good Inv. Example 2117 0.01 FC 11.5 1.11 1.5 0 66 alkali silicate 24 Spraying very good Inv. Example 2118 0.08 FC 9.6 1.07 5.5 1.6 72 urethane-based resin 150 Spraying very good Inv. Example 2119 0.09 FC 8.5 1.42 4.5 0 40 alkali silicate 18 Spraying very good Inv. Example 2120 4.25 FC 2.36 1.33 0 0.1 44 alkyl silicate 18 Spraying very good Inv. Example 2121 0.04 FC 23.5 1.42 0.01 0 44 alkali silicate 38 Spraying very good Inv. Example 2122 0.06 FC 101.5 1.38 3.2 0.9 36 alkyl silicate 18 Spraying very good Inv. Example 2123 0.06 FC 55.4 1.38 0 0.5 76 alkyl silicate 10 Spraying very good Inv. Example 2124 0.07 FC 10.5 1.12 0.2 0.1 77 alkyl silicate 37 Spraying very good Inv. Example 2125 0.01 FC 12.5 1.23 1.2 0.6 43 alkali silicate 2 Spraying good Inv. Example 2126 0.08 FC 18.5 1.36 0.5 0 52 alkyl silicate 160 Brushing very good Inv. Example 2127 0.09 FC 11.5 1.11 1.5 0.9 66 alkali silicate 5 Brushing very good Inv. Example 2128 0.05 FC 9.6 1.07 0.5 0 72 alkyl silicate 56 Brushing very good Inv. Example 2129 0.06 FC 10.05 1.14 1.5 0.9 53 urethane-based resin 99 Spraying very good Inv. Example 2130 29.9 FC 10.5 1.36 0 0 55 urethane-based resin 700 Spraying very good Inv. Example 2131 16.5 FC 7.5 1.11 0.01 0 47 alkyl silicate 554 Spraying very good Inv. Example 2132 12.5 FC 2.6 1.07 3.2 0.9 79 urethane-based resin 688 Brushing very good Inv. Example 2133 9.8 FC 3.5 1.42 0 0.5 42 urethane-based resin 421 Spraying very good Inv. Example 2134 9.6 FC 4.5 1.33 0.2 0.1 36 urethane-based resin 651 Spraying very good Inv. Example 2135 7.5 FC 1.6 1.42 0 0.5 53 urethane-based resin 402 Brushing very good Inv. Example 2136 4.6 FC 2.5 1.12 5.8 0.1 55 alkali silicate 354 Spraying very good Inv. Example 2137 3.8 FC 23.5 1.23 1.2 0.6 42 urethane-based resin 504 Brushing very good Inv. Example 2138 0.05 FC 9.8 1.27 15.5 0 76 urethane-based resin 666 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

Example 3

Zn alloy particles with the chemical ingredients shown in Tables 27 to 42 were produced in the same way as in Example 1. The rest is the same as Example 1.

The Mg solid solution phase was identified by the X-ray diffraction method. Further, the Zn—Mg intermetallic compounds were identified by analysis of the ratio of composition of the Mg and Zn at the physical fracture facets or crack surfaces by the X-ray diffraction method or by observation by a scanning electron microscopy with an energy dispersion type X-ray analyzer.

When the content of Mg was less than 16 mass %, at the detected X-ray diffraction peaks, the Mg₂Zn₁₁ or MgZn₂ peaks were the main peaks. When the content of Mg was 16 mass % or more, the ratio of composition of the Mg and Zn at the physical fracture facets or crack surfaces was analyzed by the X-ray diffraction method or by observation by a scanning electron microscopy with an energy dispersion type X-ray analyzer whereupon the presence of Mg₂Zn₃, MgZn, or Mg₇Zn₃ was confirmed.

From Tables 27 to 42, it is learned that due to the presence of the Mg solid solution phase and Zn—Mg intermetallic compounds at the surfaces of the particles including fractured parts, the painting test pieces using the Zn alloy particles of the present invention are improved in corrosion resistance and rust protection regardless of the type of base resin, that is, both for inorganic-based and organic-based binders.

TABLE 27 Zn-Alloy Particle Properties Coat Properties Mg Solid- Ratio Solution of Phase & Metal Zn—Mg Par- Inter- ticle Fracture Average metallic in Facet Value Compounds Dry Coat Mg &/or Mean of Al Si on Coat Thick- Result of (mass Cracks Size Aspect (mass (mass Surface of MgZn₂ or (mass ness Coating Corrosion %) (*1) (μm) Ratio %) %) Particles Mg₂Zn₁₁ %) Base Resin (μm) Method Test Inv. Example 87 17.3 F 29.24 1.37 11.4 0.24 Existence No 30 alkali silicate 30 Spraying very good Inv. Example 88 18.5 F 1.28 1.10 0.04 0.03 Existence No 80 alkyl silicate 5 Spraying very good Inv. Example 89 19.3 F 33.57 1.04 0.25 0.07 Existence No 35 alkali silicate 57 Brushing very good Inv. Example 90 3.5 F 3.04 1.02 5.43 0.65 Existence No 43 alkyl silicate 12 Brushing very good Inv. Example 91 22.5 F 7.54 1.01 17.5 2.41 Existence No 55 alkali silicate 15 Spraying very good Inv. Example 92 23.7 F 68.12 1.08 0.01 0.08 Existence No 76 alkyl silicate 85 Brushing very good Inv. Example 93 24.2 F 0.52 1.14 0.02 2.23 Existence No 65 alkali silicate 2 Spraying very good Inv. Example 94 0.2 F 0.12 1.23 0.02 0.06 Existence No 73 alkyl silicate 2 Spraying very good Inv. Example 95 27.1 F 58.74 1.33 0.04 0.02 Existence No 54 alkali silicate 70 Brushing very good Inv. Example 96 29.3 F 13.57 1.37 0.05 0.02 Existence No 62 alkyl silicate 30 Spraying very good Inv. Example 97 0.5 F 6.4 1.44 1.24 1.37 Existence No 57 alkali silicate 15 Spraying very good Inv. Example 98 2.7 F 41.23 1.21 27.5 2.43 Existence No 32 alkyl silicate 64 Brushing very good Inv. Example 99 28.4 F 0.72 1.22 0.01 0.02 Existence No 43 alkali silicate 2 Spraying very good Inv. Example 100 8.7 F 1.18 1.23 0.01 0.01 Existence No 44 alkyl silicate 5 Spraying very good Inv. Example 101 9.2 F 7.12 1.47 0.02 0.05 Existence No 54 alkali silicate 15 Brushing very good Inv. Example 102 17.8 F 8.01 1.01 0.03 0.04 Existence No 79 alkyl silicate 20 Brushing very good Inv. Example 103 20.2 F 0.84 1.04 7.78 0.24 Existence No 73 alkali silicate 2 Brushing very good Inv. Example 104 0.4 F 87.65 1.05 0.04 0.06 Existence No 69 alkyl silicate 100 Brushing very good Inv. Example 105 13.7 F 2.59 1.12 11.21 0.74 Existence No 63 alkali silicate 5 Spraying very good Inv. Example 106 14.7 F 93.45 1.11 0.09 0.01 Existence No 35 alkyl silicate 110 Brushing very good Inv. Example 107 2.4 F 9.84 1.08 5.41 1.27 Existence No 35 alkali silicate 23 Spraying very good Inv. Example 108 4.5 F 5.45 1.47 0.02 0.03 Existence No 72 alkyl silicate 15 Spraying very good Inv. Example 109 0.1 F 1.08 1.50 0.02 0.07 Existence No 46 alkali silicate 5 Spraying good Inv. Example 110 30.0 F 180.24 1.13 0.03 0.08 Existence Existence 34 alkyl silicate 200 Brushing very good Inv. Example 111 24.5 F 11.4 1.04 11.04 0.21 Existence Existence 32 alkali silicate 32 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 28 Zn-Alloy Particle Properties Coat Properties Mg Solid- Ratio Solution of Phase & Metal Zn—Mg Par- Aver- Inter- ti- age metallic cle Fracture Value Com- in Facet of pounds Dry Coat Mg &/or Mean As- Al Si on Coat Thick- Result of (mass Cracks Size pect (mass (mass Surface of MgZn₂ or (mass ness Coating Corrosion %) (*1) (μm) Ratio %) %) Particles Mg₂Zn₁₁ %) Base Resin (μm) Method Test Inv. Example 112 27.6 F 38.75 1.02 0.01 0.02 Existence Existence 45 alkyl silicate 54 Brushing very good Inv. Example 113 4.1 F 119.87 1.08 0.07 0.04 Existence Existence 47 alkali silicate 56 Brushing very good Inv. Example 114 3.2 F 1.42 1.15 0.08 0.01 Existence Existence 74 alkyl silicate 130 Brushing very good Inv. Example 115 2.7 F 12.5 1.34 0.04 0.03 Existence Existence 77 alkali silicate 22 Spraying very good Inv. Example 116 0.12 F 31.24 1.25 0.02 0.04 Existence Existence 34 alkyl silicate 43 Spraying very good Inv. Example 117 0.22 F 152.46 1.19 0.02 0.02 Existence Existence 42 epoxy-based resin 160 Brushing very good Inv. Example 118 0.37 F 13.4 1.18 4.12 0.61 Existence Existence 46 acryl-based resin 27 Spraying good Inv. Example 119 1.4 F 1.61 1.24 0.05 0.02 Existence Existence 47 urethane-based 5 Spraying good resin Inv. Example 120 4.2 F 14.1 1.11 2.14 0.74 Existence Existence 34 polyester resin 27 Spraying very good Inv. Example 121 4.8 F 1.67 1.27 0.03 0.02 Existence Existence 54 epoxy-based resin 5 Brushing very good Inv. Example 122 8.1 F 1.45 1.31 0.03 0.04 Existence Existence 62 acryl-based resin 5 Brushing very good Inv. Example 123 7.6 F 14.8 1.26 0.04 0.05 Existence Existence 66 urethane-based 34 Brushing very good resin Inv. Example 124 9.9 F 1.31 1.14 7.54 1.24 Existence Existence 67 polyester resin 5 Spraying very good Inv. Example 125 14.8 F 15.5 1.34 0.08 0.06 Existence Existence 68 epoxy-based resin 23 Spraying very good Inv. Example 126 16.7 F 0.67 1.16 0.01 0.07 Existence Existence 33 acryl-based resin 2 Spraying very good Inv. Example 127 17.9 F 137.89 1.47 29.8 0.75 Existence Existence 35 urethane-based 150 Brushing very good resin Inv. Example 128 19.5 F 1.63 1.48 0.01 0.02 Existence Existence 43 polyester resin 5 Brushing very good Inv. Example 129 22.4 F 1.12 1.49 0.03 0.01 Existence Existence 44 epoxy-based resin 3 Spraying very good Inv. Example 130 0.17 F 169.88 1.34 0.02 0.01 Existence Existence 42 acryl-based resin 180 Brushing very good Inv. Example 131 8.3 F 1.72 1.29 8.04 1.24 Existence Existence 33 urethane-based 5 Spraying very good resin Inv. Example 132 6.5 F 10.5 1.18 0.06 0.04 Existence Existence 30 polyester resin 23 Spraying very good Inv. Example 133 9.7 F 17.7 1.23 0.08 0.02 Existence Existence 35 epoxy-based resin 34 Brushing very good Inv. Example 134 11.4 F 122.54 1.27 0.03 0.01 Existence Existence 37 acryl-based resin 140 Brushing very good Inv. Example 135 22.5 F 1.84 1.17 0.04 0.03 Existence Existence 38 urethane-based 5 Brushing very good resin Inv. Example 136 25.7 F 19.1 1.16 7.42 1.22 Existence Existence 49 polyester resin 34 Spraying very good Inv. Example 137 17.8 F 1.75 1.49 0.02 0.01 Existence Existence 33 epoxy-based resin 5 Spraying very good Inv. Example 138 0.14 F 198.78 1.34 0.08 0.02 Existence Existence 53 acryl-based resin 200 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 29 Zn-Alloy Particle Properties Coat Properties Mg Solid- Ratio Solution of Phase & Metal Zn—Mg Par- Aver- Inter- ti- age metallic cle Fracture Value Com- in Facet of pounds Dry Coat Mg &/or Mean As- Al Si on Coat Thick- Result of (mass Cracks Size pect (mass (mass Surface of MgZn₂ or (mass ness Coating Corrosion %) (*1) (μm) Ratio %) %) Particles Mg₂Zn₁₁ %) Base Resin (μm) Method Test Inv. Example 787 0.15 FC 0.02 1.05 0.1 0.07 Existence Existence 35 alkali silicate 2 Spraying very good Inv. Example 788 0.19 FC 10.5 1.12 0.04 0.1 Existence Existence 77 alkyl silicate 37 Spraying very good Inv. Example 789 0.18 FC 12.5 1.23 30.0 0.01 Existence No 43 alkali silicate 2 Spraying good Inv. Example 790 0.11 FC 18.5 1.36 0.02 3 Existence Existence 52 alkyl silicate 160 Brushing very good Inv. Example 791 0.15 FC 11.5 1.11 0 0 Existence No 66 alkali silicate 5 Brushing very good Inv. Example 792 0.24 FC 9.6 1.07 0 0 Existence Existence 72 alkyl silicate 56 Brushing very good Inv. Example 793 0.18 FC 8.5 1.42 10.4 0.57 Existence No 40 alkali silicate 2 Spraying very good Inv. Example 794 0.12 FC 7.72 1.38 4.65 2.67 Existence Existence 36 alkyl silicate 18 Spraying very good Inv. Example 795 0.19 FC 8.32 1.22 24.8 2.4 Existence No 32 alkyl silicate 23 Spraying very good Inv. Example 796 0.18 FC 10.05 1.14 4.52 0.57 Existence No 53 epoxy-based resin 30 Brushing very good Inv. Example 797 0.21 FC 10.6 1.13 17.5 2.45 Existence Existence 67 acryl-based resin 77 Brushing very good Inv. Example 798 0.76 FC 5.7 1.02 0 0 Existence No 72 urethane-based 54 Brushing very good resin Inv. Example 799 0.11 FC 6.4 1.06 11.05 0.23 Existence Existence 77 polyester resin 47 Spraying very good Inv. Example 800 0.14 FC 3.2 1.05 2.65 0.74 Existence Existence 34 epoxy-based resin 43 Spraying very good Inv. Example 801 15 FC 4.5 1.24 6.45 2.14 Existence No 43 acryl-based resin 52 Brushing very good Inv. Example 802 14.5 FC 5.2 1.33 0 0 Existence No 53 urethane-based 20 Brushing very good resin Inv. Example 803 18.5 FC 1.9 1.27 0 0 Existence Existence 60 polyester resin 200 Brushing very good Inv. Example 804 15.1 FC 0.02 1.05 0.05 0.03 Existence No 35 alkali silicate 22 Spraying very good Inv. Example 805 15.6 FC 10.5 1.12 0 0.08 Existence No 77 alkyl silicate 25 Spraying very good Inv. Example 806 12.5 FC 12.5 1.23 0.05 0 Existence Existence 43 alkali silicate 14 Spraying very good Inv. Example 807 18.7 FC 18.5 1.36 0.44 0.07 Existence Existence 52 urethane-based 112 Spraying very good resin Inv. Example 808 14.5 FC 11.5 1.11 0.08 0.07 Existence Existence 66 alkali silicate 24 Spraying very good Inv. Example 809 7.5 FC 9.6 1.07 0.1 0.2 Existence No 72 urethane-based 150 Spraying very good resin Inv. Example 810 4.5 FC 8.5 1.42 0 0 Existence Existence 40 alkali silicate 18 Spraying very good Inv. Example 811 1.5 FC 7.72 1.38 0 0 Existence Existence 36 alkyl silicate 19 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 30 Zn-Alloy Particle Properties Coat Properties Mg Solid- Ratio Solution of Phase & Metal Zn—Mg Par- Aver- Inter- ti- age metallic cle Fracture Value Com- in Facet of pounds Dry Coat Mg &/or Mean As- Al Si on Coat Thick- Result of (mass Cracks Size pect (mass (mass Surface of MgZn₂ or (mass ness Coating Corrosion %) (*1) (μm) Ratio %) %) Particles Mg₂Zn₁₁ %) Base Resin (μm) Method Test Inv. Example 812 4.8 FC 8.32 1.22 0 0.07 Existence Existence 32 alkyl silicate 24 Spraying very good Inv. Example 813 9.6 FC 10.05 1.14 0 0.02 Existence No 53 urethane-based 99 Spraying very good resin Inv. Example 814 11.5 FC 10.6 1.13 25.8 0.05 Existence Existence 67 alkyl silicate 7 Spraying very good Inv. Example 815 9.8 FC 5.7 1.02 22.1 0 Existence Existence 72 epoxy-based resin 100 Spraying very good Inv. Example 816 7.6 FC 6.4 1.06 21.5 0.05 Existence Existence 77 alkyl silicate 27 Brushing very good Inv. Example 817 3.2 FC 3.2 1.05 0.05 2.29 Existence No 34 alkyl silicate 15 Spraying very good Inv. Example 818 1.9 FC 4.5 1.24 0.05 0.03 Existence Existence 43 alkyl silicate 14 Spraying very good Inv. Example 819 11.5 FC 5.2 1.33 0 0.08 Existence Existence 53 urethane-based 55 Spraying very good resin Inv. Example 820 8.7 FC 1.9 1.27 0 0 Existence No 35 alkyl silicate 8 Spraying very good Inv. Example 821 9.6 FC 0.02 1.05 0 0 Existence Existence 77 urethane-based 122 Brushing very good resin Inv. Example 822 9.4 FC 10.5 1.12 0.08 0.07 Existence No 43 alkyl silicate 54 Spraying very good Inv. Example 823 10.5 FC 12.5 1.23 0.1 0.2 Existence Existence 52 alkyl silicate 19 Spraying very good Inv. Example 824 12.6 FC 18.5 1.36 0.05 0.2 Existence No 66 alkyl silicate 25 Brushing very good Inv. Example 825 29.5 FC 11.5 1.11 0.07 0 Existence Existence 72 alkyl silicate 58 Spraying very good Inv. Example 826 29.4 FC 9.6 1.07 0 0.07 Existence Existence 40 alkyl silicate 21 Spraying very good Inv. Example 827 27.5 FC 8.5 1.42 0 0.02 Existence Existence 36 alkyl silicate 19 Brushing very good Inv. Example 828 0.8 FC 7.72 1.38 25.8 0.05 Existence Existence 32 urethane-based 56 Spraying very good resin Inv. Example 829 1.6 FC 8.32 1.22 22.1 0 Existence No 53 alkyl silicate 77 Spraying very good Inv. Example 830 22.9 FC 10.05 1.14 21.5 0.05 Existence No 67 alkyl silicate 54 Spraying very good Inv. Example 831 28.5 FC 10.6 1.13 0.05 2.29 Existence No 72 alkyl silicate 64 Spraying very good Inv. Example 832 29.5 FC 5.7 1.02 0.1 0.2 Existence Existence 77 alkyl silicate 34 Brushing very good Inv. Example 833 18.7 FC 6.4 1.06 0.05 0.2 Existence No 34 alkyl silicate 28 Spraying very good Inv. Example 834 19.5 FC 3.2 1.05 0.07 0 Existence Existence 43 urethane-based 109 Brushing very good resin Inv. Example 835 20.4 FC 4.5 1.24 0 0.07 Existence Existence 53 alkyl silicate 15 Spraying very good Inv. Example 836 0.6 FC 5.2 1.33 0 0.02 Existence Existence 72 alkyl silicate 14 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 31 Zn-Alloy Particle Properties Coat Properties Mg Solid- Ratio Solution of Phase & Metal Zn—Mg Par- Aver- Inter- ti- age metallic cle Fracture Value Com- in Facet of pounds Dry Coat Mg &/or Mean As- Al Si on Coat Thick- Result of (mass Cracks Size pect (mass (mass Surface of MgZn₂ or (mass ness Coating Corrosion %) (*1) (μm) Ratio %) %) Particles Mg₂Zn₁₁ %) Base Resin (μm) Method Test Inv. Example 837 0.8 FC 1.9 1.27 22.1 0 Existence Existence 77 alkyl silicate 18 Spraying very good Inv. Example 838 22.5 FC 0.02 1.05 0.1 0.07 Existence Existence 35 alkali silicate 2 Spraying very good Inv. Example 839 20.6 FC 10.5 1.12 0.04 0.1 Existence Existence 77 alkyl silicate 37 Spraying very good Inv. Example 840 21.6 FC 12.5 1.23 30.0 0.01 Existence No 43 alkali silicate 2 Spraying good Inv. Example 841 20.8 FC 7.72 1.38 0 0 Existence Existence 52 alkyl silicate 160 Brushing very good Inv. Example 842 23.6 FC 8.32 1.22 0 0 Existence Existence 66 alkali silicate 5 Brushing very good Inv. Example 843 24.5 FC 10.05 1.14 4.52 0.57 Existence No 72 alkyl silicate 56 Brushing very good Inv. Example 844 18.6 FC 10.6 1.13 17.5 2.45 Existence Existence 40 alkali silicate 2 Spraying very good Inv. Example 845 17.8 FC 5.2 1.33 27.6 2.4 Existence No 36 alkyl silicate 18 Spraying very good Inv. Example 846 16.5 FC 1.9 1.27 4.32 1.07 Existence Existence 32 alkyl silicate 23 Spraying very good Inv. Example 847 14.5 FC 0.02 1.05 0.05 0.03 Existence No 53 epoxy-based resin 30 Brushing very good Inv. Example 848 19 FC 10.5 1.12 0 0.08 Existence No 67 acryl-based resin 77 Brushing very good Inv. Example 849 15 FC 12.5 1.23 0.05 0 Existence Existence 72 urethane-based 54 Brushing very good resin Inv. Example 850 16.4 FC 18.5 1.36 0.44 0.07 Existence Existence 77 polyester resin 47 Spraying very good Inv. Example 851 13.5 FC 11.5 1.11 0.08 0.07 Existence Existence 34 epoxy-based resin 43 Spraying very good Inv. Example 852 10.6 FC 11.5 1.11 8.02 2.04 Existence No 43 acryl-based resin 52 Brushing very good Inv. Example 853 10.7 FC 9.6 1.07 15.6 1.27 Existence Existence 53 urethane-based 20 Brushing very good resin Inv. Example 854 10.9 FC 8.5 1.42 10.4 0.57 Existence No 60 polyester resin 200 Brushing very good Inv. Example 855 11.6 FC 7.72 1.38 4.65 2.67 Existence Existence 35 alkali silicate 22 Spraying very good Inv. Example 856 14.7 FC 8.32 1.22 24.8 2.4 Existence No 77 alkyl silicate 25 Spraying very good Inv. Example 857 19.5 FC 10.05 1.14 4.52 0.57 Existence No 43 alkali silicate 14 Spraying very good Inv. Example 858 10.2 FC 10.6 1.13 0 0 Existence Existence 52 urethane-based 112 Spraying very good resin Inv. Example 859 4 FC 5.7 1.02 0 0 Existence No 66 alkali silicate 24 Spraying very good Inv. Example 860 7.2 FC 6.4 1.06 11.05 0.23 Existence Existence 72 urethane-based 150 Spraying very good resin Inv. Example 861 3.6 FC 3.2 1.05 2.65 0.74 Existence Existence 40 alkali silicate 18 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 32 Zn-Alloy Particle Properties Coat Properties Mg Solid- Ratio Solution of Phase & Metal Zn—Mg Par- Aver- Inter- ti- age metallic cle Fracture Value Com- in Facet of pounds Dry Coat Mg &/or Mean As- Al Si on Coat Thick- Result of (mass Cracks Size pect (mass (mass Surface of MgZn₂ or (mass ness Coating Corrosion %) (*1) (μm) Ratio %) %) Particles Mg₂Zn₁₁ %) Base Resin (μm) Method Test Inv. Example 862 26.9 FC 4.5 1.24 6.45 2.14 Existence No 36 alkyl silicate 19 Brushing very good Inv. Example 863 27.9 FC 5.2 1.33 27.6 2.4 Existence No 32 alkyl silicate 24 Spraying very good Inv. Example 864 28.9 FC 1.9 1.27 4.32 1.07 Existence Existence 53 urethane-based 99 Spraying very good resin Inv. Example 865 23.8 FC 0.02 1.05 0.05 0.03 Existence No 67 alkyl silicate 7 Spraying very good Inv. Example 866 26.8 FC 10.5 1.12 0 0.08 Existence No 72 epoxy-based resin 100 Spraying very good Inv. Example 867 25.6 FC 12.5 1.23 0.05 0 Existence Existence 77 alkyl silicate 27 Brushing very good Inv. Example 868 29.8 FC 18.5 1.36 0.44 0.07 Existence Existence 34 alkali silicate 15 Spraying very good Inv. Example 869 18.9 FC 11.5 1.11 0.08 0.07 Existence Existence 43 alkyl silicate 14 Spraying very good Inv. Example 870 5.6 FC 9.6 1.07 0.1 0.2 Existence No 53 urethane-based 55 Spraying very good resin Inv. Example 871 4.7 FC 8.5 1.42 0.05 0.2 Existence Existence 35 alkyl silicate 8 Spraying very good Inv. Example 872 6.8 FC 7.72 1.38 0.07 0 Existence Existence 77 urethane-based 122 Brushing very good resin Inv. Example 873 9 FC 8.32 1.22 0 0.07 Existence Existence 43 alkyl silicate 54 Spraying very good Inv. Example 874 2.1 FC 10.05 1.14 0 0.02 Existence No 52 alkali silicate 19 Spraying very good Inv. Example 875 4.8 FC 10.6 1.13 0 0 Existence Existence 66 alkyl silicate 25 Brushing very good Inv. Example 876 4.2 FC 5.7 1.02 0 0 Existence Existence 72 alkyl silicate 58 Spraying very good Inv. Example 877 4.3 FC 6.4 1.06 21.5 0.05 Existence Existence 40 alkyl silicate 21 Spraying very good Inv. Example 878 4 FC 3.2 1.05 0.05 2.29 Existence No 36 alkali silicate 19 Brushing very good Inv. Example 879 3.7 FC 4.5 1.24 0.05 0.03 Existence Existence 32 urethane-based 56 Spraying very good resin Inv. Example 880 6.4 FC 5.2 1.33 0 0.08 Existence Existence 53 alkyl silicate 77 Spraying very good Inv. Example 881 6.9 FC 1.9 1.27 0.05 0 Existence No 67 alkyl silicate 54 Spraying very good Inv. Example 882 16.9 FC 0.02 1.05 0.44 0.07 Existence Existence 72 alkyl silicate 64 Spraying very good Inv. Example 883 18.7 FC 10.5 1.12 0.08 0.07 Existence No 77 alkyl silicate 34 Brushing very good Inv. Example 884 24.4 FC 12.5 1.23 0.1 0.2 Existence Existence 34 alkali silicate 28 Spraying very good Inv. Example 885 10.6 FC 18.5 1.36 0 0 Existence No 43 urethane-based 109 Brushing very good resin Inv. Example 886 15.8 FC 11.5 1.11 0 0 Existence Existence 53 alkyl silicate 15 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 33 Zn-Alloy Particle Properties Coat Properties Mg Solid- Ratio Solution of Phase & Metal Zn—Mg Par- Aver- Inter- ti- age metallic cle Fracture Value Com- in Facet of pounds Dry Coat Mg &/or Mean As- Al Si on Coat Thick- Result of (mass Cracks Size pect (mass (mass Surface of MgZn₂ or (mass ness Coating Corrosion %) (*1) (μm) Ratio %) %) Particles Mg₂Zn₁₁ %) Base Resin (μm) Method Test Inv. Example 887 19.5 FC 9.6 1.07 0 0.07 Existence Existence 72 alkyl silicate 14 Spraying very good Inv. Example 888 7.8 FC 8.5 1.42 0 0.02 Existence Existence 77 alkyl silicate 18 Spraying very good Inv. Example 889 4.9 FC 7.72 1.38 25.8 0.05 Existence Existence 77 urethane-based 122 Brushing very good resin Inv. Example 890 10.8 FC 8.32 1.22 22.1 0 Existence No 43 alkyl silicate 54 Spraying very good Inv. Example 891 3.8 FC 10.05 1.14 21.5 0.05 Existence No 52 alkali silicate 19 Spraying very good Inv. Example 892 22.6 FC 10.6 1.13 0.05 2.29 Existence No 66 alkyl silicate 25 Brushing very good Inv. Example 893 27.9 FC 5.7 1.02 0 0 Existence Existence 72 alkyl silicate 58 Spraying very good Inv. Example 894 24.8 FC 6.4 1.06 0 0 Existence No 40 alkyl silicate 21 Spraying very good Inv. Example 895 26.8 FC 3.2 1.05 0.07 0 Existence Existence 36 alkali silicate 19 Brushing very good Inv. Example 896 25.9 FC 4.5 1.24 0 0.07 Existence Existence 32 urethane-based 56 Spraying very good resin Inv. Example 897 9.8 FC 5.2 1.33 0 0.02 Existence Existence 53 alkyl silicate 77 Spraying very good Inv. Example 898 5.6 FC 1.9 1.27 22.1 0 Existence Existence 67 alkyl silicate 54 Spraying very good Inv. Example 899 12.3 FC 0.02 1.05 1.24 1.8 Existence Existence 52 alkali silicate 2 Spraying very good Inv. Example 900 0.8 FC 27.89 1.12 1.24 0.9 Existence Existence 55 alkali silicate 20 Spraying very good Inv. Example 901 1 FC 0.32 1.23 0.8 0.7 Existence No 69 alkali silicate 5 Spraying very good Inv. Example 902 2.3 FC 11.44 1.36 0 1.8 Existence Existence 78 alkyl silicate 20 Spraying very good Inv. Example 903 15.6 FC 1.05 1.11 1.1 2.41 Existence Existence 42 alkali silicate 15 Brushing very good Inv. Example 904 6.7 FC 36.47 1.07 1.8 0.08 Existence Existence 32 alkyl silicate 57 Brushing very good Inv. Example 905 7.5 FC 5.07 1.42 3.8 2.23 Existence No 66 alkali silicate 13 Brushing very good Inv. Example 906 8.4 FC 7.72 1.38 2.9 0.06 Existence Existence 67 alkyl silicate 22 Brushing very good Inv. Example 907 9.3 FC 8.32 1.22 10.5 0.02 Existence Existence 64 alkali silicate 20 Spraying very good Inv. Example 908 10.4 FC 10.05 1.14 2.9 0.02 Existence Existence 74 alkyl silicate 27 Spraying very good Inv. Example 909 11.2 FC 6.08 1.13 16.8 1.37 Existence No 82 alkali silicate 15 Spraying very good Inv. Example 910 11.7 FC 17.89 1.02 0 2.43 Existence Existence 37 alkyl silicate 35 Spraying very good Inv. Example 911 21.5 FC 19.54 1.06 3.6 0.02 Existence Existence 42 alkali silicate 34 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 34 Zn-Alloy Particle Properties Coat Properties Mg Solid- Ratio Solution of Phase & Metal Zn—Mg Par- Inter- ticle Fracture Average metallic in Facet Value Compounds Dry Coat Mg &/or Mean of Al Si on Coat Thick- Result of (mass Cracks Size Aspect (mass (mass Surface of MgZn₂ or (mass ness Coating Corrosion %) (*1) (μm) Ratio %) %) Particles Mg₂Zn₁₁ %) Base Resin (μm) Method Test Inv. Example 912 13.4 FC 21.08 1.05 2.1 1.5 Existence No 66 alkyl silicate 45 Brushing very good Inv. Example 913 14.6 FC 23.04 1.24 0.06 1.3 Existence Existence 48 alkali silicate 52 Brushing very good Inv. Example 914 25.8 FC 9.21 1.33 0.02 1.8 Existence Existence 33 alkyl silicate 23 Brushing very good Inv. Example 915 16.7 FC 0.12 1.27 1.6 0.9 Existence Existence 75 alkali silicate 5 Spraying very good Inv. Example 916 17.3 FC 29.24 1.37 3.5 0 Existence Existence 77 alkyl silicate 52 Brushing very good Inv. Example 917 18.5 FC 128.74 1.10 9.8 1.8 Existence No 66 alkali silicate 150 Brushing very good Inv. Example 918 19.3 FC 33.57 1.04 11.5 0.7 Existence Existence 67 alkyl silicate 60 Brushing very good Inv. Example 919 3.5 FC 3.04 1.02 0.4 1.5 Existence Existence 45 alkali silicate 15 Spraying very good Inv. Example 920 22.5 FC 7.54 1.01 0.6 1.3 Existence Existence 48 alkyl silicate 24 Spraying very good Inv. Example 921 23.7 FC 6.81 1.08 10.6 1.8 Existence No 68 alkali silicate 34 Spraying very good Inv. Example 922 24.2 FC 5.25 1.14 9.5 0 Existence Existence 35 alkyl silicate 20 Brushing very good Inv. Example 923 0.2 FC 194.23 1.23 11.04 0.7 Existence Existence 37 alkali silicate 200 Brushing very good Inv. Example 924 27.1 FC 28.74 1.33 0.01 1.8 Existence Existence 38 alkyl silicate 56 Brushing very good Inv. Example 925 29.3 FC 13.57 1.37 0.07 0.7 Existence Existence 41 alkali silicate 34 Spraying very good Inv. Example 926 0.5 FC 0.65 1.44 1.8 1.5 Existence Existence 54 alkyl silicate 2 Spraying very good Inv. Example 927 2.7 FC 4.12 1.21 0 1.3 Existence Existence 57 alkali silicate 15 Spraying very good Inv. Example 928 28.4 FC 0.72 1.22 2.9 1.8 Existence Existence 59 alkali silicate 10 Spraying very good Inv. Example 929 8.7 FC 117.54 1.23 10.5 0.9 Existence Existence 64 alkyl silicate 125 Brushing very good Inv. Example 930 9.2 FC 7.81 1.47 2.9 0.7 Existence Existence 66 alkali silicate 24 Brushing very good Inv. Example 931 17.8 FC 80.25 1.01 16.8 1.8 Existence No 67 alkyl silicate 110 Brushing very good Inv. Example 932 20.2 FC 8.47 1.04 2.7 0.7 Existence Existence 34 alkali silicate 24 Brushing very good Inv. Example 933 0.4 FC 0.87 1.05 0.04 0.7 Existence Existence 54 alkyl silicate 2 Spraying very good Inv. Example 934 13.7 FC 25.78 1.12 0 0.04 Existence Existence 62 alkali silicate 37 Spraying very good Inv. Example 935 14.7 FC 93.45 1.11 1.24 0.05 Existence Existence 66 alkyl silicate 113 Brushing very good Inv. Example 936 2.4 FC 0.97 1.08 0.05 1.24 Existence Existence 67 alkali silicate 2 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 35 Zn-Alloy Particle Properties Coat Properties Mg Solid- Ratio Solution of Phase & Metal Zn—Mg Par- Aver- Inter- ti- age metallic cle Fracture Value Com- in Facet of pounds Dry Coat Mg &/or Mean As- Al Si on Coat Thick- Result of (mass Cracks Size pect (mass (mass Surface of MgZn₂ or (mass ness Coating Corrosion %) (*1) (μm) Ratio %) %) Particles Mg₂Zn₁₁ %) Base Resin (μm) Method Test Inv. Example 937 4.5 FC 54.89 1.47 1.24 0.06 Existence Existence 68 alkyl silicate 75 Brushing very good Inv. Example 938 0.1 FC 10.81 1.50 1.24 0.07 Existence Existence 33 alkali silicate 30 Brushing very good Inv. Example 939 30.0 FC 18.24 1.13 0 0.75 Existence Existence 35 alkyl silicate 34 Brushing very good Inv. Example 940 24.5 FC 114.78 1.04 0.9 1.5 Existence Existence 43 epoxy-based resin 124 Brushing very good Inv. Example 941 27.6 FC 3.87 1.02 0.03 1.3 Existence Existence 44 acryl-based resin 15 Spraying very good Inv. Example 942 4.1 FC 11.94 1.08 10.5 1.8 Existence No 43 urethane-based 23 Spraying very good resin Inv. Example 943 3.2 FC 142.58 1.15 2.9 0.9 Existence Existence 44 polyester resin 157 Brushing very good Inv. Example 944 2.7 FC 12.5 1.34 16.8 0.7 Existence Existence 54 epoxy-based resin 26 Spraying very good Inv. Example 945 0.12 FC 31.24 1.25 2.7 1.8 Existence Existence 79 acryl-based resin 38 Spraying very good Inv. Example 946 0.22 FC 152.46 1.19 0.02 0.7 Existence Existence 73 urethane-based 160 Brushing very good resin Inv. Example 947 0.37 FC 13.4 1.18 0 1.5 Existence Existence 69 polyester resin 27 Brushing very good Inv. Example 948 1.4 FC 160.57 1.24 7.42 1.3 Existence Existence 63 epoxy-based resin 180 Brushing very good Inv. Example 949 4.2 FC 14.1 1.11 0.02 1.8 Existence Existence 35 acryl-based resin 26 Spraying very good Inv. Example 950 4.8 FC 167.55 1.27 0.04 0.9 Existence Existence 35 urethane-based 180 Brushing very good resin Inv. Example 951 8.1 FC 1.45 1.31 17.5 0 Existence Existence 66 polyester resin 15 Spraying very good Inv. Example 952 7.6 FC 0.15 1.26 0.01 1.8 Existence Existence 67 epoxy-based resin 2 Spraying very good Inv. Example 953 9.9 FC 13.1 1.14 0.02 0.7 Existence Existence 68 acryl-based resin 28 Spraying very good Inv. Example 954 14.8 FC 15.5 1.34 3.8 0 Existence Existence 33 urethane-based 30 Spraying very good resin Inv. Example 955 16.7 FC 0.67 1.16 2.9 0 Existence Existence 35 polyester resin 2 Spraying very good Inv. Example 956 17.9 FC 137.89 1.47 10.5 1.8 Existence Existence 43 epoxy-based resin 157 Brushing very good Inv. Example 957 19.5 FC 16.3 1.48 2.9 0.9 Existence Existence 44 acryl-based resin 28 Brushing very good Inv. Example 958 22.4 FC 110.38 1.49 16.8 0.7 Existence Existence 42 urethane-based 130 Brushing very good resin Inv. Example 959 0.17 FC 12.4 1.34 2.7 1.8 Existence Existence 33 polyester resin 29 Brushing very good Inv. Example 960 8.3 FC 17.2 1.29 0.02 0.7 Existence No 30 epoxy-based resin 30 Brushing very good Inv. Example 961 6.5 FC 105.23 1.18 0.02 0.7 Existence Existence 35 acryl-based resin 120 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 36 Zn-Alloy Particle Properties Coat Properties Mg Solid- Ratio Solution of Phase & Metal Zn—Mg Par- Inter- ticle Fracture Average metallic in Facet Value Compounds Dry Coat Mg &/or Mean of Al Si on Coat Thick- Result of (mass Cracks Size Aspect (mass (mass Surface of MgZn₂ or (mass ness Coating Corrosion %) (*1) (μm) Ratio %) %) Particles Mg₂Zn₁₁ %) Base Resin (μm) Method Test Inv. Example 962 9.7 FC 177.89 1.23 0.04 0.02 Existence Existence 37 urethane- 187 Brushing very good based resin Inv. Example 963 11.4 FC 12.2 1.27 0.05 0.02 Existence Existence 77 polyester 28 Spraying very good resin Inv. Example 964 22.5 FC 1.84 1.17 1.24 1.37 Existence Existence 41 epoxy-based 5 Spraying very good resin Inv. Example 965 25.7 FC 16.02 1.16 0.05 0.02 Existence Existence 35 acryl-based 35 Spraying very good resin Inv. Example 966 17.8 FC 1.75 1.49 1.24 1.37 Existence Existence 58 urethane- 5 Spraying very good based resin Inv. Example 967 0.14 FC 198.78 1.34 1.24 1.37 Existence Existence 37 polyester 200 Brushing very good resin Inv. Example 968 6.7 FC 13.1 1.16 0.8 1.5 Existence Existence 68 alkali silicate 25 Spraying very good Inv. Example 969 7.5 FC 15.5 1.47 0.9 1.3 Existence Existence 55 alkali silicate 15 Spraying very good Inv. Example 970 8.4 FC 0.67 1.48 1.1 1.8 Existence No 77 alkyl silicate 20 Spraying very good Inv. Example 971 9.3 FC 12.2 1.49 1.8 0.9 Existence Existence 43 alkali silicate 18 Spraying very good Inv. Example 972 1.4 FC 1.84 1.34 3.8 0.7 Existence Existence 45 alkyl silicate 22 Spraying very good Inv. Example 973 4.2 FC 16.02 1.29 2.9 1.8 Existence Existence 66 alkali silicate 19 Spraying very good Inv. Example 974 4.8 FC 1.75 1.18 10.5 0.7 Existence Existence 33 alkyl silicate 29 Spraying very good Inv. Example 975 8.1 FC 12.4 1.23 2.9 1.5 Existence Existence 66 alkali silicate 23 Spraying very good Inv. Example 976 7.6 FC 17.2 1.27 16.8 1.3 Existence Existence 55 alkyl silicate 21 Spraying very good Inv. Example 977 9.9 FC 13.1 1.17 2.7 1.8 Existence Existence 49 alkali silicate 19 Spraying very good Inv. Example 978 0.4 FC 29.9 1.16 3.6 0.9 Existence Existence 77 alkyl silicate 15 Spraying very good Inv. Example 979 10.5 FC 0.21 1.27 0 0.7 Existence Existence 41 alkali silicate 18 Spraying very good Inv. Example 980 0.4 FC 0.22 1.17 0.06 1.8 Existence Existence 64 alkyl silicate 22 Spraying very good Inv. Example 981 10.5 FC 29.5 1.27 0.02 0.7 Existence Existence 58 alkyl silicate 21 Spraying very good Inv. Example 982 0.51 FC 29.9 1.18 1.6 1.5 Existence Existence 33 alkyl silicate 29 Spraying very good Inv. Example 983 9.8 FC 0.21 1.23 3.5 0 Existence Existence 66 alkali silicate 23 Spraying very good Inv. Example 984 0.52 FC 0.22 1.27 9.8 1.8 Existence Existence 55 alkyl silicate 21 Spraying very good Inv. Example 985 9.9 FC 29.5 1.17 11.5 0.9 Existence No 49 alkali silicate 19 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 37 Zn-Alloy Particle Properties Mg Solid- Solution Phase & Zn—Mg Fracture Average Intermetallic Facet Mean Value of Compounds on Mg &/or Size Aspect Al Si Surface of MgZn₂ or (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ Inv. Example 986 14.8 FC 16.02 1.48 0.4 0.7 Existence Existence Inv. Example 987 16.7 FC 1.75 1.49 0.6 1.8 Existence Existence Inv. Example 988 17.9 FC 12.4 1.34 10.6 0.7 Existence Existence Inv. Example 989 19.5 FC 17.2 1.29 9.5 0.7 Existence Existence Comp. Example 35 2.3 FC 205.6 1.23 0.07 0 Existence Existence Comp. Example 36 2.3 FC 0.005 1.23 0 0.07 Existence Existence Comp. Example 37 2.3 FC 205.6 1.23 0 0.02 Existence Existence Comp. Example 38 2.3 FC 0.005 1.23 22.1 0 Existence Existence Comp. Example 39 0.01 FC 0.4 1.24 1.2 0.5 Existence Existence Comp. Example 40 0.8 FC 3.2 2.54 0.6 0.8 Existence Existence Comp. Example 41 8.47 NO 0.67 1.25 2 1.9 Existence Existence Comp. Example 42 24.5 NO 2.5 1.05 0.8 0.9 Existence Existence Comp. Example 43 0.01 FC 0.4 1.24 0 0.02 Existence Existence Comp. Example 44 0.8 FC 0.2 1.78 25.8 0.05 Existence Existence Comp. Example 45 8.47 NO 0.67 1.25 22.1 0 Existence Existence Comp. Example 46 24.5 NO 2.5 1.05 21.5 0.05 Existence Existence Comp. Example 47 4.05 NO 0.02 1.23 0.05 2.29 Existence Existence Comp. Example 48 6.78 NO 12.5 1.35 0 0 Existence Existence Comp. Example 49 15.8 NO 23.3 1.14 0 0 Existence Existence Comp. Example 50 4.5 FC 3.5 2.84 22.1 0 Existence Existence Comp. Example 51 3.2 FC 6.7 1.75 0.05 2.29 Existence Existence Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 986 77 alkyl silicate 21 Spraying very good Inv. Example 987 43 alkali silicate 19 Spraying very good Inv. Example 988 45 alkyl silicate 15 Spraying very good Inv. Example 989 66 alkali silicate 18 Spraying very good Comp. Example 35 75 alkyl silicate 25 Spraying poor Comp. Example 36 75 alkyl silicate 25 Spraying poor Comp. Example 37 75 alkyl silicate 105 Brushing poor Comp. Example 38 75 alkyl silicate 165 Spraying poor Comp. Example 39 58 acryl-based resin 5 Spraying poor Comp. Example 40 64 urethane-based resin 2 Spraying poor Comp. Example 41 54 polyester resin 12 Brushing poor Comp. Example 42 32 epoxy-based resin 15 Brushing poor Comp. Example 43 57 alkali silicate 2 Spraying poor Comp. Example 44 70 alkyl silicate 5 Spraying poor Comp. Example 45 64 alkali silicate 12 Brushing poor Comp. Example 46 42 alkyl silicate 15 Brushing poor Comp. Example 47 38 alkali silicate 13 Brushing poor Comp. Example 48 44 alkyl silicate 22 Spraying poor Comp. Example 49 56 alkali silicate 34 Spraying poor Comp. Example 50 76 alkyl silicate 15 Brushing poor Comp. Example 51 65 alkyl silicate 15 Spraying poor (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 38 Zn-Alloy Particle Properties Mg Solid- Solution Phase & Zn—Mg MgZn₂, Fracture Average Intermetallic Mg₂Zn₁₁, Facet Mean Value of Compounds on Mg₂Zn₃, Mg &/or Size Aspect Al Si Surface of MgZn, or (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₇Zn₃ Inv. Example 2139 7.5 FC 5.07 1.42 0 0 Existence Existence Inv. Example 2140 8.06 FC 7.72 1.38 0 0 Existence Existence Inv. Example 2141 9.3 FC 8.32 1.22 0 0 Existence No Inv. Example 2142 3.5 FC 3.04 1.02 0 0 Existence Existence Inv. Example 2143 2.7 FC 4.12 1.21 0 0 Existence No Inv. Example 2144 9.2 FC 7.81 1.47 0 0 Existence Existence Inv. Example 2145 8.1 FC 1.45 1.31 0 0 Existence No Inv. Example 2146 7.5 FC 9.6 1.07 0 0 Existence Existence Inv. Example 2147 4.5 FC 8.5 1.42 0 0 Existence No Inv. Example 2148 3.6 FC 3.2 1.05 0 0 Existence No Inv. Example 2149 4.2 FC 5.7 1.02 1.5 0 Existence Existence Inv. Example 2150 4.3 FC 6.4 1.06 5.5 1.6 Existence No Inv. Example 2151 4 FC 3.2 1.05 0 0 Existence Existence Inv. Example 2152 6.4 FC 5.2 1.33 0 0 Existence Existence Inv. Example 2153 9.8 FC 5.2 1.33 0 0 Existence No Inv. Example 2154 7.5 FC 5.07 1.42 0 0 Existence No Inv. Example 2155 8.4 FC 7.72 1.38 0.5 0 Existence Existence Inv. Example 2156 2.7 FC 4.12 1.21 0 0 Existence No Inv. Example 2157 2.64 FC 5.5 1.22 0 0 Existence No Inv. Example 2158 1.59 FC 6.7 1.14 0 0 Existence Existence Inv. Example 2159 2.58 FC 8.9 1.13 0 0 Existence Existence Inv. Example 2160 7.55 FC 2.15 1.14 0 0 Existence Existence Inv. Example 2161 8.01 FC 2.54 1.13 0 0 Existence No Inv. Example 2162 1.06 FC 3.4 1.38 0 0 Existence Existence Inv. Example 2163 2.64 FC 5.5 1.22 0 0 Existence Existence Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 2139 74 alkali silicate 24 Brushing very good Inv. Example 2140 82 alkyl silicate 25 Spraying very good Inv. Example 2141 37 alkali silicate 14 Spraying very good Inv. Example 2142 48 alkali silicate 15 Spraying very good Inv. Example 2143 32 alkali silicate 15 Spraying very good Inv. Example 2144 45 alkyl silicate 15 Brushing very good Inv. Example 2145 37 epoxy-based resin 5 Spraying good Inv. Example 2146 72 urethane-based resin 150 Spraying very good Inv. Example 2147 40 alkali silicate 18 Spraying very good Inv. Example 2148 40 alkali silicate 18 Spraying very good Inv. Example 2149 72 alkyl silicate 58 Spraying very good Inv. Example 2150 40 alkyl silicate 21 Spraying very good Inv. Example 2151 36 alkali silicate 19 Brushing very good Inv. Example 2152 53 alkyl silicate 77 Spraying very good Inv. Example 2153 53 alkyl silicate 77 Spraying very good Inv. Example 2154 66 alkali silicate 13 Brushing very good Inv. Example 2155 67 alkyl silicate 22 Brushing very good Inv. Example 2156 57 alkali silicate 15 Spraying very good Inv. Example 2157 43 alkyl silicate 16 Spraying very good Inv. Example 2158 76 alkyl silicate 5 Spraying very good Inv. Example 2159 49 alkyl silicate 22 Spraying very good Inv. Example 2160 75 alkyl silicate 18 Spraying very good Inv. Example 2161 73 alkyl silicate 16 Spraying very good Inv. Example 2162 49 alkyl silicate 8 Spraying very good Inv. Example 2163 43 alkyl silicate 16 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 39 Zn-Alloy Particle Properties Mg Solid- Solution Phase & Zn—Mg MgZn₂, Fracture Average Intermetallic Mg₂Zn₁₁, Facet Mean Value of Compounds on Mg₂Zn₃, Mg &/or Size Aspect Al Si Surface of MgZn, or (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₇Zn₃ Inv. Example 2164 1.59 FC 6.7 1.14 0 0 Existence Existence Inv. Example 2165 20.5 FC 2.15 1.14 1.5 0 Existence No Inv. Example 2166 18.5 FC 2.54 1.13 5.5 1.6 Existence Existence Inv. Example 2167 9.51 FC 2.77 1.38 4.5 0 Existence Existence Inv. Example 2168 10.01 FC 3.68 1.22 0 1.6 Existence Existence Inv. Example 2169 3.54 FC 5.5 1.22 0 0 Existence No Inv. Example 2170 4.05 FC 2.06 1.13 0 0 Existence Existence Inv. Example 2171 8.57 FC 4.99 1.02 0 0 Existence Existence Inv. Example 2172 0.01 FC 6.4 1.06 0 0 Existence No Inv. Example 2173 25.5 FC 3.09 1.07 0 0 Existence Existence Inv. Example 2174 2.36 FC 3.99 1.22 0 0 Existence No Inv. Example 2175 0.05 FC 7.72 1.38 0 0 Existence Existence Inv. Example 2176 0.04 FC 8.32 1.22 0 0 Existence No Inv. Example 2177 5.22 FC 3.55 1.12 0 0 Existence Existence Inv. Example 2178 4.01 FC 2.64 1.23 0 0 Existence Existence Inv. Example 2179 0.05 FC 5.2 1.33 0 0 Existence Existence Inv. Example 2180 0.04 FC 1.9 1.27 0 0 Existence Existence Inv. Example 2181 0.05 FC 2.5 1.05 0 1.2 Existence No Inv. Example 2182 0.07 FC 0.09 1.12 0 0.6 Existence No Inv. Example 2183 2.64 FC 5.5 1.22 0 0.01 Existence No Inv. Example 2184 0.08 FC 5.6 1.36 1.5 0 Existence Existence Inv. Example 2185 0.09 FC 11.5 1.11 5.5 1.6 Existence No Inv. Example 2186 0.05 FC 19.5 1.07 4.5 0 Existence Existence Inv. Example 2187 1.59 FC 6.7 1.14 0 0.1 Existence Existence Inv. Example 2188 2.58 FC 8.9 1.13 0.01 0 Existence Existence Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 2164 76 alkyl silicate 5 Spraying very good Inv. Example 2165 75 alkyl silicate 18 Spraying very good Inv. Example 2166 73 alkyl silicate 16 Spraying very good Inv. Example 2167 55 alkyl silicate 5 Spraying very good Inv. Example 2168 48 alkyl silicate 22 Spraying very good Inv. Example 2169 78 alkyl silicate 18 Spraying very good Inv. Example 2170 52 alkyl silicate 8 Spraying very good Inv. Example 2171 61 alkyl silicate 16 Spraying very good Inv. Example 2172 77 polyester resin 47 Spraying very good Inv. Example 2173 49 alkyl silicate 22 Spraying very good Inv. Example 2174 80 alkyl silicate 21 Spraying very good Inv. Example 2175 36 alkyl silicate 19 Brushing very good Inv. Example 2176 32 alkyl silicate 24 Spraying very good Inv. Example 2177 55 alkyl silicate 19 Spraying very good Inv. Example 2178 40 alkyl silicate 8 Spraying very good Inv. Example 2179 53 urethane-based resin 20 Brushing very good Inv. Example 2180 60 polyester resin 200 Brushing very good Inv. Example 2181 38 alkali silicate 19 Spraying very good Inv. Example 2182 49 alkyl silicate 11 Spraying very good Inv. Example 2183 43 alkyl silicate 16 Spraying very good Inv. Example 2184 66 alkyl silicate 16 Brushing very good Inv. Example 2185 67 alkali silicate 33 Brushing very good Inv. Example 2186 54 alkyl silicate 8 Brushing good Inv. Example 2187 76 alkyl silicate 5 Spraying very good Inv. Example 2188 49 alkyl silicate 22 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 40 Zn-Alloy Particle Properties Mg Solid- Solution Phase & Zn—Mg MgZn₂, Fracture Average Intermetallic Mg₂Zn₁₁, Facet Mean Value of Compounds on Mg₂Zn₃, Mg &/or Size Aspect Al Si Surface of MgZn, or (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₇Zn₃ Inv. Example 2189 0.06 FC 8.32 1.22 3.2 0.9 Existence Existence Inv. Example 2190 0.18 FC 10.05 1.14 0 0.5 Existence Existence Inv. Example 2191 7.55 FC 2.15 1.14 0.2 0.1 Existence Existence Inv. Example 2192 0.01 FC 0.06 1.23 1.2 0.6 Existence No Inv. Example 2193 12.5 FC 2.54 1.13 0.5 0 Existence Existence Inv. Example 2194 1.06 FC 3.4 1.38 1.5 0.9 Existence Existence Inv. Example 2195 0.04 FC 8.5 1.42 0 1.2 Existence No Inv. Example 2196 0.06 FC 7.72 1.38 0 0.6 Existence Existence Inv. Example 2197 9.51 FC 2.77 1.38 0 0.01 Existence No Inv. Example 2198 15.5 FC 3.68 1.22 1.5 0 Existence Existence Inv. Example 2199 0.05 FC 10.6 1.13 5.5 1.6 Existence No Inv. Example 2200 0.07 FC 5.7 1.02 4.5 0 Existence No Inv. Example 2201 3.54 FC 5.5 1.22 0 0.1 Existence Existence Inv. Example 2202 0.08 FC 3.2 1.05 0.01 0 Existence Existence Inv. Example 2203 0.07 FC 4.5 1.24 3.2 0.9 Existence Existence Inv. Example 2204 15.5 FC 2.54 1.14 0 0.5 Existence No Inv. Example 2205 4.05 FC 2.06 1.13 0.2 0.1 Existence Existence Inv. Example 2206 8.57 FC 4.99 1.02 1.2 0.6 Existence No Inv. Example 2207 0.01 FC 6.4 1.06 0.5 0 Existence Existence Inv. Example 2208 4.59 FC 3.09 1.07 1.5 0.9 Existence No Inv. Example 2209 9.88 FC 4.66 1.42 0 1.2 Existence No Inv. Example 2210 4.55 FC 4.09 1.38 0 0.6 Existence Existence Inv. Example 2211 2.36 FC 3.99 1.22 0 0.01 Existence No Inv. Example 2212 0.05 FC 7.72 1.38 1.5 0 Existence Existence Inv. Example 2213 0.04 FC 8.32 1.22 5.5 1.6 Existence Existence Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 2189 32 alkyl silicate 23 Spraying very good Inv. Example 2190 53 epoxy-based resin 30 Spraying very good Inv. Example 2191 75 alkyl silicate 18 Spraying very good Inv. Example 2192 75 alkali silicate 5 Spraying good Inv. Example 2193 73 alkyl silicate 16 Spraying very good Inv. Example 2194 49 alkyl silicate 8 Spraying very good Inv. Example 2195 40 alkali silicate 2 Spraying very good Inv. Example 2196 36 alkyl silicate 18 Spraying very good Inv. Example 2197 55 alkyl silicate 5 Spraying very good Inv. Example 2198 48 alkyl silicate 22 Spraying very good Inv. Example 2199 67 acryl-based resin 77 Brushing very good Inv. Example 2200 72 urethane-based resin 54 Brushing very good Inv. Example 2201 78 alkyl silicate 18 Spraying very good Inv. Example 2202 34 epoxy-based resin 43 Spraying very good Inv. Example 2203 43 acryl-based resin 52 Brushing very good Inv. Example 2204 45 alkyl silicate 19 Spraying very good Inv. Example 2205 52 alkyl silicate 8 Spraying very good Inv. Example 2206 61 alkyl silicate 16 Spraying very good Inv. Example 2207 77 polyester resin 47 Spraying very good Inv. Example 2208 49 alkyl silicate 22 Spraying very good Inv. Example 2209 79 alkyl silicate 18 Spraying very good Inv. Example 2210 76 alkyl silicate 18 Spraying very good Inv. Example 2211 80 alkyl silicate 21 Spraying very good Inv. Example 2212 36 alkyl silicate 19 Brushing very good Inv. Example 2213 32 alkyl silicate 24 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 41 Zn-Alloy Particle Properties Mg Solid- Solution Phase & Zn—Mg MgZn₂, Fracture Average Intermetallic Mg₂Zn₁₁, Facet Mean Value of Compounds on Mg₂Zn₃, Mg &/or Size Aspect Al Si Surface of MgZn, or (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₇Zn₃ Inv. Example 2214 2.64 FC 4.55 1.11 4.5 0 Existence No Inv. Example 2215 0.06 FC 10.6 1.13 0 0.1 Existence No Inv. Example 2216 0.18 FC 5.7 1.02 0.01 0 Existence Existence Inv. Example 2217 6.31 FC 3.52 1.27 3.2 0.9 Existence No Inv. Example 2218 5.22 FC 3.55 1.12 0 0.5 Existence No Inv. Example 2219 28.5 FC 2.64 1.23 0.2 0.1 Existence Existence Inv. Example 2220 3.52 FC 3.15 1.36 1.2 0.6 Existence Existence Inv. Example 2221 0.05 FC 5.2 1.33 0.5 0 Existence Existence Inv. Example 2222 0.04 FC 1.9 1.27 1.5 0.9 Existence No Inv. Example 2223 0.06 FC 10.5 1.12 0 1.2 Existence Existence Inv. Example 2224 0.05 FC 12.5 1.23 0 0.6 Existence Existence Inv. Example 2225 0.07 FC 18.5 1.36 0 0.01 Existence Existence Inv. Example 2226 0.01 FC 11.5 1.11 1.5 0 Existence No Inv. Example 2227 0.08 FC 9.6 1.07 5.5 1.6 Existence Existence Inv. Example 2228 0.03 FC 8.5 1.42 4.5 0 Existence Existence Inv. Example 2229 4.25 FC 2.36 1.33 0 0.1 Existence Existence Inv. Example 2230 0.04 FC 23.5 1.42 0.01 0 Existence No Inv. Example 2231 0.06 FC 101.5 1.38 3.2 0.9 Existence Existence Inv. Example 2232 0.06 FC 55.4 1.38 0 0.5 Existence Existence Inv. Example 2233 0.07 FC 10.5 1.12 0.2 0.1 Existence No Inv. Example 2234 0.01 FC 12.5 1.23 1.2 0.6 Existence Existence Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 2214 43 alkyl silicate 5 Spraying very good Inv. Example 2215 67 alkyl silicate 7 Spraying very good Inv. Example 2216 72 epoxy-based resin 100 Spraying very good Inv. Example 2217 51 alkyl silicate 21 Spraying very good Inv. Example 2218 55 alkyl silicate 19 Spraying very good Inv. Example 2219 40 alkyl silicate 8 Spraying very good Inv. Example 2220 51 alkyl silicate 16 Spraying very good Inv. Example 2221 53 urethane-based resin 20 Brushing very good Inv. Example 2222 60 polyester resin 200 Brushing very good Inv. Example 2223 77 alkyl silicate 25 Spraying very good Inv. Example 2224 43 alkali silicate 14 Spraying very good Inv. Example 2225 52 urethane-based resin 112 Spraying very good Inv. Example 2226 66 alkali silicate 24 Spraying very good Inv. Example 2227 72 urethane-based resin 150 Spraying very good Inv. Example 2228 40 alkali silicate 18 Spraying very good Inv. Example 2229 44 alkyl silicate 18 Spraying very good Inv. Example 2230 44 alkali silicate 38 Spraying very good Inv. Example 2231 36 alkyl silicate 18 Spraying very good Inv. Example 2232 76 alkyl silicate 10 Spraying very good Inv. Example 2233 77 alkyl silicate 37 Spraying very good Inv. Example 2234 43 alkali silicate 2 Spraying good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 42 Zn-Alloy Particle Properties Mg Solid- Solution Phase & Zn—Mg MgZn₂, Fracture Average Intermetallic Mg₂Zn₁₁, Facet Mean Value of Compounds on Mg₂Zn₃, Mg &/or Size Aspect Al Si Surface of MgZn, or (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₇Zn₃ Inv. Example 2235 0.08 FC 18.5 1.36 0.5 0 Existence No Inv. Example 2236 0.09 FC 11.5 1.11 1.5 0.9 Existence Existence Inv. Example 2237 0.05 FC 9.6 1.07 0.5 0 Existence No Inv. Example 2238 0.06 FC 10.05 1.14 1.5 0.9 Existence Existence Inv. Example 2239 29.9 FC 10.5 1.36 0 0 Existence Existence Inv. Example 2240 16.5 FC 7.5 1.11 0.01 0 Existence Existence Inv. Example 2241 12.5 FC 2.6 1.07 3.2 0.9 Existence No Inv. Example 2242 9.8 FC 3.5 1.42 0 0.5 Existence Existence Inv. Example 2243 9.6 FC 4.5 1.33 0.2 0.1 Existence No Inv. Example 2244 7.5 FC 1.6 1.42 0 0.5 Existence Existence Inv. Example 2245 4.6 FC 2.5 1.12 5.8 0.1 Existence Existence Inv. Example 2246 3.8 FC 23.5 1.23 1.2 0.6 Existence Existence Inv. Example 2247 0.05 FC 9.8 1.27 15.5 0 Existence Existence Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 2235 52 alkyl silicate 160 Brushing very good Inv. Example 2236 66 alkali silicate 5 Brushing very good Inv. Example 2237 72 alkyl silicate 56 Brushing very good Inv. Example 2238 53 urethane-based resin 99 Spraying very good Inv. Example 2239 55 urethane-based resin 700 Spraying very good Inv. Example 2240 47 alkyl silicate 554 Spraying very good Inv. Example 2241 79 urethane-based resin 688 Brushing very good Inv. Example 2242 42 urethane-based resin 421 Spraying very good Inv. Example 2243 36 urethane-based resin 651 Spraying very good Inv. Example 2244 53 urethane-based resin 402 Brushing very good Inv. Example 2245 55 alkali silicate 354 Spraying very good Inv. Example 2246 42 urethane-based resin 504 Brushing very good Inv. Example 2247 76 urethane-based resin 666 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

Example 4

Zn alloy particles with the chemical ingredients shown in Tables 43 to 57 were prepared in the same way as in Example 1. The rest is the same as Example 3.

MgZn₂, Mg₂Zn₁₁, Mg₂Zn₃, MgZn, or, Mg₇Zn₃ were identified by analysis of the ratio of composition of the Mg and Zn at the physical fracture facets or crack surfaces by the X-ray diffraction method or by observation by a scanning electron microscopy with an energy dispersion type X-ray analyzer.

Further, the number of facets of the Zn alloy particles was measured by observing 50 to 100 randomly extracted particles by a scan type electron microscope.

From Tables 43 to 57, it is learned that due to the surfaces of the particles including fractured parts having, as intermetallic compounds, at least one type of compound of MgZn₂, Mg₂Zn₁₁, Mg₂Zn₃, MgZn, and Mg₇Zn₃ or due to the number of facets being two facets or more, the painting test pieces using the Zn alloy particles of the present invention are improved in corrosion resistance and rust protection regardless of the type of base resin, that is, both for inorganic-based and organic-based binders.

TABLE 43 Zn-Alloy Particle Properties Mg Solid- Solution Average Phase & Zn—Mg Fracture Value Intermetallic Facet Mean of Compounds on Mg &/or Size Aspect Al Si Surface of MgZn₂ or # of (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ facets Inv. Example 139 17.3 F 29.24 1.37 11.4 0.24 Existence No 6 Inv. Example 140 18.5 F 1.28 1.10 0.04 0.03 Existence No 6 Inv. Example 141 19.3 F 33.57 1.04 0.25 0.07 Existence No 7 Inv. Example 142 3.5 F 3.04 1.02 5.43 0.65 Existence No 7 Inv. Example 143 22.5 F 7.54 1.01 17.5 2.41 Existence No 6 Inv. Example 144 23.7 F 68.12 1.08 0.01 0.08 Existence No 6 Inv. Example 145 24.2 F 0.52 1.14 0.02 2.23 Existence No 6 Inv. Example 146 0.2 F 0.12 1.23 0.02 0.06 Existence No 7 Inv. Example 147 27.1 F 58.74 1.33 0.04 0.02 Existence No 6 Inv. Example 148 29.3 F 13.57 1.37 0.05 0.02 Existence No 6 Inv. Example 149 0.5 F 6.4 1.44 1.24 1.37 Existence No 6 Inv. Example 150 2.7 F 41.23 1.21 27.5 2.43 Existence No 7 Inv. Example 151 28.4 F 0.72 1.22 0.01 0.02 Existence No 6 Inv. Example 152 8.7 F 1.18 1.23 0.01 0.01 Existence No 7 Inv. Example 153 9.2 F 7.12 1.47 0.02 0.05 Existence No 6 Inv. Example 154 17.8 F 8.01 1.01 0.03 0.04 Existence No 6 Inv. Example 155 20.2 F 0.84 1.04 7.78 0.24 Existence No 6 Inv. Example 156 0.4 F 87.65 1.05 0.04 0.06 Existence No 7 Inv. Example 157 13.7 F 2.59 1.12 11.21 0.74 Existence No 6 Inv. Example 158 14.7 F 93.45 1.11 0.09 0.01 Existence No 6 Inv. Example 159 2.4 F 9.84 1.08 5.41 1.27 Existence No 7 Inv. Example 160 4.5 F 5.45 1.47 0.02 0.03 Existence No 6 Inv. Example 161 0.1 F 1.08 1.50 0.02 0.07 Existence No 7 Inv. Example 162 30.0 F 180.24 1.13 0.03 0.08 Existence Existence 6 Inv. Example 163 24.5 F 11.4 1.04 11.04 0.21 Existence Existence 6 Inv. Example 164 27.6 F 38.75 1.02 0.01 0.02 Existence Existence 6 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 139 30 alkali silicate 35 Spraying very good Inv. Example 140 34 alkyl silicate 5 Spraying very good Inv. Example 141 42 alkali silicate 43 Spraying very good Inv. Example 142 51 alkyl silicate 15 Spraying very good Inv. Example 143 33 alkali silicate 20 Spraying very good Inv. Example 144 64 alkyl silicate 70 Brushing very good Inv. Example 145 74 alkali silicate 2 Brushing very good Inv. Example 146 82 alkyl silicate 3 Brushing very good Inv. Example 147 37 alkali silicate 65 Brushing very good Inv. Example 148 42 alkyl silicate 23 Spraying very good Inv. Example 149 66 alkali silicate 15 Spraying very good Inv. Example 150 48 alkyl silicate 55 Brushing very good Inv. Example 151 33 alkali silicate 2 Brushing very good Inv. Example 152 75 alkyl silicate 15 Brushing very good Inv. Example 153 77 alkali silicate 20 Spraying very good Inv. Example 154 68 alkyl silicate 22 Spraying very good Inv. Example 155 61 alkali silicate 56 Brushing very good Inv. Example 156 59 alkyl silicate 95 Brushing very good Inv. Example 157 39 alkali silicate 13 Spraying very good Inv. Example 158 42 alkyl silicate 100 Brushing very good Inv. Example 159 48 alkali silicate 18 Spraying very good Inv. Example 160 44 alkyl silicate 15 Spraying very good Inv. Example 161 47 alkali silicate 12 Spraying very good Inv. Example 162 52 alkyl silicate 5 Spraying very good Inv. Example 163 55 alkali silicate 130 Brushing very good Inv. Example 164 69 alkyl silicate 70 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 44 Zn-Alloy Particle Properties Mg Solid- Solution Average Phase & Zn—Mg Fracture Value Intermetallic Facet Mean of Compounds on Mg &/or Size Aspect Al Si Surface of MgZn₂ or # of (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ facets Inv. Example 165 4.1 F 119.87 1.08 0.07 0.04 Existence Existence 6 Inv. Example 166 3.2 F 1.42 1.15 0.08 0.01 Existence Existence 7 Inv. Example 167 2.7 F 12.5 1.34 0.04 0.03 Existence Existence 6 Inv. Example 168 0.12 F 31.24 1.25 0.02 0.04 Existence Existence 6 Inv. Example 169 0.22 F 152.46 1.19 0.02 0.02 Existence Existence 6 Inv. Example 170 0.37 F 13.4 1.18 4.12 0.61 Existence Existence 7 Inv. Example 171 1.4 F 1.61 1.24 0.05 0.02 Existence Existence 6 Inv. Example 172 4.2 F 14.1 1.11 2.14 0.74 Existence Existence 6 Inv. Example 173 4.8 F 1.67 1.27 0.03 0.02 Existence Existence 7 Inv. Example 174 8.1 F 1.45 1.31 0.03 0.04 Existence Existence 6 Inv. Example 175 7.6 F 14.8 1.26 0.04 0.05 Existence Existence 6 Inv. Example 176 9.9 F 1.31 1.14 7.54 1.24 Existence Existence 6 Inv. Example 177 14.8 F 15.5 1.34 0.08 0.06 Existence Existence 7 Inv. Example 178 16.7 F 0.67 1.16 0.01 0.07 Existence Existence 7 Inv. Example 179 17.9 F 137.89 1.47 29.8 0.75 Existence Existence 6 Inv. Example 180 19.5 F 1.63 1.48 0.01 0.02 Existence Existence 6 Inv. Example 181 22.4 F 1.12 1.49 0.03 0.01 Existence Existence 7 Inv. Example 182 0.17 F 169.88 1.34 0.02 0.01 Existence Existence 6 Inv. Example 183 8.3 F 1.72 1.29 8.04 1.24 Existence Existence 6 Inv. Example 184 6.5 F 10.5 1.18 0.06 0.04 Existence Existence 6 Inv. Example 185 9.7 F 17.7 1.23 0.08 0.02 Existence Existence 7 Inv. Example 186 11.4 F 122.54 1.27 0.03 0.01 Existence Existence 6 Inv. Example 187 22.5 F 1.84 1.17 0.04 0.03 Existence Existence 6 Inv. Example 188 25.7 F 19.1 1.16 7.42 1.22 Existence Existence 6 Inv. Example 189 17.8 F 1.75 1.49 0.02 0.01 Existence Existence 7 Inv. Example 190 0.14 F 198.78 1.34 0.08 0.02 Existence Existence 6 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 165 78 alkali silicate 123 Brushing very good Inv. Example 166 42 alkyl silicate 15 Spraying very good Inv. Example 167 32 alkali silicate 25 Spraying very good Inv. Example 168 66 alkyl silicate 66 Brushing very good Inv. Example 169 67 alkali silicate 170 Brushing very good Inv. Example 170 45 alkyl silicate 24 Brushing very good Inv. Example 171 48 alkali silicate 15 Brushing very good Inv. Example 172 68 alkyl silicate 20 Spraying very good Inv. Example 173 35 alkali silicate 15 Spraying very good Inv. Example 174 37 alkyl silicate 12 Spraying very good Inv. Example 175 38 alkali silicate 12 Spraying very good Inv. Example 176 41 alkyl silicate 15 Brushing very good Inv. Example 177 54 alkali silicate 160 Brushing very good Inv. Example 178 57 alkyl silicate 2 Brushing very good Inv. Example 179 59 epoxy-based resin 140 Brushing very good Inv. Example 180 64 acryl-based resin 15 Spraying very good Inv. Example 181 66 urethane-based resin 170 Brushing very good Inv. Example 182 67 polyester resin 20 Brushing very good Inv. Example 183 75 epoxy-based resin 2 Spraying very good Inv. Example 184 74 acryl-based resin 15 Spraying very good Inv. Example 185 77 urethane-based resin 27 Spraying very good Inv. Example 186 41 polyester resin 145 Brushing very good Inv. Example 187 35 epoxy-based resin 5 Spraying very good Inv. Example 188 58 acryl-based resin 15 Spraying very good Inv. Example 189 78 urethane-based resin 20 Brushing very good Inv. Example 190 66 polyester resin 200 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 45 Zn-Alloy Particle Properties Mg Solid- Solution Average Phase & Zn—Mg Fracture Value Intermetallic Facet Mean of Compounds on Mg &/or Size Aspect Al Si Surface of MgZn₂ or # of (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ facets Inv. Example 990 0.15 FC 0.02 1.05 0.1 0.07 Existence Existence 6 Inv. Example 991 0.19 FC 10.5 1.12 0.04 0.1 Existence Existence 6 Inv. Example 992 0.18 FC 12.5 1.23 30.0 0.01 Existence No 7 Inv. Example 993 0.11 FC 18.5 1.36 0.02 3 Existence Existence 7 Inv. Example 994 0.15 FC 11.5 1.11 0 0 Existence No 6 Inv. Example 995 0.24 FC 9.6 1.07 0 0 Existence Existence 6 Inv. Example 996 0.18 FC 8.5 1.42 10.4 0.57 Existence No 6 Inv. Example 997 0.12 FC 7.72 1.38 4.65 2.67 Existence Existence 7 Inv. Example 998 0.19 FC 8.32 1.22 24.8 2.4 Existence No 6 Inv. Example 999 0.18 FC 10.05 1.14 4.52 0.57 Existence No 6 Inv. Example 1000 0.21 FC 10.6 1.13 17.5 2.45 Existence Existence 6 Inv. Example 1001 0.76 FC 5.7 1.02 0 0 Existence No 7 Inv. Example 1002 0.11 FC 6.4 1.06 11.05 0.23 Existence Existence 6 Inv. Example 1003 0.14 FC 3.2 1.05 2.65 0.74 Existence Existence 7 Inv. Example 1004 15 FC 4.5 1.24 6.45 2.14 Existence No 6 Inv. Example 1005 14.5 FC 5.2 1.33 0 0 Existence No 6 Inv. Example 1006 18.5 FC 1.9 1.27 0 0 Existence Existence 6 Inv. Example 1007 15.1 FC 0.02 1.05 0.05 0.03 Existence No 7 Inv. Example 1008 15.6 FC 10.5 1.12 0 0.08 Existence No 6 Inv. Example 1009 12.5 FC 12.5 1.23 0.05 0 Existence Existence 6 Inv. Example 1010 18.7 FC 18.5 1.36 0.44 0.07 Existence Existence 7 Inv. Example 1011 14.5 FC 11.5 1.11 0.08 0.07 Existence Existence 6 Inv. Example 1012 7.5 FC 9.6 1.07 0.1 0.2 Existence No 7 Inv. Example 1013 4.5 FC 8.5 1.42 0 0 Existence Existence 6 Inv. Example 1014 1.5 FC 7.72 1.38 0 0 Existence Existence 6 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 990 35 alkali silicate 2 Spraying very good Inv. Example 991 77 alkyl silicate 37 Spraying very good Inv. Example 992 43 alkali silicate 2 Spraying good Inv. Example 993 52 alkyl silicate 160 Brushing very good Inv. Example 994 66 alkali silicate 5 Brushing very good Inv. Example 995 72 alkyl silicate 56 Brushing very good Inv. Example 996 40 alkali silicate 2 Spraying very good Inv. Example 997 36 alkyl silicate 18 Spraying very good Inv. Example 998 32 alkyl silicate 23 Spraying very good Inv. Example 999 53 epoxy-based resin 30 Brushing very good Inv. Example 1000 67 acryl-based resin 77 Brushing very good Inv. Example 1001 72 urethane-based resin 54 Brushing very good Inv. Example 1002 77 polyester resin 47 Spraying very good Inv. Example 1003 34 epoxy-based resin 43 Spraying very good Inv. Example 1004 43 acryl-based resin 52 Brushing very good Inv. Example 1005 53 urethane-based resin 20 Brushing very good Inv. Example 1006 60 polyester resin 200 Brushing very good Inv. Example 1007 35 alkali silicate 22 Spraying very good Inv. Example 1008 77 alkyl silicate 25 Spraying very good Inv. Example 1009 43 alkali silicate 14 Spraying very good Inv. Example 1010 52 urethane-based resin 112 Spraying very good Inv. Example 1011 66 alkali silicate 24 Spraying very good Inv. Example 1012 72 urethane-based resin 150 Spraying very good Inv. Example 1013 40 alkali silicate 18 Spraying very good Inv. Example 1014 36 alkyl silicate 19 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 46 Zn-Alloy Particle Properties Mg Solid- Solution Average Phase & Zn—Mg Fracture Value Intermetallic Facet Mean of Compounds on Mg &/or Size Aspect Al Si Surface of MgZn₂ or # of (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ facets Inv. Example 1015 4.8 FC 8.32 1.22 0 0.07 Existence Existence 6 Inv. Example 1016 9.6 FC 10.05 1.14 0 0.02 Existence No 6 Inv. Example 1017 11.5 FC 10.6 1.13 25.8 0.05 Existence Existence 7 Inv. Example 1018 9.8 FC 5.7 1.02 22.1 0 Existence Existence 6 Inv. Example 1019 7.6 FC 6.4 1.06 21.5 0.05 Existence Existence 6 Inv. Example 1020 3.2 FC 3.2 1.05 0.05 2.29 Existence No 6 Inv. Example 1021 1.9 FC 4.5 1.24 0.05 0.03 Existence Existence 7 Inv. Example 1022 11.5 FC 5.2 1.33 0 0.08 Existence Existence 6 Inv. Example 1023 8.7 FC 1.9 1.27 0 0 Existence No 6 Inv. Example 1024 9.6 FC 0.02 1.05 0 0 Existence Existence 7 Inv. Example 1025 9.4 FC 10.5 1.12 0.08 0.07 Existence No 6 Inv. Example 1026 10.5 FC 12.5 1.23 0.1 0.2 Existence Existence 6 Inv. Example 1027 12.6 FC 18.5 1.36 0.05 0.2 Existence No 6 Inv. Example 1028 29.5 FC 11.5 1.11 0.07 0 Existence Existence 7 Inv. Example 1029 29.4 FC 9.6 1.07 0 0.07 Existence Existence 7 Inv. Example 1030 27.5 FC 8.5 1.42 0 0.02 Existence Existence 6 Inv. Example 1031 0.8 FC 7.72 1.38 25.8 0.05 Existence Existence 6 Inv. Example 1032 1.6 FC 8.32 1.22 22.1 0 Existence No 7 Inv. Example 1033 22.9 FC 10.05 1.14 21.5 0.05 Existence No 6 Inv. Example 1034 28.5 FC 10.6 1.13 0.05 2.29 Existence No 6 Inv. Example 1035 29.5 FC 5.7 1.02 0.1 0.2 Existence Existence 6 Inv. Example 1036 18.7 FC 6.4 1.06 0.05 0.2 Existence No 7 Inv. Example 1037 19.5 FC 3.2 1.05 0.07 0 Existence Existence 6 Inv. Example 1038 20.4 FC 4.5 1.24 0 0.07 Existence Existence 6 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 1015 32 alkyl silicate 24 Spraying very good Inv. Example 1016 53 urethane-based resin 99 Spraying very good Inv. Example 1017 67 alkyl silicate 7 Spraying very good Inv. Example 1018 72 epoxy-based resin 100 Spraying very good Inv. Example 1019 77 alkyl silicate 27 Brushing very good Inv. Example 1020 34 alkali silicate 15 Spraying very good Inv. Example 1021 43 alkyl silicate 14 Spraying very good Inv. Example 1022 53 urethane-based resin 55 Spraying very good Inv. Example 1023 35 alkyl silicate 8 Spraying very good Inv. Example 1024 77 urethane-based resin 122 Brushing very good Inv. Example 1025 43 alkyl silicate 54 Spraying very good Inv. Example 1026 52 alkali silicate 19 Spraying very good Inv. Example 1027 66 alkyl silicate 25 Brushing very good Inv. Example 1028 72 alkyl silicate 58 Spraying very good Inv. Example 1029 40 alkyl silicate 21 Spraying very good Inv. Example 1030 36 alkali silicate 19 Brushing very good Inv. Example 1031 32 urethane-based resin 56 Spraying very good Inv. Example 1032 53 alkyl silicate 77 Spraying very good Inv. Example 1033 67 alkyl silicate 54 Spraying very good Inv. Example 1034 72 alkyl silicate 64 Spraying very good Inv. Example 1035 77 alkyl silicate 34 Brushing very good Inv. Example 1036 34 alkali silicate 28 Spraying very good Inv. Example 1037 43 urethane-based resin 109 Brushing very good Inv. Example 1038 53 alkyl silicate 15 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 47 Zn-Alloy Particle Properties Mg Solid- Solution Average Phase & Zn—Mg Fracture Value Intermetallic Facet Mean of Compounds on Mg &/or Size Aspect Al Si Surface of MgZn₂ or # or (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ facets Inv. Example 1039 0.6 FC 5.2 1.33 0 0.02 Existence Existence 6 Inv. Example 1040 0.8 FC 1.9 1.27 22.1 0 Existence Existence 7 Inv. Example 1041 22.5 FC 0.02 1.05 0.1 0.07 Existence Existence 6 Inv. Example 1042 20.6 FC 10.5 1.12 0.04 0.1 Existence Existence 6 Inv. Example 1043 21.6 FC 12.5 1.23 30.0 0.01 Existence No 7 Inv. Example 1044 20.8 FC 7.72 1.38 0 0 Existence Existence 7 Inv. Example 1045 23.6 FC 8.32 1.22 0 0 Existence Existence 6 Inv. Example 1046 24.5 FC 10.05 1.14 4.52 0.57 Existence No 6 Inv. Example 1047 18.6 FC 10.6 1.13 17.5 2.45 Existence Existence 7 Inv. Example 1048 17.8 FC 5.2 1.33 27.6 2.4 Existence No 6 Inv. Example 1049 16.5 FC 1.9 1.27 4.32 1.07 Existence Existence 6 Inv. Example 1050 14.5 FC 0.02 1.05 0.05 0.03 Existence No 7 Inv. Example 1051 19 FC 10.5 1.12 0 0.08 Existence No 6 Inv. Example 1052 15 FC 12.5 1.23 0.05 0 Existence Existence 6 Inv. Example 1053 16.4 FC 18.5 1.36 0.44 0.07 Existence Existence 7 Inv. Example 1054 13.5 FC 11.5 1.11 0.08 0.07 Existence Existence 6 Inv. Example 1055 10.6 FC 11.5 1.11 8.02 2.04 Existence No 6 Inv. Example 1056 10.7 FC 9.6 1.07 15.6 1.27 Existence Existence 6 Inv. Example 1057 10.9 FC 8.5 1.42 10.4 0.57 Existence No 6 Inv. Example 1058 11.6 FC 7.72 1.38 4.65 2.67 Existence Existence 7 Inv. Example 1059 14.7 FC 8.32 1.22 24.8 2.4 Existence No 6 Inv. Example 1060 19.5 FC 10.05 1.14 4.52 0.57 Existence No 6 Inv. Example 1061 10.2 FC 10.6 1.13 0 0 Existence Existence 6 Inv. Example 1062 4 FC 5.7 1.02 0 0 Existence No 7 Inv. Example 1063 7.2 FC 6.4 1.06 11.05 0.23 Existence Existence 6 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 1039 72 alkyl silicate 14 Spraying very good Inv. Example 1040 77 alkyl silicate 18 Spraying very good Inv. Example 1041 35 alkali silicate 2 Spraying very good Inv. Example 1042 77 alkyl silicate 37 Spraying very good Inv. Example 1043 43 alkali silicate 2 Spraying good Inv. Example 1044 52 alkyl silicate 160 Brushing very good Inv. Example 1045 66 alkali silicate 5 Brushing very good Inv. Example 1046 72 alkyl silicate 56 Brushing very good Inv. Example 1047 40 alkali silicate 2 Spraying very good Inv. Example 1048 36 alkyl silicate 18 Spraying very good Inv. Example 1049 32 alkyl silicate 23 Spraying very good Inv. Example 1050 53 epoxy-based resin 30 Brushing very good Inv. Example 1051 67 acryl-based resin 77 Brushing very good Inv. Example 1052 72 urethane-based resin 54 Brushing very good Inv. Example 1053 77 polyester resin 47 Spraying very good Inv. Example 1054 34 epoxy-based resin 43 Spraying very good Inv. Example 1055 43 acryl-based resin 52 Brushing very good Inv. Example 1056 53 urethane-based resin 20 Brushing very good Inv. Example 1057 60 polyester resin 200 Brushing very good Inv. Example 1058 35 alkali silicate 22 Spraying very good Inv. Example 1059 77 alkyl silicate 25 Spraying very good Inv. Example 1060 43 alkali silicate 14 Spraying very good Inv. Example 1061 52 urethane-based resin 112 Spraying very good Inv. Example 1062 66 alkali silicate 24 Spraying very good Inv. Example 1063 72 urethane-based resin 150 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 48 Zn-Alloy Particle Properties Mg Solid- Solution Average Phase & Zn—Mg MgZn₂, Fracture Value Intermetallic Zn₁₁, Facet Mean of Compounds on Mg₂Zn3, Mg &/or Size Aspect Al Si Surface of MgZn, or # or (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg7Zn3 facets Inv. Example 1064 3.6 FC 3.2 1.05 2.65 0.74 Existence Existence 7 Inv. Example 1065 26.9 FC 4.5 1.24 6.45 2.14 Existence No 6 Inv. Example 1066 27.9 FC 5.2 1.33 27.6 2.4 Existence No 6 Inv. Example 1067 28.9 FC 1.9 1.27 4.32 1.07 Existence Existence 6 Inv. Example 1068 23.8 FC 0.02 1.05 0.05 0.03 Existence No 7 Inv. Example 1069 26.8 FC 10.5 1.12 0 0.08 Existence No 6 Inv. Example 1070 25.6 FC 12.5 1.23 0.05 0 Existence Existence 6 Inv. Example 1071 29.8 FC 18.5 1.36 0.44 0.07 Existence Existence 7 Inv. Example 1072 18.9 FC 11.5 1.11 0.08 0.07 Existence Existence 6 Inv. Example 1073 5.6 FC 9.6 1.07 0.1 0.2 Existence No 7 Inv. Example 1074 4.7 FC 8.5 1.42 0.05 0.2 Existence Existence 6 Inv. Example 1075 6.8 FC 7.72 1.38 0.07 0 Existence Existence 6 Inv. Example 1076 9 FC 8.32 1.22 0 0.07 Existence Existence 6 Inv. Example 1077 2.1 FC 10.05 1.14 0 0.02 Existence No 6 Inv. Example 1078 4.8 FC 10.6 1.13 0 0 Existence Existence 7 Inv. Example 1079 4.2 FC 5.7 1.02 0 0 Existence Existence 6 Inv. Example 1080 4.3 FC 6.4 1.06 21.5 0.05 Existence Existence 6 Inv. Example 1081 4 FC 3.2 1.05 0.05 2.29 Existence No 6 Inv. Example 1082 3.7 FC 4.5 1.24 0.05 0.03 Existence Existence 7 Inv. Example 1083 6.4 FC 5.2 1.33 0 0.08 Existence Existence 6 Inv. Example 1084 6.9 FC 1.9 1.27 0.05 0 Existence No 6 Inv. Example 1085 16.9 FC 0.02 1.05 0.44 0.07 Existence Existence 7 Inv. Example 1086 18.7 FC 10.5 1.12 0.08 0.07 Existence No 6 Inv. Example 1087 24.4 FC 12.5 1.23 0.1 0.2 Existence Existence 6 Inv. Example 1088 10.6 FC 18.5 1.36 0 0 Existence No 6 Inv. Example 1089 15.8 FC 11.5 1.11 0 0 Existence Existence 7 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 1064 40 alkali silicate 18 Spraying very good Inv. Example 1065 36 alkyl silicate 19 Brushing very good Inv. Example 1066 32 alkyl silicate 24 Spraying very good Inv. Example 1067 53 urethane-based resin 99 Spraying very good Inv. Example 1068 67 alkyl silicate 7 Spraying very good Inv. Example 1069 72 epoxy-based resin 100 Spraying very good Inv. Example 1070 77 alkyl silicate 27 Brushing very good Inv. Example 1071 34 alkali silicate 15 Spraying very good Inv. Example 1072 43 alkyl silicate 14 Spraying very good Inv. Example 1073 53 urethane-based resin 55 Spraying very good Inv. Example 1074 35 alkyl silicate 8 Spraying very good Inv. Example 1075 77 urethane-based resin 122 Brushing very good Inv. Example 1076 43 alkyl silicate 54 Spraying very good Inv. Example 1077 52 alkali silicate 19 Spraying very good Inv. Example 1078 66 alkyl silicate 25 Brushing very good Inv. Example 1079 72 alkyl silicate 58 Spraying very good Inv. Example 1080 40 alkyl silicate 21 Spraying very good Inv. Example 1081 36 alkali silicate 19 Brushing very good Inv. Example 1082 32 urethane-based resin 56 Spraying very good Inv. Example 1083 53 alkyl silicate 77 Spraying very good Inv. Example 1084 67 alkyl silicate 54 Spraying very good Inv. Example 1085 72 alkyl silicate 64 Spraying very good Inv. Example 1086 77 alkyl silicate 34 Brushing very good Inv. Example 1087 34 alkali silicate 28 Spraying very good Inv. Example 1088 43 urethane-based resin 109 Brushing very good Inv. Example 1089 53 alkyl silicate 15 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 49 Zn-Alloy Particle Properties Mg Solid- Solution Average Phase & Zn—Mg MgZn₂, Fracture Value Intermetallic Mg₂Zn₁₁, Facet Mean of Compounds on Mg₂Zn3 Mg &/or Size Aspect Al Si Surface of MgZn, or # or (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg7Zn3 facets Inv. Example 1090 19.5 FC 9.6 1.07 0 0.07 Existence Existence 7 Inv. Example 1091 7.8 FC 8.5 1.42 0 0.02 Existence Existence 6 Inv. Example 1092 4.9 FC 7.72 1.38 25.8 0.05 Existence Existence 6 Inv. Example 1093 10.8 FC 8.32 1.22 22.1 0 Existence No 7 Inv. Example 1094 3.8 FC 10.05 1.14 21.5 0.05 Existence No 6 Inv. Example 1095 22.6 FC 10.6 1.13 0.05 2.29 Existence No 6 Inv. Example 1096 27.9 FC 5.7 1.02 0 0 Existence Existence 6 Inv. Example 1097 24.8 FC 6.4 1.06 0 0 Existence No 7 Inv. Example 1098 26.8 FC 3.2 1.05 0.07 0 Existence Existence 6 Inv. Example 1099 25.9 FC 4.5 1.24 0 0.07 Existence Existence 6 Inv. Example 1100 9.8 FC 5.2 1.33 0 0.02 Existence Existence 6 Inv. Example 1101 5.6 FC 1.9 1.27 22.1 0 Existence Existence 7 Inv. Example 1102 12.3 FC 0.02 1.05 1.24 1.8 Existence Existence 7 Inv. Example 1103 0.8 FC 27.89 1.12 1.24 0.9 Existence Existence 6 Inv. Example 1104 1 FC 0.32 1.23 0.8 0.7 Existence No 7 Inv. Example 1105 2.3 FC 11.44 1.36 0 1.8 Existence Existence 6 Inv. Example 1106 15.6 FC 1.05 1.11 1.1 2.41 Existence Existence 6 Inv. Example 1107 6.7 FC 36.47 1.07 1.8 0.08 Existence Existence 6 Inv. Example 1108 7.5 FC 5.07 1.42 3.8 2.23 Existence No 6 Inv. Example 1109 8.4 FC 7.72 1.38 2.9 0.06 Existence Existence 7 Inv. Example 1110 9.3 FC 8.32 1.22 10.5 0.02 Existence Existence 6 Inv. Example 1111 10.4 FC 10.05 1.14 2.9 0.02 Existence Existence 6 Inv. Example 1112 11.2 FC 6.08 1.13 16.8 1.37 Existence No 7 Inv. Example 1113 11.7 FC 17.89 1.02 0 2.43 Existence Existence 6 Inv. Example 1114 21.5 FC 19.54 1.06 3.6 0.02 Existence Existence 6 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 1090 72 alkyl silicate 14 Spraying very good Inv. Example 1091 77 alkyl silicate 18 Spraying very good Inv. Example 1092 77 urethane-based resin 122 Brushing very good Inv. Example 1093 43 alkyl silicate 54 Spraying very good Inv. Example 1094 52 alkali silicate 19 Spraying very good Inv. Example 1095 66 alkyl silicate 25 Brushing very good Inv. Example 1096 72 alkyl silicate 58 Spraying very good Inv. Example 1097 40 alkyl silicate 21 Spraying very good Inv. Example 1098 36 alkali silicate 19 Brushing very good Inv. Example 1099 32 urethane-based resin 56 Spraying very good Inv. Example 1100 53 alkyl silicate 77 Spraying very good Inv. Example 1101 67 alkyl silicate 54 Spraying very good Inv. Example 1102 52 alkali silicate 2 Spraying very good Inv. Example 1103 55 alkali silicate 20 Spraying very good Inv. Example 1104 69 alkali silicate 5 Spraying very good Inv. Example 1105 78 alkyl silicate 20 Spraying very good Inv. Example 1106 42 alkali silicate 15 Brushing very good Inv. Example 1107 32 alkyl silicate 57 Brushing very good Inv. Example 1108 66 alkali silicate 13 Brushing very good Inv. Example 1109 67 alkyl silicate 22 Brushing very good Inv. Example 1110 64 alkali silicate 20 Spraying very good Inv. Example 1111 74 alkyl silicate 27 Spraying very good Inv. Example 1112 82 alkali silicate 15 Spraying very good Inv. Example 1113 37 alkyl silicate 35 Spraying very good Inv. Example 1114 42 alkali silicate 34 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 50 Zn-Alloy Particle Properties Mg Solid- Solution Average Phase & Zn—Mg MgZn₂, Fracture Value Intermetallic Mg₂Zn₁₁, Facet Mean of Compounds on Mg₂Zn3 Mg &/or Size Aspect Al Si Surface of MgZn, or # or (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg7Zn3 facets Inv. Example 1115 13.4 FC 21.08 1.05 2.1 1.5 Existence No 6 Inv. Example 1116 14.6 FC 23.04 1.24 0.06 1.3 Existence Existence 6 Inv. Example 1117 25.8 FC 9.21 1.33 0.02 1.8 Existence Existence 7 Inv. Example 1118 16.7 FC 0.12 1.27 1.6 0.9 Existence Existence 6 Inv. Example 1119 17.3 FC 29.24 1.37 3.5 0 Existence Existence 6 Inv. Example 1120 18.5 FC 128.74 1.10 9.8 1.8 Existence No 7 Inv. Example 1121 19.3 FC 33.57 1.04 11.5 0.7 Existence Existence 6 Inv. Example 1122 3.5 FC 3.04 1.02 0.4 1.5 Existence Existence 6 Inv. Example 1123 22.5 FC 7.54 1.01 0.6 1.3 Existence Existence 6 Inv. Example 1124 23.7 FC 6.81 1.08 10.6 1.8 Existence No 6 Inv. Example 1125 24.2 FC 5.25 1.14 9.5 0 Existence Existence 7 Inv. Example 1126 0.2 FC 194.23 1.23 11.04 0.7 Existence Existence 6 Inv. Example 1127 27.1 FC 28.74 1.33 0.01 1.8 Existence Existence 6 Inv. Example 1128 29.3 FC 13.57 1.37 0.07 0.7 Existence Existence 7 Inv. Example 1129 0.5 FC 0.65 1.44 1.8 1.5 Existence Existence 6 Inv. Example 1130 2.7 FC 4.12 1.21 0 1.3 Existence Existence 6 Inv. Example 1131 28.4 FC 0.72 1.22 2.9 1.8 Existence Existence 6 Inv. Example 1132 8.7 FC 117.54 1.23 10.5 0.9 Existence Existence 6 Inv. Example 1133 9.2 FC 7.81 1.47 2.9 0.7 Existence Existence 7 Inv. Example 1134 17.8 FC 80.25 1.01 16.8 1.8 Existence No 6 Inv. Example 1135 20.2 FC 8.47 1.04 2.7 0.7 Existence Existence 6 Inv. Example 1136 0.4 FC 0.87 1.05 0.04 0.7 Existence Existence 7 Inv. Example 1137 13.7 FC 25.78 1.12 0 0.04 Existence Existence 6 Inv. Example 1138 14.7 FC 93.45 1.11 1.24 0.05 Existence Existence 6 Inv. Example 1139 2.4 FC 0.97 1.08 0.05 1.24 Existence Existence 6 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 1115 66 alkyl silicate 45 Brushing very good Inv. Example 1116 48 alkali silicate 52 Brushing very good Inv. Example 1117 33 alkyl silicate 23 Brushing very good Inv. Example 1118 75 alkali silicate 5 Spraying very good Inv. Example 1119 77 alkyl silicate 52 Brushing very good Inv. Example 1120 66 alkali silicate 150 Brushing very good Inv. Example 1121 67 alkyl silicate 60 Brushing very good Inv. Example 1122 45 alkali silicate 15 Spraying very good Inv. Example 1123 48 alkyl silicate 24 Spraying very good Inv. Example 1124 68 alkali silicate 34 Spraying very good Inv. Example 1125 35 alkyl silicate 20 Brushing very good Inv. Example 1126 37 alkali silicate 200 Brushing very good Inv. Example 1127 38 alkyl silicate 56 Brushing very good Inv. Example 1128 41 alkali silicate 34 Spraying very good Inv. Example 1129 54 alkyl silicate 2 Spraying very good Inv. Example 1130 57 alkali silicate 15 Spraying very good Inv. Example 1131 59 alkali silicate 10 Spraying very good Inv. Example 1132 64 alkyl silicate 125 Brushing very good Inv. Example 1133 66 alkali silicate 24 Brushing very good Inv. Example 1134 67 alkyl silicate 110 Brushing very good Inv. Example 1135 34 alkali silicate 24 Brushing very good Inv. Example 1136 54 alkyl silicate 2 Spraying very good Inv. Example 1137 62 alkali silicate 37 Spraying very good Inv. Example 1138 66 alkyl silicate 113 Brushing very good Inv. Example 1139 67 alkali silicate 2 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 51 Zn-Alloy Particle Properties Mg Solid- Solution Average Phase & Zn—Mg MgZn₂, Fracture Value Intermetallic Mg₂Zn₁₁, Facet Mean of Compounds on Mg₂Zn3 Mg &/or Size Aspect Al Si Surface of MgZn, or # or (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg7Zn3 facets Inv. Example 1140 4.5 FC 54.89 1.47 1.24 0.06 Existence Existence 6 Inv. Example 1141 0.1 FC 10.81 1.50 1.24 0.07 Existence Existence 7 Inv. Example 1142 30.0 FC 18.24 1.13 0 0.75 Existence Existence 6 Inv. Example 1143 24.5 FC 114.78 1.04 0.9 1.5 Existence Existence 6 Inv. Example 1144 27.6 FC 3.87 1.02 0.03 1.3 Existence Existence 7 Inv. Example 1145 4.1 FC 11.94 1.08 10.5 1.8 Existence No 6 Inv. Example 1146 3.2 FC 142.58 1.15 2.9 0.9 Existence Existence 6 Inv. Example 1147 2.7 FC 12.5 1.34 16.8 0.7 Existence Existence 6 Inv. Example 1148 0.12 FC 31.24 1.25 2.7 1.8 Existence Existence 6 Inv. Example 1149 0.22 FC 152.46 1.19 0.02 0.7 Existence Existence 7 Inv. Example 1150 0.37 FC 13.4 1.18 0 1.5 Existence Existence 6 Inv. Example 1151 1.4 FC 160.57 1.24 7.42 1.3 Existence Existence 6 Inv. Example 1152 4.2 FC 14.1 1.11 0.02 1.8 Existence Existence 7 Inv. Example 1153 4.8 FC 167.55 1.27 0.04 0.9 Existence Existence 6 Inv. Example 1154 8.1 FC 1.45 1.31 17.5 0 Existence Existence 6 Inv. Example 1155 7.6 FC 0.15 1.26 0.01 1.8 Existence Existence 6 Inv. Example 1156 9.9 FC 13.1 1.14 0.02 0.7 Existence Existence 6 Inv. Example 1157 14.8 FC 15.5 1.34 3.8 0 Existence Existence 7 Inv. Example 1158 16.7 FC 0.67 1.16 2.9 0 Existence Existence 6 Inv. Example 1159 17.9 FC 137.89 1.47 10.5 1.8 Existence Existence 6 Inv. Example 1160 19.5 FC 16.3 1.48 2.9 0.9 Existence Existence 7 Inv. Example 1161 22.4 FC 110.38 1.49 16.8 0.7 Existence Existence 6 Inv. Example 1162 0.17 FC 12.4 1.34 2.7 1.8 Existence Existence 6 Inv. Example 1163 8.3 FC 17.2 1.29 0.02 0.7 Existence No 6 Inv. Example 1164 6.5 FC 105.23 1.18 0.02 0.7 Existence Existence 6 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 1140 68 alkyl silicate 75 Brushing very good Inv. Example 1141 33 alkali silicate 30 Brushing very good Inv. Example 1142 35 alkyl silicate 34 Brushing very good Inv. Example 1143 43 epoxy-based resin 124 Brushing very good Inv. Example 1144 44 acryl-based resin 15 Spraying very good Inv. Example 1145 43 urethane-based resin 23 Spraying very good Inv. Example 1146 44 polyester resin 157 Brushing very good Inv. Example 1147 54 epoxy-based resin 26 Spraying very good Inv. Example 1148 79 acryl-based resin 38 Spraying very good Inv. Example 1149 73 urethane-based resin 160 Brushing very good Inv. Example 1150 69 polyester resin 27 Brushing very good Inv. Example 1151 63 epoxy-based resin 180 Brushing very good Inv. Example 1152 35 acryl-based resin 26 Spraying very good Inv. Example 1153 35 urethane-based resin 180 Brushing very good Inv. Example 1154 66 polyester resin 15 Spraying very good Inv. Example 1155 67 epoxy-based resin 2 Spraying very good Inv. Example 1156 68 acryl-based resin 28 Spraying very good Inv. Example 1157 33 urethane-based resin 30 Spraying very good Inv. Example 1158 35 polyester resin 2 Spraying very good Inv. Example 1159 43 epoxy-based resin 157 Brushing very good Inv. Example 1160 44 acryl-based resin 28 Brushing very good Inv. Example 1161 42 urethane-based resin 130 Brushing very good Inv. Example 1162 33 polyester resin 29 Brushing very good Inv. Example 1163 30 epoxy-based resin 30 Brushing very good Inv. Example 1164 35 acryl-based resin 120 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 52 Zn-Alloy Particle Properties Mg Solid- Solution Average Phase & Zn—Mg MgZn₂, Fracture Value Intermetallic Mg₂Zn₁₁, Facet Mean of Compounds on Mg₂Zn3, Mg &/or Size Aspect Al Si Surface of MgZn, or # of (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg7Zn3 facets Inv. Example 1165 9.7 FC 177.89 1.23 0.04 0.02 Existence Existence 7 Inv. Example 1166 11.4 FC 12.2 1.27 0.05 0.02 Existence Existence 6 Inv. Example 1167 22.5 FC 1.84 1.17 1.24 1.37 Existence Existence 6 Inv. Example 1168 25.7 FC 16.02 1.16 0.05 0.02 Existence Existence 7 Inv. Example 1169 17.8 FC 1.75 1.49 1.24 1.37 Existence Existence 6 Inv. Example 1170 0.14 FC 198.78 1.34 1.24 1.37 Existence Existence 6 Inv. Example 1171 6.7 FC 13.1 1.16 0.8 1.5 Existence Existence 6 Inv. Example 1172 7.5 FC 15.5 1.47 0.9 1.3 Existence Existence 6 Inv. Example 1173 8.4 FC 0.67 1.48 1.1 1.8 Existence No 7 Inv. Example 1174 9.3 FC 12.2 1.49 1.8 0.9 Existence Existence 6 Inv. Example 1175 1.4 FC 1.84 1.34 3.8 0.7 Existence Existence 6 Inv. Example 1176 4.2 FC 16.02 1.29 2.9 1.8 Existence Existence 7 Inv. Example 1177 4.8 FC 1.75 1.18 10.5 0.7 Existence Existence 6 Inv. Example 1178 8.1 FC 12.4 1.23 2.9 1.5 Existence Existence 6 Inv. Example 1179 7.6 FC 17.2 1.27 16.8 1.3 Existence Existence 6 Inv. Example 1180 9.9 FC 13.1 1.17 2.7 1.8 Existence Existence 6 Inv. Example 1181 0.4 FC 29.9 1.16 3.6 0.9 Existence Existence 7 Inv. Example 1182 10.5 FC 0.21 1.27 0 0.7 Existence Existence 6 Inv. Example 1183 0.4 FC 0.22 1.17 0.06 1.8 Existence Existence 7 Inv. Example 1184 10.5 FC 29.5 1.27 0.02 0.7 Existence Existence 6 Inv. Example 1185 0.51 FC 29.9 1.18 1.6 1.5 Existence Existence 6 Inv. Example 1186 9.8 FC 0.21 1.23 3.5 0 Existence Existence 6 Inv. Example 1187 0.52 FC 0.22 1.27 9.8 1.8 Existence Existence 6 Inv. Example 1188 9.9 FC 29.5 1.17 11.5 0.9 Existence No 7 Inv. Example 1189 14.8 FC 16.02 1.48 0.4 0.7 Existence Existence 6 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 1165 37 urethane-based resin 187 Brushing very good Inv. Example 1166 77 polyester resin 28 Spraying very good Inv. Example 1167 41 epoxy-based resin 5 Spraying very good Inv. Example 1168 35 acryl-based resin 35 Spraying very good Inv. Example 1169 58 urethane-based resin 5 Spraying very good Inv. Example 1170 37 polyester resin 200 Brushing very good Inv. Example 1171 68 alkali silicate 25 Spraying very good Inv. Example 1172 55 alkali silicate 15 Spraying very good Inv. Example 1173 77 alkyl silicate 20 Spraying very good Inv. Example 1174 43 alkali silicate 18 Spraying very good Inv. Example 1175 45 alkyl silicate 22 Spraying very good Inv. Example 1176 66 alkali silicate 19 Spraying very good Inv. Example 1177 33 alkyl silicate 29 Spraying very good Inv. Example 1178 66 alkali silicate 23 Spraying very good Inv. Example 1179 55 alkyl silicate 21 Spraying very good Inv. Example 1180 49 alkali silicate 19 Spraying very good Inv. Example 1181 77 alkyl silicate 15 Spraying very good Inv. Example 1182 41 alkali silicate 18 Spraying very good Inv. Example 1183 64 alkyl silicate 22 Spraying very good Inv. Example 1184 58 alkyl silicate 21 Spraying very good Inv. Example 1185 33 alkyl silicate 29 Spraying very good Inv. Example 1186 66 alkali silicate 23 Spraying very good Inv. Example 1187 55 alkyl silicate 21 Spraying very good Inv. Example 1188 49 alkali silicate 19 Spraying very good Inv. Example 1189 77 alkyl silicate 21 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 53 Zn-Alloy Particle Properties Mg Solid- Solution Average Phase & Zn—Mg MgZn₂, Fracture Value Intermetallic Mg₂Zn₁₁, Facet Mean of Compounds on Mg₂Zn3, Mg &/or Size Aspect Al Si Surface of MgZn, or # of (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg7Zn3 facets Inv. Example 1190 16.7 FC 1.75 1.49 0.6 1.8 Existence Existence 6 Inv. Example 1191 17.9 FC 12.4 1.34 10.6 0.7 Existence Existence 7 Inv. Example 1192 19.5 FC 17.2 1.29 9.5 0.7 Existence Existence 6 Comp. Example 52 2.3 FC 205.6 1.23 0.07 0 Existence Existence 6 Comp. Example 53 2.3 FC 0.005 1.23 0 0.07 Existence Existence 7 Comp. Example 54 2.3 FC 205.6 1.23 0 0.02 Existence Existence 6 Comp. Example 55 2.3 FC 0.005 1.23 22.1 0 Existence Existence 6 Comp. Example 56 2.3 FC 205.6 1.23 0.07 0 Existence Existence 7 Comp. Example 57 2.3 FC 0.005 1.23 0 0.07 Existence Existence 6 Comp. Example 58 2.3 FC 205.6 1.23 0 0.02 Existence Existence 7 Comp. Example 59 2.3 FC 0.005 1.23 22.1 0 Existence Existence 6 Comp. Example 60 0.01 FC 0.4 1.24 1.2 0.5 Existence Existence 6 Comp. Example 61 0.8 FC 3.2 2.54 0.6 0.8 Existence Existence 7 Comp. Example 62 8.47 NO 0.67 1.25 2 1.9 Existence Existence 6 Comp. Example 63 24.5 NO 2.5 1.05 0.8 0.9 Existence Existence 7 Comp. Example 64 0.01 FC 0.4 1.24 0 0.02 Existence Existence 6 Comp. Example 65 0.8 FC 0.2 1.78 25.8 0.05 Existence Existence 6 Comp. Example 66 8.47 NO 0.67 1.25 22.1 0 Existence Existence 7 Comp. Example 67 24.5 NO 2.5 1.05 21.5 0.05 Existence Existence 6 Comp. Example 68 4.05 NO 0.02 1.23 0.05 2.29 Existence Existence 7 Comp. Example 69 6.78 NO 12.5 1.35 0 0 Existence Existence 6 Comp. Example 70 15.8 NO 23.3 1.14 0 0 Existence Existence 6 Comp. Example 71 4.5 FC 3.5 2.84 22.1 0 Existence Existence 6 Comp. Example 72 3.2 FC 6.7 1.75 0.05 2.29 Existence Existence 6 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 1190 43 alkali silicate 19 Spraying very good Inv. Example 1191 45 alkyl silicate 15 Spraying very good Inv. Example 1192 66 alkali silicate 18 Spraying very good Comp. Example 52 75 alkyl silicate 25 Spraying poor Comp. Example 53 75 alkyl silicate 25 Spraying poor Comp. Example 54 75 alkyl silicate 105 Brushing poor Comp. Example 55 75 alkyl silicate 165 Spraying poor Comp. Example 56 75 alkyl silicate 25 Spraying poor Comp. Example 57 75 alkyl silicate 25 Spraying poor Comp. Example 58 75 alkyl silicate 105 Brushing poor Comp. Example 59 75 alkyl silicate 165 Spraying poor Comp. Example 60 58 acryl-based resin 5 Spraying poor Comp. Example 61 64 urethane-based resin 2 Spraying poor Comp. Example 62 54 polyester resin 12 Brushing poor Comp. Example 63 32 epoxy-based resin 15 Brushing poor Comp. Example 64 57 alkali silicate 2 Spraying poor Comp. Example 65 70 alkyl silicate 5 Spraying poor Comp. Example 66 64 alkali silicate 12 Brushing poor Comp. Example 67 42 alkyl silicate 15 Brushing poor Comp. Example 68 38 alkali silicate 13 Brushing poor Comp. Example 69 44 alkyl silicate 22 Spraying poor Comp. Example 70 56 alkali silicate 34 Spraying poor Comp. Example 71 76 alkyl silicate 15 Brushing poor Comp. Example 72 65 alkyl silicate 15 Spraying poor (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 54 Zn-Alloy Particle Properties Mg Solid- Solution Average Phase & Zn—Mg MgZn₂, Fracture Value Intermetallic Mg₂Zn₁₁, Facet Mean of Compounds on Mg₂Zn3, Mg &/or Size Aspect Al Si Surface of MgZn, or # of (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg7Zn3 facets Inv. Example 2248 7.5 FC 5.07 1.42 0 0 Existence Existence 2 Inv. Example 2249 8.06 FC 7.72 1.38 0 0 Existence Existence 2 Inv. Example 2250 9.3 FC 8.32 1.22 0 0 Existence No 2 Inv. Example 2251 3.5 FC 3.04 1.02 0 0 Existence Existence 2 Inv. Example 2252 2.7 FC 4.12 1.21 0 0 Existence No 6 Inv. Example 2253 9.2 FC 7.81 1.47 0 0 Existence Existence 6 Inv. Example 2254 8.1 FC 1.45 1.31 0 0 Existence No 7 Inv. Example 2255 7.5 FC 9.6 1.07 0 0 Existence Existence 6 Inv. Example 2256 4.5 FC 8.5 1.42 0 0 Existence No 2 Inv. Example 2257 3.6 FC 3.2 1.05 0 0 Existence No 7 Inv. Example 2258 4.2 FC 5.7 1.02 1.5 0 Existence Existence 2 Inv. Example 2259 4.3 FC 6.4 1.06 5.5 1.6 Existence No 6 Inv. Example 2260 4 FC 3.2 1.05 0 0 Existence Existence 6 Inv. Example 2261 6.4 FC 5.2 1.33 0 0 Existence Existence 2 Inv. Example 2262 9.8 FC 5.2 1.33 0 0 Existence No 2 Inv. Example 2263 7.5 FC 5.07 1.42 0 0 Existence No 7 Inv. Example 2264 8.4 FC 7.72 1.38 0.5 0 Existence Existence 6 Inv. Example 2265 2.7 FC 4.12 1.21 0 0 Existence No 7 Inv. Example 2266 2.64 FC 5.5 1.22 0 0 Existence No 2 Inv. Example 2267 1.59 FC 6.7 1.14 0 0 Existence Existence 7 Inv. Example 2268 2.58 FC 8.9 1.13 0 0 Existence Existence 6 Inv. Example 2269 7.55 FC 2.15 1.14 0 0 Existence Existence 7 Inv. Example 2270 8.01 FC 2.54 1.13 0 0 Existence No 6 Inv. Example 2271 1.06 FC 3.4 1.38 0 0 Existence Existence 7 Inv. Example 2272 2.64 FC 5.5 1.22 0 0 Existence Existence 6 Inv. Example 2273 1.59 FC 6.7 1.14 0 0 Existence Existence 2 Inv. Example 2274 20.5 FC 2.15 1.14 1.5 0 Existence No 7 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 2248 74 alkali silicate 24 Brushing very good Inv. Example 2249 82 alkyl silicate 25 Spraying very good Inv. Example 2250 37 alkali silicate 14 Spraying very good Inv. Example 2251 48 alkali silicate 15 Spraying very good Inv. Example 2252 32 alkali silicate 15 Spraying very good Inv. Example 2253 45 alkyl silicate 15 Brushing very good Inv. Example 2254 37 epoxy-based resin 5 Spraying good Inv. Example 2255 72 urethane-based resin 150 Spraying very good Inv. Example 2256 40 alkali silicate 18 Spraying very good Inv. Example 2257 40 alkali silicate 18 Spraying very good Inv. Example 2258 72 alkyl silicate 58 Spraying very good Inv. Example 2259 40 alkyl silicate 21 Spraying very good Inv. Example 2260 36 alkali silicate 19 Brushing very good Inv. Example 2261 53 alkyl silicate 77 Spraying very good Inv. Example 2262 53 alkyl silicate 77 Spraying very good Inv. Example 2263 66 alkali silicate 13 Brushing very good Inv. Example 2264 67 alkyl silicate 22 Brushing very good Inv. Example 2265 57 alkali silicate 15 Spraying very good Inv. Example 2266 43 alkyl silicate 16 Spraying very good Inv. Example 2267 76 alkyl silicate 5 Spraying very good Inv. Example 2268 49 alkyl silicate 22 Spraying very good Inv. Example 2269 75 alkyl silicate 18 Spraying very good Inv. Example 2270 73 alkyl silicate 16 Spraying very good Inv. Example 2271 49 alkyl silicate 8 Spraying very good Inv. Example 2272 43 alkyl silicate 16 Spraying very good Inv. Example 2273 76 alkyl silicate 5 Spraying very good Inv. Example 2274 75 alkyl silicate 18 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 55 Zn-Alloy Particle Properties Mg Solid- Solution Average Phase & Zn—Mg MgZn₂, Fracture Value Intermetallic Mg₂Zn₁₁, Facet Mean of Compounds on Mg₂Zn3, Mg &/or Size Aspect Al Si Surface of MgZn, or # of (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg7Zn3 facets Inv. Example 2275 18.5 FC 2.54 1.13 5.5 1.6 Existence Existence 6 Inv. Example 2276 9.51 FC 2.77 1.38 4.5 0 Existence Existence 6 Inv. Example 2277 10.01 FC 3.68 1.22 0 1.6 Existence Existence 6 Inv. Example 2278 3.54 FC 5.5 1.22 0 0 Existence No 2 Inv. Example 2279 4.05 FC 2.06 1.13 0 0 Existence Existence 6 Inv. Example 2280 8.57 FC 4.99 1.02 0 0 Existence Existence 7 Inv. Example 2281 0.01 FC 6.4 1.06 0 0 Existence No 2 Inv. Example 2282 25.5 FC 3.09 1.07 0 0 Existence Existence 6 Inv. Example 2283 2.36 FC 3.99 1.22 0 0 Existence No 2 Inv. Example 2284 0.05 FC 7.72 1.38 0 0 Existence Existence 6 Inv. Example 2285 0.04 FC 8.32 1.22 0 0 Existence No 7 Inv. Example 2286 5.22 FC 3.55 1.12 0 0 Existence Existence 7 Inv. Example 2287 4.01 FC 2.64 1.23 0 0 Existence Existence 2 Inv. Example 2288 0.05 FC 5.2 1.33 0 0 Existence Existence 2 Inv. Example 2289 0.04 FC 1.9 1.27 0 0 Existence Existence 6 Inv. Example 2290 0.05 FC 2.5 1.05 0 1.2 Existence No 7 Inv. Example 2291 0.07 FC 0.09 1.12 0 0.6 Existence No 6 Inv. Example 2292 2.64 FC 5.5 1.22 0 0.01 Existence No 7 Inv. Example 2293 0.08 FC 5.6 1.36 1.5 0 Existence Existence 6 Inv. Example 2294 0.09 FC 11.5 1.11 5.5 1.6 Existence No 2 Inv. Example 2295 0.05 FC 19.5 1.07 4.5 0 Existence Existence 2 Inv. Example 2296 1.59 FC 6.7 1.14 0 0.1 Existence Existence 6 Inv. Example 2297 2.58 FC 8.9 1.13 0.01 0 Existence Existence 7 Inv. Example 2298 0.06 FC 8.32 1.22 3.2 0.9 Existence Existence 6 Inv. Example 2299 0.18 FC 10.05 1.14 0 0.5 Existence Existence 6 Inv. Example 2300 7.55 FC 2.15 1.14 0.2 0.1 Existence Existence 2 Inv. Example 2301 0.01 FC 0.06 1.23 1.2 0.6 Existence No 7 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 2275 73 alkyl silicate 16 Spraying very good Inv. Example 2276 55 alkyl silicate 5 Spraying very good Inv. Example 2277 48 alkyl silicate 22 Spraying very good Inv. Example 2278 78 alkyl silicate 18 Spraying very good Inv. Example 2279 52 alkyl silicate 8 Spraying very good Inv. Example 2280 61 alkyl silicate 16 Spraying very good Inv. Example 2281 77 polyester resin 47 Spraying very good Inv. Example 2282 49 alkyl silicate 22 Spraying very good Inv. Example 2283 80 alkyl silicate 21 Spraying very good Inv. Example 2284 36 alkyl silicate 19 Brushing very good Inv. Example 2285 32 alkyl silicate 24 Spraying very good Inv. Example 2286 55 alkyl silicate 19 Spraying very good Inv. Example 2287 40 alkyl silicate 8 Spraying very good Inv. Example 2288 53 urethane-based resin 20 Brushing very good Inv. Example 2289 60 polyester resin 200 Brushing very good Inv. Example 2290 38 alkali silicate 19 Spraying very good Inv. Example 2291 49 alkyl silicate 11 Spraying very good Inv. Example 2292 43 alkyl silicate 16 Spraying very good Inv. Example 2293 66 alkyl silicate 16 Brushing very good Inv. Example 2294 67 alkali silicate 33 Brushing very good Inv. Example 2295 54 alkyl silicate 8 Brushing good Inv. Example 2296 76 alkyl silicate 5 Spraying very good Inv. Example 2297 49 alkyl silicate 22 Spraying very good Inv. Example 2298 32 alkyl silicate 23 Spraying very good Inv. Example 2299 53 epoxy-based resin 30 Spraying very good Inv. Example 2300 75 alkyl silicate 18 Spraying very good Inv. Example 2301 75 alkali silicate 5 Spraying good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 56 Zn-Alloy Particle Properties Mg Solid- Solution Average Phase & Zn—Mg MgZn₂, Fracture Value Intermetallic Mg₂Zn₁₁, Facet Mean of Compounds on Mg₂Zn3, Mg &/or Size Aspect Al Si Surface of MgZn, or # of (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg7Zn3 facets Inv. Example 2302 12.5 FC 2.54 1.13 0.5 0 Existence Existence 2 Inv. Example 2303 1.06 FC 3.4 1.38 1.5 0.9 Existence Existence 2 Inv. Example 2304 0.04 FC 8.5 1.42 0 1.2 Existence No 6 Inv. Example 2305 0.06 FC 7.72 1.38 0 0.6 Existence Existence 7 Inv. Example 2306 9.51 FC 2.77 1.38 0 0.01 Existence No 7 Inv. Example 2307 15.5 FC 3.68 1.22 1.5 0 Existence Existence 6 Inv. Example 2308 0.05 FC 10.6 1.13 5.5 1.6 Existence No 7 Inv. Example 2309 0.07 FC 5.7 1.02 4.5 0 Existence No 7 Inv. Example 2310 3.54 FC 5.5 1.22 0 0.1 Existence Existence 6 Inv. Example 2311 0.08 FC 3.2 1.05 0.01 0 Existence Existence 7 Inv. Example 2312 0.07 FC 4.5 1.24 3.2 0.9 Existence Existence 2 Inv. Example 2313 15.5 FC 2.54 1.14 0 0.5 Existence No 7 Inv. Example 2314 4.05 FC 2.06 1.13 0.2 0.1 Existence Existence 7 Inv. Example 2315 8.57 FC 4.99 1.02 1.2 0.6 Existence No 2 Inv. Example 2316 0.01 FC 6.4 1.06 0.5 0 Existence Existence 6 Inv. Example 2317 4.59 FC 3.09 1.07 1.5 0.9 Existence No 6 Inv. Example 2318 9.88 FC 4.66 1.42 0 1.2 Existence No 7 Inv. Example 2319 4.55 FC 4.09 1.38 0 0.6 Existence Existence 7 Inv. Example 2320 2.36 FC 3.99 1.22 0 0.01 Existence No 6 Inv. Example 2321 0.05 FC 7.72 1.38 1.5 0 Existence Existence 7 Inv. Example 2322 0.04 FC 8.32 1.22 5.5 1.6 Existence Existence 2 Inv. Example 2323 2.64 FC 4.55 1.11 4.5 0 Existence No 2 Inv. Example 2324 0.06 FC 10.6 1.13 0 0.1 Existence No 6 Inv. Example 2325 0.18 FC 5.7 1.02 0.01 0 Existence Existence 7 Inv. Example 2326 6.31 FC 3.52 1.27 3.2 0.9 Existence No 6 Inv. Example 2327 5.22 FC 3.55 1.12 0 0.5 Existence No 2 Inv. Example 2328 28.5 FC 2.64 1.23 0.2 0.1 Existence Existence 2 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 2302 73 alkyl silicate 16 Spraying very good Inv. Example 2303 49 alkyl silicate 8 Spraying very good Inv. Example 2304 40 alkali silicate 2 Spraying very good Inv. Example 2305 36 alkyl silicate 18 Spraying very good Inv. Example 2306 55 alkyl silicate 5 Spraying very good Inv. Example 2307 48 alkyl silicate 22 Spraying very good Inv. Example 2308 67 acryl-based resin 77 Brushing very good Inv. Example 2309 72 urethane-based resin 54 Brushing very good Inv. Example 2310 78 alkyl silicate 18 Spraying very good Inv. Example 2311 34 epoxy-based resin 43 Spraying very good Inv. Example 2312 43 acryl-based resin 52 Brushing very good Inv. Example 2313 45 alkyl silicate 19 Spraying very good Inv. Example 2314 52 alkyl silicate 8 Spraying very good Inv. Example 2315 61 alkyl silicate 16 Spraying very good Inv. Example 2316 77 polyester resin 47 Spraying very good Inv. Example 2317 49 alkyl silicate 22 Spraying very good Inv. Example 2318 79 alkyl silicate 18 Spraying very good Inv. Example 2319 76 alkyl silicate 18 Spraying very good Inv. Example 2320 80 alkyl silicate 21 Spraying very good Inv. Example 2321 36 alkyl silicate 19 Brushing very good Inv. Example 2322 32 alkyl silicate 24 Spraying very good Inv. Example 2323 43 alkyl silicate 5 Spraying very good Inv. Example 2324 67 alkyl silicate 7 Spraying very good Inv. Example 2325 72 epoxy-based resin 100 Spraying very good Inv. Example 2326 51 alkyl silicate 21 Spraying very good Inv. Example 2327 55 alkyl silicate 19 Spraying very good Inv. Example 2328 40 alkyl silicate 8 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 57 Zn-Alloy Particle Properties Mg Solid- Solution Average Phase & Zn—Mg MgZn₂, Fracture Value Intermetallic Mg₂Zn₁₁, Facet Mean of Compounds on Mg₂Zn3, Mg &/or Size Aspect Al Si Surface of MgZn, or # of (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg7Zn3 facets Inv. Example 2329 3.52 FC 3.15 1.36 1.2 0.6 Existence Existence 7 Inv. Example 2330 0.05 FC 5.2 1.33 0.5 0 Existence Existence 6 Inv. Example 2331 0.04 FC 1.9 1.27 1.5 0.9 Existence No 7 Inv. Example 2332 0.06 FC 10.5 1.12 0 1.2 Existence Existence 7 Inv. Example 2333 0.05 FC 12.5 1.23 0 0.6 Existence Existence 6 Inv. Example 2334 0.07 FC 18.5 1.36 0 0.01 Existence Existence 2 Inv. Example 2335 0.01 FC 11.5 1.11 1.5 0 Existence No 7 Inv. Example 2336 0.08 FC 9.6 1.07 5.5 1.6 Existence Existence 2 Inv. Example 2337 0.03 FC 8.5 1.42 4.5 0 Existence Existence 2 Inv. Example 2338 4.25 FC 2.36 1.33 0 0.1 Existence Existence 7 Inv. Example 2339 0.04 FC 23.5 1.42 0.01 0 Existence No 2 Inv. Example 2340 0.06 FC 101.5 1.38 3.2 0.9 Existence Existence 7 Inv. Example 2341 0.06 FC 55.4 1.38 0 0.5 Existence Existence 2 Inv. Example 2342 0.07 FC 10.5 1.12 0.2 0.1 Existence No 6 Inv. Example 2343 0.01 FC 12.5 1.23 1.2 0.6 Existence Existence 6 Inv. Example 2344 0.08 FC 18.5 1.36 0.5 0 Existence No 7 Inv. Example 2345 0.09 FC 11.5 1.11 1.5 0.9 Existence Existence 6 Inv. Example 2346 0.05 FC 9.6 1.07 0.5 0 Existence No 2 Inv. Example 2347 0.06 FC 10.05 1.14 1.5 0.9 Existence Existence 2 Inv. Example 2348 29.9 FC 10.5 1.36 0 0 Existence Existence 2 Inv. Example 2349 16.5 FC 7.5 1.11 0.01 0 Existence Existence 7 Inv. Example 2350 12.5 FC 2.6 1.07 3.2 0.9 Existence No 2 Inv. Example 2351 9.8 FC 3.5 1.42 0 0.5 Existence Existence 6 Inv. Example 2352 9.6 FC 4.5 1.33 0.2 0.1 Existence No 6 Inv. Example 2353 7.5 FC 1.6 1.42 0 0.5 Existence Existence 2 Inv. Example 2354 4.6 FC 2.5 1.12 5.8 0.1 Existence Existence 7 Inv. Example 2355 3.8 FC 23.5 1.23 1.2 0.6 Existence Existence 6 Inv. Example 2356 0.05 FC 9.8 1.27 15.5 0 Existence Existence 6 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 2329 51 alkyl silicate 16 Spraying very good Inv. Example 2330 53 urethane-based resin 20 Brushing very good Inv. Example 2331 60 polyester resin 200 Brushing very good Inv. Example 2332 77 alkyl silicate 25 Spraying very good Inv. Example 2333 43 alkali silicate 14 Spraying very good Inv. Example 2334 52 urethane-based resin 112 Spraying very good Inv. Example 2335 66 alkali silicate 24 Spraying very good Inv. Example 2336 72 urethane-based resin 150 Spraying very good Inv. Example 2337 40 alkali silicate 18 Spraying very good Inv. Example 2338 44 alkyl silicate 18 Spraying very good Inv. Example 2339 44 alkali silicate 38 Spraying very good Inv. Example 2340 36 alkyl silicate 18 Spraying very good Inv. Example 2341 76 alkyl silicate 10 Spraying very good Inv. Example 2342 77 alkyl silicate 37 Spraying very good Inv. Example 2343 43 alkali silicate 2 Spraying good Inv. Example 2344 52 alkyl silicate 160 Brushing very good Inv. Example 2345 66 alkali silicate 5 Brushing very good Inv. Example 2346 72 alkyl silicate 56 Brushing very good Inv. Example 2347 53 urethane-based resin 99 Spraying very good Inv. Example 2348 55 urethane-based resin 700 Spraying very good Inv. Example 2349 47 alkyl silicate 554 Spraying very good Inv. Example 2350 79 urethane-based resin 688 Brushing very good Inv. Example 2351 42 urethane-based resin 421 Spraying very good Inv. Example 2352 36 urethane-based resin 651 Spraying very good Inv. Example 2353 53 urethane-based resin 402 Brushing very good Inv. Example 2354 55 alkali silicate 354 Spraying very good Inv. Example 2355 42 urethane-based resin 504 Brushing very good Inv. Example 2356 76 urethane-based resin 666 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

Example 5

Zn alloy particles with the chemical ingredients shown Tables 58 to 75 were produced in the same way as in Example 1. Zn metal particles of an average particle size 0.05 to 50 μm were mixed in the paints. The rest is the same as Example 1.

From Tables 58 to 75, it is learned that the painting test pieces using the Zn alloy particles and Zn metal particles of the present invention are improved in corrosion resistance and rust prevention regardless of the type of base resin, that is, both for inorganic-based and organic-based binders.

TABLE 58 Zn-Alloy Particle Properties Average Mean Size of Zn Blend Ratio Mg Contents to Fracture Value of Metallic (Zn Alloy Total Metal Mg Facet &/or Mean Size Aspect particle particle:Zn Particle (mass %) Cracks (*1) (μm) Ratio (μm) Metal Particle) (mass %) Inv. Example 191 12.3 F 0.02 1.05 2.04 300:1 12.26 Inv. Example 192 0.8 F 27.89 1.12 50.00   1:99 0.01 Inv. Example 193 1 F 0.32 1.23 2.45 100:1 0.99 Inv. Example 194 2.3 F 11.44 1.36 5.33 200:1 2.29 Inv. Example 195 15.6 F 1.05 1.11 2.41 100:1 15.45 Inv. Example 196 6.7 F 36.47 1.07 23.43 150:1 6.66 Inv. Example 197 7.5 F 5.07 1.42 6.03  3:1 5.63 Inv. Example 198 8.4 F 7.72 1.38 24.5  80:1 8.30 Inv. Example 199 9.3 F 8.32 1.22 5.32   1:15 0.58 Inv. Example 200 10.4 F 10.05 1.14 14.34   1:30 0.34 Inv. Example 201 11.2 F 6.08 1.13 5.04   1:45 0.24 Inv. Example 202 11.7 F 17.89 1.02 2.32   1:55 0.21 Inv. Example 203 21.5 F 19.54 1.06 20.34   1:65 0.33 Inv. Example 204 13.4 F 21.08 1.05 12.33   1:75 0.18 Inv. Example 205 14.6 F 23.04 1.24 17.84 110:1 14.47 Inv. Example 206 25.8 F 9.21 1.33 6.66 115:1 25.58 Inv. Example 207 16.7 F 0.12 1.27 3.65  70:1 16.46 Inv. Example 208 17.3 F 29.24 1.37 22.62  80:1 17.09 Inv. Example 209 18.5 F 128.74 1.10 45.33  65:1 18.22 Inv. Example 210 19.3 F 33.57 1.04 43.22  70:1 19.03 Inv. Example 211 3.5 F 3.04 1.02 12.33 300:1 3.49 Inv. Example 212 22.5 F 7.54 1.01 13.42 300:1 22.43 Inv. Example 213 23.7 F 6.81 1.08 22.32  70:1 23.37 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 191 52 alkali silicate 2 Spraying very good Inv. Example 192 55 alkyl silicate 33 Spraying very good Inv. Example 193 69 alkali silicate 5 Spraying very good Inv. Example 194 78 alkyl silicate 20 Spraying very good Inv. Example 195 42 alkali silicate 15 Brushing very good Inv. Example 196 32 alkyl silicate 57 Brushing very good Inv. Example 197 66 alkali silicate 13 Brushing very good Inv. Example 198 67 alkyl silicate 22 Brushing very good Inv. Example 199 64 alkali silicate 20 Spraying very good Inv. Example 200 74 alkyl silicate 27 Spraying very good Inv. Example 201 82 alkali silicate 15 Spraying very good Inv. Example 202 37 alkyl silicate 35 Spraying very good Inv. Example 203 42 alkali silicate 34 Brushing very good Inv. Example 204 66 alkyl silicate 45 Brushing very good Inv. Example 205 48 alkali silicate 52 Brushing very good Inv. Example 206 33 alkyl silicate 23 Brushing very good Inv. Example 207 75 alkali silicate 5 Spraying very good Inv. Example 208 77 alkyl silicate 52 Brushing very good Inv. Example 209 66 alkali silicate 150 Brushing very good Inv. Example 210 67 alkyl silicate 60 Brushing very good Inv. Example 211 45 alkali silicate 15 Spraying very good Inv. Example 212 48 alkyl silicate 24 Spraying very good Inv. Example 213 68 alkali silicate 34 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 59 Zn-Alloy Particle Properties Average Mean Size of Zn Blend Ratio Mg Contents to Fracture Value of Metallic (Zn Alloy Total Metal Mg Facet &/or Mean Size Aspect particle particle:Zn Particle (mass %) Cracks (*1) (μm) Ratio (μm) Metal Particle) (mass %) Inv. Example 214 24.2 F 5.25 1.14 7.34 300:1 24.12 Inv. Example 215 0.2 F 194.23 1.23 44.54 100:1 0.20 Inv. Example 216 27.1 F 28.74 1.33 32.87 250:1 26.99 Inv. Example 217 29.3 F 13.57 1.37 20.32 150:1 29.11 Inv. Example 218 0.5 F 0.65 1.44 2.03 170:1 0.50 Inv. Example 219 2.7 F 4.12 1.21 5.33 300:1 2.69 Inv. Example 220 28.4 F 0.72 1.22 2.33 200:1 28.26 Inv. Example 221 8.7 F 117.54 1.23 27.44  65:1 8.57 Inv. Example 222 9.2 F 7.81 1.47 12.33 300:1 9.17 Inv. Example 223 17.8 F 80.25 1.01 36.43 120:1 17.65 Inv. Example 224 20.2 F 8.47 1.04 12.33 300:1 20.13 Inv. Example 225 0.4 F 0.87 1.05 3.21 300:1 0.40 Inv. Example 226 13.7 F 25.78 1.12 26.33 300:1 13.65 Inv. Example 227 14.7 F 93.45 1.11 44.21  70:1 14.49 Inv. Example 228 2.4 F 0.97 1.08 3.43  80:1 2.37 Inv. Example 229 4.5 F 54.89 1.47 47.32 300:1 4.49 Inv. Example 230 0.1 F 10.81 1.50 12.33  70:1 0.10 Inv. Example 231 30.0 F 18.24 1.13 17.44  65:1 29.55 Inv. Example 232 24.5 F 114.78 1.04 42.21 300:1 24.42 Inv. Example 233 27.6 F 3.87 1.02 12.34 300:1 27.51 Inv. Example 234 4.1 F 11.94 1.08 20.32 300:1 4.09 Inv. Example 235 3.2 F 142.58 1.15 23.44  65:1 3.15 Inv. Example 236 2.7 F 12.5 1.34 23.45 300:1 2.69 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 214 35 alkyl silicate 20 Brushing very good Inv. Example 215 37 alkali silicate 200 Brushing very good Inv. Example 216 38 alkyl silicate 56 Brushing very good Inv. Example 217 41 alkali silicate 34 Spraying very good Inv. Example 218 54 alkyl silicate 2 Spraying very good Inv. Example 219 57 alkali silicate 15 Spraying very good Inv. Example 220 59 alkali silicate 10 Spraying very good Inv. Example 221 64 alkyl silicate 125 Brushing very good Inv. Example 222 66 alkali silicate 24 Brushing very good Inv. Example 223 67 alkyl silicate 110 Brushing very good Inv. Example 224 34 alkali silicate 24 Brushing very good Inv. Example 225 54 alkyl silicate 2 Spraying very good Inv. Example 226 62 alkali silicate 37 Spraying very good Inv. Example 227 66 alkyl silicate 113 Brushing very good Inv. Example 228 67 alkali silicate 2 Spraying very good Inv. Example 229 68 alkyl silicate 75 Brushing very good Inv. Example 230 33 alkali silicate 30 Brushing very good Inv. Example 231 35 alkyl silicate 34 Brushing very good Inv. Example 232 43 epoxy-based 124 Brushing very good resin Inv. Example 233 44 acryl-based 15 Spraying very good resin Inv. Example 234 43 urethane- 23 Spraying very good based resin Inv. Example 235 44 polyester 157 Brushing very good resin Inv. Example 236 54 epoxy-based 26 Spraying very good resin (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 60 Zn-Alloy Particle Properties Average Mean Size of Zn Blend Ratio Mg Contents to Fracture Value of Metallic (Zn Alloy Total Metal Mg Facet &/or Mean Size Aspect particle particle:Zn Particle (mass %) Cracks (*1) (μm) Ratio (μm) Metal Particle) (mass %) Inv. Example 237 0.12 F 31.24 1.25 23.21 150:1 0.12 Inv. Example 238 0.22 F 152.46 1.19 39.44 300:1 0.22 Inv. Example 239 0.37 F 13.4 1.18 12.34  65:1 0.36 Inv. Example 240 1.4 F 160.57 1.24 29.99 300:1 1.40 Inv. Example 241 4.2 F 14.1 1.11 15.21 300:1 4.19 Inv. Example 242 4.8 F 167.55 1.27 23.34  65:1 4.73 Inv. Example 243 8.1 F 1.45 1.31 2.32 300:1 8.07 Inv. Example 244 7.6 F 0.15 1.26 4.21  65:1 7.48 Inv. Example 245 9.9 F 13.1 1.14 12.22 300:1 9.87 Inv. Example 246 14.8 F 15.5 1.34 13.45 150:1 14.70 Inv. Example 247 16.7 F 0.67 1.16 2.34 300:1 16.64 Inv. Example 248 17.9 F 137.89 1.47 28.34  65:1 17.63 Inv. Example 249 19.5 F 16.3 1.48 19.87 300:1 19.44 Inv. Example 250 22.4 F 110.38 1.49 39.74 150:1 22.25 Inv. Example 251 0.17 F 12.4 1.34 24.32 300:1 0.17 Inv. Example 252 8.3 F 17.2 1.29 22.33  65:1 8.17 Inv. Example 253 6.5 F 105.23 1.18 48.54 300:1 6.48 Inv. Example 254 9.7 F 177.89 1.23 23.75 300:1 9.67 Inv. Example 255 11.4 F 12.2 1.27 15.62  65:1 11.23 Inv. Example 256 22.5 F 1.84 1.17 2.34 300:1 22.43 Inv. Example 257 25.7 F 16.02 1.16 23.04 300:1 25.61 Inv. Example 258 17.8 F 1.75 1.49 3.05 150:1 17.68 Inv. Example 259 0.14 F 198.78 1.34 43.23 300:1 0.14 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 237 79 acryl-based resin 38 Spraying very good Inv. Example 238 73 urethane-based 160 Brushing very good resin Inv. Example 239 69 polyester resin 27 Brushing very good Inv. Example 240 63 epoxy-based resin 180 Brushing very good Inv. Example 241 35 acryl-based resin 26 Spraying very good Inv. Example 242 35 urethane based 180 Brushing very good resin Inv. Example 243 66 polyester resin 15 Spraying very good Inv. Example 244 67 epoxy-based resin 2 Spraying very good Inv. Example 245 68 acryl-based resin 28 Spraying very good Inv. Example 246 33 urethane-based 30 Spraying very good resin Inv. Example 247 35 polyester resin 2 Spraying very good Inv. Example 248 43 epoxy-based resin 157 Brushing very good Inv. Example 249 44 acryl-based resin 28 Brushing very good Inv. Example 250 42 urethane-based 130 Brushing very good resin Inv. Example 251 33 polyester resin 29 Brushing very good Inv. Example 252 30 epoxy-based resin 30 Brushing very good Inv. Example 253 35 acryl-based resin 120 Brushing very good Inv. Example 254 37 urethane-based 187 Brushing very good resin Inv. Example 255 77 polyester resin 28 Spraying very good Inv. Example 256 41 epoxy-based resin 5 Spraying very good Inv. Example 257 35 acryl-based resin 35 Spraying very good Inv. Example 258 58 urethane-based 5 Spraying very good resin Inv. Example 259 37 polyester resin 200 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 61 Zn-Alloy Particle Properties Average Mean Size of Zn Blend Ratio Mg Contents to Fracture Value of Metallic (Zn Alloy Total Metal Mg Facet &/or Mean Size Aspect particle particle:Zn Particle (mass %) Cracks (*1) (μm) Ratio (μm) Metal Particle) (mass %) Inv. Example 1193 0.15 FC 0.02 1.05 2.04  5:2 0.11 Inv. Example 1194 0.19 FC 10.5 1.12 50.00  7:1 0.17 Inv. Example 1195 0.18 FC 12.5 1.23 2.45  68:1 0.18 Inv. Example 1196 0.11 FC 18.5 1.36 5.33  10:1 0.10 Inv. Example 1197 0.15 FC 11.5 1.11 2.41  25:7 0.12 Inv. Example 1198 0.24 FC 9.6 1.07 23.43 300:9 0.23 Inv. Example 1199 0.18 FC 8.5 1.42 6.03 180:1 0.18 Inv. Example 1200 0.12 FC 7.72 1.38 24.5  23:1 0.12 Inv. Example 1201 0.19 FC 8.32 1.22 5.32 165:1 0.19 Inv. Example 1202 0.18 FC 10.05 1.14 14.34 300:1 0.18 Inv. Example 1203 0.21 FC 10.6 1.13 5.04 120:1 0.21 Inv. Example 1204 0.76 FC 5.7 1.02 2.32  2:9 0.14 Inv. Example 1205 0.11 FC 6.4 1.06 20.34 119:3 0.11 Inv. Example 1206 0.14 FC 3.2 1.05 12.33 233:1 0.14 Inv. Example 1207 15 FC 4.5 1.24 17.84   1:132 0.11 Inv. Example 1208 14.5 FC 5.2 1.33 6.66   1:55 10.24 Inv. Example 1209 18.5 FC 1.9 1.27 3.65   1:23 0.77 Inv. Example 1210 15.1 FC 0.02 1.05 22.62 200:1 15.02 Inv. Example 1211 15.6 FC 10.5 1.12 45.33   1:15 0.98 Inv. Example 1212 12.5 FC 12.5 1.23 43.22   1:10 1.14 Inv. Example 1213 18.7 FC 18.5 1.36 12.33  1:6 2.67 Inv. Example 1214 14.5 FC 11.5 1.11 13.42   1:45 0.32 Inv. Example 1215 7.5 FC 9.6 1.07 22.32   1:50 0.15 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 1193 35 alkali silicate 2 Spraying very good Inv. Example 1194 77 alkyl silicate 37 Spraying very good Inv. Example 1195 43 alkali silicate 2 Spraying good Inv. Example 1196 52 alkyl silicate 160 Brushing very good Inv. Example 1197 66 alkali silicate 5 Brushing very good Inv. Example 1198 72 alkyl silicate 56 Brushing very good Inv. Example 1199 40 alkali silicate 2 Spraying very good Inv. Example 1200 36 alkyl silicate 18 Spraying very good Inv. Example 1201 32 alkyl silicate 23 Spraying very good Inv. Example 1202 53 epoxy-based resin 30 Brushing very good Inv. Example 1203 67 acryl-based resin 77 Brushing very good Inv. Example 1204 72 urethane-based 54 Brushing very good resin Inv. Example 1205 77 polyester resin 47 Spraying very good Inv. Example 1206 34 epoxy-based resin 43 Spraying very good Inv. Example 1207 43 acryl-based resin 52 Brushing very good Inv. Example 1208 53 urethane-based 20 Brushing very good resin Inv. Example 1209 60 polyester resin 200 Brushing very good Inv. Example 1210 35 alkali silicate 22 Spraying very good Inv. Example 1211 77 alkyl silicate 25 Spraying very good Inv. Example 1212 43 alkali silicate 14 Spraying very good Inv. Example 1213 52 urethane-based 112 Spraying very good resin Inv. Example 1214 66 alkali silicate 24 Spraying very good Inv. Example 1215 72 urethane-based 150 Spraying very good resin (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 62 Zn-Alloy Particle Properties Average Mean Size of Zn Blend Ratio Mg Contents to Fracture Value of Metallic (Zn Alloy Total Metal Mg Facet &/or Mean Size Aspect particle particle:Zn Particle (mass %) Cracks (*1) (μm) Ratio (μm) Metal Particle) (mass %) Inv. Example 1216 4.5 FC 8.5 1.42 7.34 1:9 0.45 Inv. Example 1217 1.5 FC 7.72 1.38 44.54 1:7 0.19 Inv. Example 1218 4.8 FC 8.32 1.22 32.87 1:4 0.96 Inv. Example 1219 9.6 FC 10.05 1.14 20.32  1:14 0.64 Inv. Example 1220 11.5 FC 10.6 1.13 2.03  1:11 0.96 Inv. Example 1221 9.8 FC 5.7 1.02 5.33  1:28 0.34 Inv. Example 1222 7.6 FC 6.4 1.06 2.33 1:4 1.52 Inv. Example 1223 3.2 FC 3.2 1.05 27.44 250:1  3.19 Inv. Example 1224 1.9 FC 4.5 1.24 12.33 1:1 0.95 Inv. Example 1225 11.5 FC 5.2 1.33 36.43 1:4 2.30 Inv. Example 1226 8.7 FC 1.9 1.27 12.33  1:12 0.67 Inv. Example 1227 9.6 FC 0.02 1.05 3.21 70:1  9.46 Inv. Example 1228 9.4 FC 10.5 1.12 26.33 1:3 2.35 Inv. Example 1229 10.5 FC 12.5 1.23 44.21  1:24 0.42 Inv. Example 1230 12.6 FC 18.5 1.36 3.43  1:10 1.15 Inv. Example 1231 29.5 FC 11.5 1.11 47.32 300:1  29.40 Inv. Example 1232 29.4 FC 9.6 1.07 12.33  1:66 0.44 Inv. Example 1233 27.5 FC 8.5 1.42 17.44 120:1  27.27 Inv. Example 1234 0.8 FC 7.72 1.38 42.21 6:5 0.44 Inv. Example 1235 1.6 FC 8.32 1.22 12.34 1:1 0.80 Inv. Example 1236 22.9 FC 10.05 1.14 20.32 1:1 11.45 Inv. Example 1237 28.5 FC 10.6 1.13 23.44  1:76 0.37 Inv. Example 1238 29.5 FC 5.7 1.02 23.45 1:6 4.21 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 1216 40 alkali silicate 18 Spraying very good Inv. Example 1217 36 alkyl silicate 19 Brushing very good Inv. Example 1218 32 alkyl silicate 24 Spraying very good Inv. Example 1219 53 urethane-based 99 Spraying very good resin Inv. Example 1220 67 alkyl silicate 7 Spraying very good Inv. Example 1221 72 epoxy-based resin 100 Spraying very good Inv. Example 1222 77 alkyl silicate 27 Brushing very good Inv. Example 1223 34 alkali silicate 15 Spraying very good Inv. Example 1224 43 alkyl silicate 14 Spraying very good Inv. Example 1225 53 urethane-based 55 Spraying very good resin Inv. Example 1226 35 alkyl silicate 8 Spraying very good Inv. Example 1227 77 urethane-based 122 Brushing very good resin Inv. Example 1228 43 alkyl silicate 54 Spraying very good Inv. Example 1229 52 alkali silicate 19 Spraying very good Inv. Example 1230 66 alkyl silicate 25 Brushing very good Inv. Example 1231 72 alkyl silicate 58 Spraying very good Inv. Example 1232 40 alkyl silicate 21 Spraying very good Inv. Example 1233 36 alkali silicate 19 Brushing very good Inv. Example 1234 32 urethane-based 56 Spraying very good resin Inv. Example 1235 53 alkyl silicate 77 Spraying very good Inv. Example 1236 67 alkyl silicate 54 Spraying very good Inv. Example 1237 72 alkyl silicate 64 Spraying very good Inv. Example 1238 77 alkyl silicate 34 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 63 Zn-Alloy Particle Properties Average Mean Size of Zn Blend Ratio Mg Contents to Fracture Value of Metallic (Zn Alloy Total Metal Mg Facet &/or Mean Size Aspect particle particle:Zn Particle (mass %) Cracks (*1) (μm) Ratio (μm) Metal Particle) (mass %) Inv. Example 1239 18.7 FC 6.4 1.06 23.21 1:35 0.52 Inv. Example 1240 19.5 FC 3.2 1.05 39.44 1:5  3.25 Inv. Example 1241 20.4 FC 4.5 1.24 12.34 1:62 0.32 Inv. Example 1242 0.6 FC 5.2 1.33 29.99 1:4  0.12 Inv. Example 1243 0.8 FC 1.9 1.27 15.21 5:9  0.29 Inv. Example 1244 22.5 FC 0.02 1.05 23.34  1:220 0.10 Inv. Example 1245 20.6 FC 10.5 1.12 2.32 1:80 0.25 Inv. Example 1246 21.6 FC 12.5 1.23 4.21 1:50 0.42 Inv. Example 1247 20.8 FC 7.72 1.38 15.21 1:10 1.89 Inv. Example 1248 23.6 FC 8.32 1.22 23.34 1:1  11.80 Inv. Example 1249 24.5 FC 10.05 1.14 2.32 1:78 0.31 Inv. Example 1250 18.6 FC 10.6 1.13 4.21 1:10 1.69 Inv. Example 1251 17.8 FC 5.2 1.33 29.99 1:50 0.35 Inv. Example 1252 16.5 FC 1.9 1.27 15.21 1:10 1.50 Inv. Example 1253 14.5 FC 0.02 1.05 23.34 1:1  7.25 Inv. Example 1254 19 FC 10.5 1.12 2.32 1:3  4.75 Inv. Example 1255 15 FC 12.5 1.23 4.21 1:7  1.88 Inv. Example 1256 16.4 FC 18.5 1.36 15.21 1:50 0.32 Inv. Example 1257 13.5 FC 11.5 1.11 23.34 1:10 1.23 Inv. Example 1258 10.6 FC 11.5 1.11 13.45 1:3  2.65 Inv. Example 1259 10.7 FC 9.6 1.07 2.34 1:10 0.97 Inv. Example 1260 10.9 FC 8.5 1.42 28.34 1:5  1.82 Inv. Example 1261 11.6 FC 7.72 1.38 19.87 200:1   11.54 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 1239 34 alkali silicate 28 Spraying very good Inv. Example 1240 43 urethane-based 109 Brushing very good resin Inv. Example 1241 53 alkyl silicate 15 Spraying very good Inv. Example 1242 72 alkyl silicate 14 Spraying very good Inv. Example 1243 77 alkyl silicate 18 Spraying very good Inv. Example 1244 35 alkali silicate 2 Spraying very good Inv. Example 1245 77 alkyl silicate 37 Spraying very good Inv. Example 1246 43 alkali silicate 2 Spraying good Inv. Example 1247 52 alkyl silicate 160 Brushing very good Inv. Example 1248 66 alkali silicate 5 Brushing very good Inv. Example 1249 72 alkyl silicate 56 Brushing very good Inv. Example 1250 40 alkali silicate 2 Spraying very good Inv. Example 1251 36 alkyl silicate 18 Spraying very good Inv. Example 1252 32 alkyl silicate 23 Spraying very good Inv. Example 1253 53 epoxy-based resin 30 Brushing very good Inv. Example 1254 67 acryl-based resin 77 Brushing very good Inv. Example 1255 72 urethane-based 54 Brushing very good resin Inv. Example 1256 77 polyester resin 47 Spraying very good Inv. Example 1257 34 epoxy-based resin 43 Spraying very good Inv. Example 1258 43 acryl-based resin 52 Brushing very good Inv. Example 1259 53 urethane-based 20 Brushing very good resin Inv. Example 1260 60 polyester resin 200 Brushing very good Inv. Example 1261 35 alkali silicate 22 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 64 Zn-Alloy Particle Properties Average Mean Size of Zn Blend Ratio Mg Contents to Fracture Value of Metallic (Zn Alloy Total Metal Mg Facet &/or Mean Size Aspect particle particle:Zn Particle (mass %) Cracks (*1) (μm) Ratio (μm) Metal Particle) (mass %) Inv. Example 1262 14.7 FC 8.32 1.22 39.74 1:8 1.63 Inv. Example 1263 19.5 FC 10.05 1.14 24.32 1:1 9.75 Inv. Example 1264 10.2 FC 10.6 1.13 22.33 1:7 1.28 Inv. Example 1265 4 FC 5.7 1.02 48.54 1:3 1.00 Inv. Example 1266 7.2 FC 6.4 1.06 23.75 1:7 0.90 Inv. Example 1267 3.6 FC 3.2 1.05 15.62 1:2 1.20 Inv. Example 1268 26.9 FC 4.5 1.24 2.34 117:1  26.67 Inv. Example 1269 27.9 FC 5.2 1.33 23.04  1:270 0.10 Inv. Example 1270 28.9 FC 1.9 1.27 3.05  1:117 0.24 Inv. Example 1271 23.8 FC 0.02 1.05 43.23  1:66 0.36 Inv. Example 1272 26.8 FC 10.5 1.12 2.04  1:109 0.24 Inv. Example 1273 25.6 FC 12.5 1.23 50.00 250:1  25.50 Inv. Example 1274 29.8 FC 18.5 1.36 2.45 70:1  29.38 Inv. Example 1275 18.9 FC 11.5 1.11 5.33  1:15 1.18 Inv. Example 1276 5.6 FC 9.6 1.07 2.41 1:5 0.93 Inv. Example 1277 4.7 FC 8.5 1.42 23.43 2:3 1.88 Inv. Example 1278 6.8 FC 7.72 1.38 6.03 1:9 0.68 Inv. Example 1279 9 FC 8.32 1.22 24.5  1:10 0.82 Inv. Example 1280 2.1 FC 10.05 1.14 5.32  1:14 0.14 Inv. Example 1281 4.8 FC 10.6 1.13 14.34 1:7 0.60 Inv. Example 1282 4.2 FC 5.7 1.02 5.04  1:12 0.32 Inv. Example 1283 4.3 FC 6.4 1.06 2.32 1:3 1.08 Inv. Example 1284 4 FC 3.2 1.05 20.34 1:7 0.50 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 1262 77 alkyl silicate 25 Spraying very good Inv. Example 1263 43 alkali silicate 14 Spraying very good Inv. Example 1264 52 urethane-based 112 Spraying very good resin Inv. Example 1265 66 alkali silicate 24 Spraying very good Inv. Example 1266 72 urethane-based 150 Spraying very good resin Inv. Example 1267 40 alkali silicate 18 Spraying very good Inv. Example 1268 36 alkyl silicate 19 Brushing very good Inv. Example 1269 32 alkyl silicate 24 Spraying very good Inv. Example 1270 53 urethane-based 99 Spraying very good resin Inv. Example 1271 67 alkyl silicate 7 Spraying very good Inv. Example 1272 72 epoxy-based resin 100 Spraying very good Inv. Example 1273 77 alkyl silicate 27 Brushing very good Inv. Example 1274 34 alkali silicate 15 Spraying very good Inv. Example 1275 43 alkyl silicate 14 Spraying very good Inv. Example 1276 53 urethane-based 55 Spraying very good resin Inv. Example 1277 35 alkyl silicate 8 Spraying very good Inv. Example 1278 77 urethane-based 122 Brushing very good resin Inv. Example 1279 43 alkyl silicate 54 Spraying very good Inv. Example 1280 52 alkali silicate 19 Spraying very good Inv. Example 1281 66 alkyl silicate 25 Brushing very good Inv. Example 1282 72 alkyl silicate 58 Spraying very good Inv. Example 1283 40 alkyl silicate 21 Spraying very good Inv. Example 1284 36 alkali silicate 19 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 65 Zn-Alloy Particle Properties Average Mean Size of Zn Blend Ratio Mg Contents to Fracture Value of Metallic (Zn Alloy Total Metal Mg Facet &/or Mean Size Aspect particle particle:Zn Particle (mass %) Cracks (*1) (μm) Ratio (μm) Metal Particle) (mass %) Inv. Example 1285 3.7 FC 4.5 1.24 12.33  1:10 0.34 Inv. Example 1286 6.4 FC 5.2 1.33 17.84 1:1 3.20 Inv. Example 1287 6.9 FC 1.9 1.27 6.66 1:3 1.73 Inv. Example 1288 16.9 FC 0.02 1.05 3.65 2:3 6.76 Inv. Example 1289 18.7 FC 10.5 1.12 22.62 1:2 6.23 Inv. Example 1290 24.4 FC 12.5 1.23 45.33 1:4 4.88 Inv. Example 1291 10.6 FC 18.5 1.36 43.22 1:6 1.51 Inv. Example 1292 15.8 FC 11.5 1.11 12.33  1:115 0.14 Inv. Example 1293 19.5 FC 9.6 1.07 13.42  1:23 0.81 Inv. Example 1294 7.8 FC 8.5 1.42 22.32  1:12 0.60 Inv. Example 1295 4.9 FC 7.72 1.38 7.34  1:10 0.45 Inv. Example 1296 10.8 FC 8.32 1.22 44.54 1:3 2.70 Inv. Example 1297 3.8 FC 10.05 1.14 32.87 1:5 0.63 Inv. Example 1298 22.6 FC 10.6 1.13 20.32  1:25 0.87 Inv. Example 1299 27.9 FC 5.7 1.02 2.03 4:5 12.40 Inv. Example 1300 24.8 FC 6.4 1.06 5.33 3:8 6.76 Inv. Example 1301 26.8 FC 3.2 1.05 2.33  9:34 5.61 Inv. Example 1302 25.9 FC 4.5 1.24 27.44 7:8 12.09 Inv. Example 1303 9.8 FC 5.2 1.33 12.33  9:17 3.39 Inv. Example 1304 5.6 FC 1.9 1.27 36.43 1:1 2.80 Inv. Example 1305 12.3 FC 0.02 1.05 11.9  1:31 0.38 Inv. Example 1306 0.8 FC 27.89 1.12 10.5 1:4 0.16 Inv. Example 1307 1 FC 0.32 1.23 9.8 1:1 0.50 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 1285 32 urethane-based 56 Spraying very good resin Inv. Example 1286 53 alkyl silicate 77 Spraying very good Inv. Example 1287 67 alkyl silicate 54 Spraying very good Inv. Example 1288 72 alkyl silicate 64 Spraying very good Inv. Example 1289 77 alkyl silicate 34 Brushing very good Inv. Example 1290 34 alkali silicate 28 Spraying very good Inv. Example 1291 43 urethane-based 109 Brushing very good resin Inv. Example 1292 53 alkyl silicate 15 Spraying very good Inv. Example 1293 72 alkyl silicate 14 Spraying very good Inv. Example 1294 77 alkyl silicate 18 Spraying very good Inv. Example 1295 77 urethane-based 122 Brushing very good resin Inv. Example 1296 43 alkyl silicate 54 Spraying very good Inv. Example 1297 52 alkali silicate 19 Spraying very good Inv. Example 1298 66 alkyl silicate 25 Brushing very good Inv. Example 1299 72 alkyl silicate 58 Spraying very good Inv. Example 1300 40 alkyl silicate 21 Spraying very good Inv. Example 1301 36 alkali silicate 19 Brushing very good Inv. Example 1302 32 urethane-based 56 Spraying very good resin Inv. Example 1303 53 alkyl silicate 77 Spraying very good Inv. Example 1304 67 alkyl silicate 54 Spraying very good Inv. Example 1305 52 alkali silicate 2 Spraying very good Inv. Example 1306 55 alkali silicate 20 Spraying very good Inv. Example 1307 69 alkali silicate 5 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 66 Zn-Alloy Particle Properties Average Mean Size of Zn Blend Ratio Mg Contents to Fracture Value of Metallic (Zn Alloy Total Metal Mg Facet &/or Mean Size Aspect particle particle:Zn Particle (mass %) Cracks (*1) (μm) Ratio (μm) Metal Particle) (mass %) Inv. Example 1308 2.3 FC 11.44 1.36 7.9 1:7 0.29 Inv. Example 1309 15.6 FC 1.05 1.11 11.6  1:11 1.30 Inv. Example 1310 6.7 FC 36.47 1.07 16.9 1:2 2.23 Inv. Example 1311 7.5 FC 5.07 1.42 20.34 1:7 0.94 Inv. Example 1312 8.4 FC 7.72 1.38 8.9 1:4 1.68 Inv. Example 1313 9.3 FC 8.32 1.22 7.5 1:5 1.55 Inv. Example 1314 10.4 FC 10.05 1.14 10.9  1:10 0.95 Inv. Example 1315 11.2 FC 6.08 1.13 20.34 1:9 1.12 Inv. Example 1316 11.7 FC 17.89 1.02 6.7 240:1  11.65 Inv. Example 1317 21.5 FC 19.54 1.06 7.9  1:120 0.18 Inv. Example 1318 13.4 FC 21.08 1.05 5.6 99:1  13.27 Inv. Example 1319 14.6 FC 23.04 1.24 11.5  1:99 0.15 Inv. Example 1320 25.8 FC 9.21 1.33 20.34  1:242 0.11 Inv. Example 1321 16.7 FC 0.12 1.27 10.5 1:6 2.39 Inv. Example 1322 17.3 FC 29.24 1.37 7.6 1:1 8.65 Inv. Example 1323 18.5 FC 128.74 1.10 8.2 1:7 2.31 Inv. Example 1324 19.3 FC 33.57 1.04 9.1 1:5 3.22 Inv. Example 1325 3.5 FC 3.04 1.02 10.6 1:2 1.17 Inv. Example 1326 22.5 FC 7.54 1.01 8.4  1:221 0.10 Inv. Example 1327 23.7 FC 6.81 1.08 5.3  1:31 0.74 Inv. Example 1328 24.2 FC 5.25 1.14 20.34 1:4 4.84 Inv. Example 1329 0.2 FC 194.23 1.23 7.8 1:1 0.10 Inv. Example 1330 27.1 FC 28.74 1.33 10.5 1:7 3.39 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 1308 78 alkyl silicate 20 Spraying very good Inv. Example 1309 42 alkali silicate 15 Brushing very good Inv. Example 1310 32 alkyl silicate 57 Brushing very good Inv. Example 1311 66 alkali silicate 13 Brushing very good Inv. Example 1312 67 alkyl silicate 22 Brushing very good Inv. Example 1313 64 alkali silicate 20 Spraying very good Inv. Example 1314 74 alkyl silicate 27 Spraying very good Inv. Example 1315 82 alkali silicate 15 Spraying very good Inv. Example 1316 37 alkyl silicate 35 Spraying very good Inv. Example 1317 42 alkali silicate 34 Brushing very good Inv. Example 1318 66 alkyl silicate 45 Brushing very good Inv. Example 1319 48 alkali silicate 52 Brushing very good Inv. Example 1320 33 alkyl silicate 23 Brushing very good Inv. Example 1321 75 alkali silicate 5 Spraying very good Inv. Example 1322 77 alkyl silicate 52 Brushing very good Inv. Example 1323 66 alkali silicate 150 Brushing very good Inv. Example 1324 67 alkyl silicate 60 Brushing very good Inv. Example 1325 45 alkali silicate 15 Spraying very good Inv. Example 1326 48 alkyl silicate 24 Spraying very good Inv. Example 1327 68 alkali silicate 34 Spraying very good Inv. Example 1328 35 alkyl silicate 20 Brushing very good Inv. Example 1329 37 alkali silicate 200 Brushing very good Inv. Example 1330 38 alkyl silicate 56 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 67 Zn-Alloy Particle Properties Average Mean Size of Zn Blend Ratio Mg Contents to Fracture Value of Metallic (Zn Alloy Total Metal Mg Facet &/or Mean Size Aspect particle particle:Zn Particle (mass %) Cracks (*1) (μm) Ratio (μm) Metal Particle) (mass %) Inv. Example 1331 29.3 FC 13.57 1.37 20.34 400:1 29.23 Inv. Example 1332 0.5 FC 0.65 1.44 7.9  1:2 0.17 Inv. Example 1333 2.7 FC 4.12 1.21 11.6   1:300 0.01 Inv. Example 1334 28.4 FC 0.72 1.22 16.9  1:4 5.68 Inv. Example 1335 8.7 FC 117.54 1.23 10.5  1:5 1.45 Inv. Example 1336 9.2 FC 7.81 1.47 8.9   1:10 0.84 Inv. Example 1337 17.8 FC 80.25 1.01 7.5  1:9 1.78 Inv. Example 1338 20.2 FC 8.47 1.04 10.9  1:1 10.10 Inv. Example 1339 0.4 FC 0.87 1.05 20.34 130:1 0.40 Inv. Example 1340 13.7 FC 25.78 1.12 6.7 130:1 13.60 Inv. Example 1341 14.7 FC 93.45 1.11 7.9   1:31 0.46 Inv. Example 1342 2.4 FC 0.97 1.08 5.6  1:1 1.20 Inv. Example 1343 4.5 FC 54.89 1.47 20.34  2:1 3.00 Inv. Example 1344 0.1 FC 10.81 1.50 9.9 300:1 0.10 Inv. Example 1345 30.0 FC 18.24 1.13 10.5   1:270 0.11 Inv. Example 1346 24.5 FC 114.78 1.04 7.6   1:115 0.21 Inv. Example 1347 27.6 FC 3.87 1.02 45.33  1:29 0.92 Inv. Example 1348 4.1 FC 11.94 1.08 43.22  1:3 1.03 Inv. Example 1349 3.2 FC 142.58 1.15 10.6  1:9 0.32 Inv. Example 1350 2.7 FC 12.5 1.34 20.34  1:5 0.45 Inv. Example 1351 0.12 FC 31.24 1.25 5.3 100:1 0.12 Inv. Example 1352 0.22 FC 152.46 1.19 10.9  1:1 0.11 Inv. Example 1353 0.37 FC 13.4 1.18 7.8  99:1 0.37 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 1331 41 alkali silicate 34 Spraying very good Inv. Example 1332 54 alkyl silicate 2 Spraying very good Inv. Example 1333 57 alkali silicate 15 Spraying very good Inv. Example 1334 59 alkali silicate 10 Spraying very good Inv. Example 1335 64 alkyl silicate 125 Brushing very good Inv. Example 1336 66 alkali silicate 24 Brushing very good Inv. Example 1337 67 alkyl silicate 110 Brushing very good Inv. Example 1338 34 alkali silicate 24 Brushing very good Inv. Example 1339 54 alkyl silicate 2 Spraying very good Inv. Example 1340 62 alkali silicate 37 Spraying very good Inv. Example 1341 66 alkyl silicate 113 Brushing very good Inv. Example 1342 67 alkali silicate 2 Spraying very good Inv. Example 1343 68 alkyl silicate 75 Brushing very good Inv. Example 1344 33 alkali silicate 30 Brushing very good Inv. Example 1345 35 alkyl silicate 34 Brushing very good Inv. Example 1346 43 epoxy-based resin 124 Brushing very good Inv. Example 1347 44 acryl-based resin 15 Spraying very good Inv. Example 1348 43 urethane-based 23 Spraying very good resin Inv. Example 1349 44 polyester resin 157 Brushing very good Inv. Example 1350 54 epoxy-based resin 26 Spraying very good Inv. Example 1351 79 acryl-based resin 38 Spraying very good Inv. Example 1352 73 urethane-based 160 Brushing very good resin Inv. Example 1353 69 polyester resin 27 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 68 Zn-Alloy Particle Properties Average Mean Size of Zn Blend Ratio Mg Contents to Fracture Value of Metallic (Zn Alloy Total Metal Mg Facet &/or Mean Size Aspect particle particle:Zn Particle (mass %) Cracks (*1) (μm) Ratio (μm) Metal Particle) (mass %) Inv. Example 1354 1.4 FC 160.57 1.24 10.5 1:6  0.20 Inv. Example 1355 4.2 FC 14.1 1.11 20.34 1:12 0.32 Inv. Example 1356 4.8 FC 167.55 1.27 7.9 1:5  0.80 Inv. Example 1357 8.1 FC 1.45 1.31 11.6 1:33 0.24 Inv. Example 1358 7.6 FC 0.15 1.26 16.9 1:9  0.76 Inv. Example 1359 9.9 FC 13.1 1.14 10.5 1:18 0.52 Inv. Example 1360 14.8 FC 15.5 1.34 8.9 1:38 0.38 Inv. Example 1361 16.7 FC 0.67 1.16 7.5  1:117 0.14 Inv. Example 1362 17.9 FC 137.89 1.47 20.34 1:42 0.42 Inv. Example 1363 19.5 FC 16.3 1.48 9.8 1:1  9.75 Inv. Example 1364 22.4 FC 110.38 1.49 6.7  1:121 0.18 Inv. Example 1365 0.17 FC 12.4 1.34 45.33 120:1   0.17 Inv. Example 1366 8.3 FC 17.2 1.29 43.22  1:145 0.06 Inv. Example 1367 6.5 FC 105.23 1.18 11.5 1:31 0.20 Inv. Example 1368 9.7 FC 177.89 1.23 9.9 1:95 0.10 Inv. Example 1369 11.4 FC 12.2 1.27 10.5 1:33 0.34 Inv. Example 1370 22.5 FC 1.84 1.17 7.6 120:1   22.31 Inv. Example 1371 25.7 FC 16.02 1.16 8.2 1:28 0.89 Inv. Example 1372 17.8 FC 1.75 1.49 9.1 1:33 0.52 Inv. Example 1373 0.14 FC 198.78 1.34 10.6 200:1   0.14 Inv. Example 1374 6.7 FC 13.1 1.16 8.4 1:4  1.34 Inv. Example 1375 7.5 FC 15.5 1.47 5.3 1:18 0.39 Inv. Example 1376 8.4 FC 0.67 1.48 10.9 1:7  1.05 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 1354 63 epoxy-based resin 180 Brushing very good Inv. Example 1355 35 acryl-based resin 26 Spraying very good Inv. Example 1356 35 urethane-based 180 Brushing very good resin Inv. Example 1357 66 polyester resin 15 Spraying very good Inv. Example 1358 67 epoxy-based resin 2 Spraying very good Inv. Example 1359 68 acryl-based resin 28 Spraying very good Inv. Example 1360 33 urethane-based 30 Spraying very good resin Inv. Example 1361 35 polyester resin 2 Spraying very good Inv. Example 1362 43 epoxy-based resin 157 Brushing very good Inv. Example 1363 44 acryl-based resin 28 Brushing very good Inv. Example 1364 42 urethane-based 130 Brushing very good resin Inv. Example 1365 33 polyester resin 29 Brushing very good Inv. Example 1366 30 epoxy-based resin 30 Brushing very good Inv. Example 1367 35 acryl-based resin 120 Brushing very good Inv. Example 1368 37 urethane-based 187 Brushing very good resin Inv. Example 1369 77 polyester resin 28 Spraying very good Inv. Example 1370 41 epoxy-based resin 5 Spraying very good Inv. Example 1371 35 acryl-based resin 35 Spraying very good Inv. Example 1372 58 urethane-based 5 Spraying very good resin Inv. Example 1373 37 polyester resin 200 Brushing very good Inv. Example 1374 68 alkali silicate 25 Spraying very good Inv. Example 1375 55 alkali silicate 15 Spraying very good Inv. Example 1376 77 alkyl silicate 20 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 69 Zn-Alloy Particle Properties Average Mean Size of Zn Blend Ratio Fracture Value of Metallic (Zn Alloy Mg Facet &/or Mean Size Aspect particle particle:Zn (mass %) Cracks (*1) (μm) Ratio (μm) Metal Particle) Inv. Example 1377 9.3 FC 12.2 1.49 7.8  1:11 Inv. Example 1378 1.4 FC 1.84 1.34 8.9 1:2 Inv. Example 1379 4.2 FC 16.02 1.29 7.5 1:7 Inv. Example 1380 4.8 FC 1.75 1.18 10.9 1:2 Inv. Example 1381 8.1 FC 12.4 1.23 9.8 1:5 Inv. Example 1382 7.6 FC 17.2 1.27 45.33  1:10 Inv. Example 1383 9.9 FC 13.1 1.17 43.22 1:9 Inv. Example 1384 0.4 FC 29.9 1.16 5.6 240:1  Inv. Example 1385 10.5 FC 0.21 1.27 11.5 120:1  Inv. Example 1386 0.4 FC 0.22 1.17 9.9 99:1  Inv. Example 1387 10.5 FC 29.5 1.27 10.5  1:99 Inv. Example 1388 0.51 FC 29.9 1.18 7.6 1:3 Inv. Example 1389 9.8 FC 0.21 1.23 8.2 1:6 Inv. Example 1390 0.52 FC 0.22 1.27 9.1 1:1 Inv. Example 1391 9.9 FC 29.5 1.17 10.6 1:7 Inv. Example 1392 14.8 FC 16.02 1.48 8.4 1:5 Inv. Example 1393 19.9 FC 1.75 1.49 5.3  1:150 Inv. Example 1394 17.9 FC 12.4 1.34 10.9  1:55 Inv. Example 1395 19.5 FC 17.2 1.29 7.8  1:121 Coat Properties Mg Contents to Ratio of Metal Total Metal Particle in Dry Coat Result of Particle Coat Thickness Coating Corrosion (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 1377 0.78 43 alkali silicate 18 Spraying very good Inv. Example 1378 0.47 45 alkyl silicate 22 Spraying very good Inv. Example 1379 0.53 66 alkali silicate 19 Spraying very good Inv. Example 1380 2.40 33 alkyl silicate 29 Spraying very good Inv. Example 1381 1.35 66 alkali silicate 23 Spraying very good Inv. Example 1382 0.69 55 alkyl silicate 21 Spraying very good Inv. Example 1383 0.99 49 alkali silicate 19 Spraying very good Inv. Example 1384 0.40 77 alkyl silicate 15 Spraying very good Inv. Example 1385 10.41 41 alkali silicate 18 Spraying very good Inv. Example 1386 0.40 64 alkyl silicate 22 Spraying very good Inv. Example 1387 0.11 58 alkyl silicate 21 Spraying very good Inv. Example 1388 0.13 33 alkyl silicate 29 Spraying very good Inv. Example 1389 1.40 66 alkali silicate 23 Spraying very good Inv. Example 1390 0.26 55 alkyl silicate 21 Spraying very good Inv. Example 1391 1.24 49 alkali silicate 19 Spraying very good Inv. Example 1392 2.47 77 alkyl silicate 21 Spraying very good Inv. Example 1393 0.13 43 alkali silicate 19 Spraying very good Inv. Example 1394 0.32 45 alkyl silicate 15 Spraying very good Inv. Example 1395 0.16 66 alkali silicate 18 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 70 Zn-Alloy Particle Properties Average Mean Size of Zn Blend Ratio Fracture Value of Metallic (Zn Alloy Mg Facet &/or Mean Size Aspect particle particle:Zn (mass %) Cracks (*1) (μm) Ratio (μm) Metal Particle) Comp. Example 73 2.3 FC 205.6 1.23 10.5 1:5  Comp. Example 74 12.5 FC 0.005 1.36 12.6 1:3  Comp. Example 75 18.9 FC 205.6 1.11 7.8 1:19  Comp. Example 76 29.5 FC 0.005 1.07 16.8 1:100 Comp. Example 77 14.5 FC 205.6 1.42 10.5 1:260 Comp. Example 78 12.5 FC 0.005 1.38 12.6 1:3  Comp. Example 79 18.9 FC 205.6 1.22 7.8 1:19  Comp. Example 80 29.5 FC 0.005 1.14 16.8 1:100 Comp. Example 81 2.3 FC 10.6 1.13 10.5 1:256 Comp. Example 82 12.5 FC 5.7 1.02 12.6 1:200 Comp. Example 83 0.5 FC 6.4 1.06 7.8 1:167 Comp. Example 84 29.5 FC 3.2 1.23 16.8 1:300 Comp. Example 85 14.5 FC 4.5 1.36 10.5 1:260 Comp. Example 86 9.8 FC 5.2 1.11 12.6 1:100 Comp. Example 87 4.6 FC 1.9 1.07 7.8 1:47  Comp. Example 88 3.2 FC 18.5 1.42 16.8 1:32  Comp. Example 89 29.9 FC 12.5 1.38 12.6 1:345 Comp. Example 90 7.6 FC 9.8 1.22 7.8 1:390 Comp. Example 91 29.9 FC 7.6 1.14 16.8 1:301 Comp. Example 92 0.6 FC 6.9 1.13 10.5 1:333 Comp. Example 93 4.5 FC 10.5 1.02 12.6 1:325 Comp. Example 94 3.7 FC 12.6 1.06 7.8 1:456 Coat Properties Mg Contents to Ratio of Metal Total Metal Particle in Dry Coat Result of Particle Coat Thickness Coating Corrosion (mass %) (mass %) Base Resin (μm) Method Test Comp. Example 73 0.38 77 alkyl silicate 25 Spraying poor Comp. Example 74 3.13 77 urethane-based 25 Spraying poor resin Comp. Example 75 0.95 43 alkyl silicate 105 Brushing poor Comp. Example 76 0.29 52 alkali silicate 165 Spraying poor Comp. Example 77 0.06 66 alkyl silicate 25 Spraying poor Comp. Example 78 3.13 72 alkyl silicate 25 Spraying poor Comp. Example 79 0.95 40 alkyl silicate 105 Brushing poor Comp. Example 80 0.29 36 alkali silicate 165 Spraying poor Comp. Example 81 0.01 32 alkyl silicate 25 Spraying poor Comp. Example 82 0.06 53 alkyl silicate 25 Spraying poor Comp. Example 83 0.00 67 alkyl silicate 105 Brushing poor Comp. Example 84 0.10 53 urethane-based 165 Spraying poor resin Comp. Example 85 0.06 67 alkyl silicate 25 Spraying poor Comp. Example 86 0.10 72 alkyl silicate 25 Spraying poor Comp. Example 87 0.10 77 alkyl silicate 105 Brushing poor Comp. Example 88 0.10 34 urethane-based 55 Spraying poor resin Comp. Example 89 0.09 43 alkyl silicate 28 Spraying poor Comp. Example 90 0.02 52 alkyl silicate 15 Spraying poor Comp. Example 91 0.10 66 alkyl silicate 14 Spraying poor Comp. Example 92 0.00 72 urethane-based 118 Brushing poor resin Comp. Example 93 0.01 40 alkyl silicate 22 Spraying poor Comp. Example 94 0.01 36 alkyl silicate 54 Spraying poor (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 71 Zn-Alloy Particle Properties Average Mean Size of Zn Blend Ratio Mg Contents to Fracture Value of Metallic (Zn Alloy Total Metal Mg Facet &/or Mean Size Aspect particle particle:Zn Particle (mass %) Cracks (*1) (μm) Ratio (μm) Metal Particle) (mass %) Inv. Example 2357 7.5 FC 5.07 1.42 23.43 0.65 10.5 Inv. Example 2358 8.06 FC 7.72 1.38 5.96 0.60 12.5 Inv. Example 2359 9.3 FC 8.32 1.22 10.64 3.72 1.5 Inv. Example 2360 3.5 FC 3.04 1.02 16.5 1.84 0.9 Inv. Example 2361 2.7 FC 4.12 1.21 7.95 0.23 10.5 Inv. Example 2362 9.2 FC 7.81 1.47 7.95 0.03 299.5 Inv. Example 2363 8.1 FC 1.45 1.31 9.64 5.40 0.5 Inv. Example 2364 7.5 FC 9.6 1.07 0.96 5.95 0.26 Inv. Example 2365 4.5 FC 8.5 1.42 5.26 3.46 0.3 Inv. Example 2366 3.6 FC 3.2 1.05 13.5 0.90 3 Inv. Example 2367 4.2 FC 5.7 1.02 13.5 0.20 20.5 Inv. Example 2368 4.3 FC 6.4 1.06 9.64 0.83 4.2 Inv. Example 2369 4 FC 3.2 1.05 16.5 1.60 1.5 Inv. Example 2370 6.4 FC 5.2 1.33 20.59 1.07 5 Inv. Example 2371 9.8 FC 5.2 1.33 0.96 0.59 15.6 Inv. Example 2372 7.5 FC 5.07 1.42 6.54 5.00 0.5 Inv. Example 2373 8.4 FC 7.72 1.38 5.26 2.90 1.9 Inv. Example 2374 2.7 FC 4.12 1.21 10.64 1.04 1.6 Inv. Example 2375 2.64 FC 5.5 1.22 9.64 0.75 2.5 Inv. Example 2376 1.59 FC 6.7 1.14 6.9 1.06 0.5 Inv. Example 2377 2.58 FC 8.9 1.13 10.5 0.43 5 Inv. Example 2378 7.55 FC 2.15 1.14 13.5 3.43 1.2 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 2357 74 alkali silicate 24 Brushing very good Inv. Example 2358 82 alkyl silicate 25 Spraying very good Inv. Example 2359 37 alkali silicate 14 Spraying very good Inv. Example 2360 48 alkali silicate 15 Spraying very good Inv. Example 2361 32 alkali silicate 15 Spraying very good Inv. Example 2362 45 alkyl silicate 15 Brushing very good Inv. Example 2363 37 epoxy-based resin 5 Spraying good Inv. Example 2364 72 urethane-based 150 Spraying very good resin Inv. Example 2365 40 alkali silicate 18 Spraying very good Inv. Example 2366 40 alkali silicate 18 Spraying very good Inv. Example 2367 72 alkyl silicate 58 Spraying very good Inv. Example 2368 40 alkyl silicate 21 Spraying very good Inv. Example 2369 36 alkali silicate 19 Brushing very good Inv. Example 2370 53 alkyl silicate 77 Spraying very good Inv. Example 2371 53 alkyl silicate 77 Spraying very good Inv. Example 2372 66 alkali silicate 13 Brushing very good Inv. Example 2373 67 alkyl silicate 22 Brushing very good Inv. Example 2374 57 alkali silicate 15 Spraying very good Inv. Example 2375 43 alkyl silicate 16 Spraying very good Inv. Example 2376 76 alkyl silicate 5 Spraying very good Inv. Example 2377 49 alkyl silicate 22 Spraying very good Inv. Example 2378 75 alkyl silicate 18 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 72 Zn-Alloy Particle Properties Average Mean Size of Zn Blend Ratio Fracture Value of Metallic (Zn Alloy Mg Facet &/or Mean Size Aspect particle particle:Zn (mass %) Cracks (*1) (μm) Ratio (μm) Metal Particle) Inv. Example 2379 8.01 FC 2.54 1.13 20.59 0.84 Inv. Example 2380 1.06 FC 3.4 1.38 7.82 0.34 Inv. Example 2381 2.64 FC 5.5 1.22 5.26 2.11 Inv. Example 2382 1.59 FC 6.7 1.14 7.06 0.80 Inv. Example 2383 20.5 FC 2.15 1.14 0.64 5.86 Inv. Example 2384 18.5 FC 2.54 1.13 46.8 3.08 Inv. Example 2385 9.51 FC 2.77 1.38 16.5 1.46 Inv. Example 2386 10.01 FC 3.68 1.22 13.5 1.33 Inv. Example 2387 3.54 FC 5.5 1.22 0.96 1.42 Inv. Example 2388 4.05 FC 2.06 1.13 0.96 0.68 Inv. Example 2389 8.57 FC 4.99 1.02 8.45 1.30 Inv. Example 2390 0.02 FC 6.4 1.06 2.9 0.02 Inv. Example 2391 25.5 FC 3.09 1.07 5.4 2.22 Inv. Example 2392 2.36 FC 3.99 1.22 10.6 1.57 Inv. Example 2393 0.05 FC 7.72 1.38 2.32 0.03 Inv. Example 2394 0.04 FC 8.32 1.22 7.8 0.03 Inv. Example 2395 5.22 FC 3.55 1.12 7.95 0.45 Inv. Example 2396 4.01 FC 2.64 1.23 20.59 2.86 Inv. Example 2397 0.05 FC 5.2 1.33 22.5 0.03 Inv. Example 2398 10.5 FC 1.9 1.27 4.6 2.33 Inv. Example 2399 0.05 FC 2.5 1.05 4.9 0.05 Inv. Example 2400 10.5 FC 0.09 1.12 10.5 2.33 Inv. Example 2401 2.64 FC 5.5 1.22 8.45 0.88 Coat Properties Mg Contents to Ratio of Metal Total Metal Particle in Dry Coat Result of Particle Coat Thickness Coating Corrosion (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 2379 8.5 73 alkyl silicate 16 Spraying very good Inv. Example 2380 2.1 49 alkyl silicate 8 Spraying very good Inv. Example 2381 0.25 43 alkyl silicate 16 Spraying very good Inv. Example 2382 1 76 alkyl silicate 5 Spraying very good Inv. Example 2383 2.5 75 alkyl silicate 18 Spraying very good Inv. Example 2384 5 73 alkyl silicate 16 Spraying very good Inv. Example 2385 5.5 55 alkyl silicate 5 Spraying very good Inv. Example 2386 6.5 48 alkyl silicate 22 Spraying very good Inv. Example 2387 1.5 78 alkyl silicate 18 Spraying very good Inv. Example 2388 5 52 alkyl silicate 8 Spraying very good Inv. Example 2389 5.6 61 alkyl silicate 16 Spraying very good Inv. Example 2390 0.05 77 polyester resin 47 Spraying very good Inv. Example 2391 10.5 49 alkyl silicate 22 Spraying very good Inv. Example 2392 0.5 80 alkyl silicate 21 Spraying very good Inv. Example 2393 0.75 36 alkyl silicate 19 Brushing very good Inv. Example 2394 0.2 32 alkyl silicate 24 Spraying very good Inv. Example 2395 10.5 55 alkyl silicate 19 Spraying very good Inv. Example 2396 0.4 40 alkyl silicate 8 Spraying very good Inv. Example 2397 0.9 53 urethane-based 20 Brushing very good resin Inv. Example 2398 3.5 60 polyester resin 200 Brushing very good Inv. Example 2399 0.01 38 alkali silicate 19 Spraying very good Inv. Example 2400 3.5 49 alkyl silicate 11 Spraying very good Inv. Example 2401 2 43 alkyl silicate 16 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 73 Zn-Alloy Particle Properties Average Mean Size of Zn Blend Ratio Mg Contents to Fracture Value of Metallic (Zn Alloy Total Metal Mg Facet &/or Mean Size Aspect particle particle:Zn Particle (mass %) Cracks (*1) (μm) Ratio (μm) Metal Particle) (mass %) Inv. Example 2402 0.08 FC 5.6 1.36 30.5 0.08 0.04 Inv. Example 2403 0.09 FC 11.5 1.11 49.5 0.05 1 Inv. Example 2404 0.05 FC 19.5 1.07 5.9 0.03 0.5 Inv. Example 2405 1.59 FC 6.7 1.14 4.52 0.27 5 Inv. Example 2406 2.58 FC 8.9 1.13 5.96 0.23 10 Inv. Example 2407 9.8 FC 8.32 1.22 5.5 2.18 3.5 Inv. Example 2408 0.18 FC 10.05 1.14 3.6 0.09 0.9 Inv. Example 2409 7.55 FC 2.15 1.14 16.5 1.68 3.5 Inv. Example 2410 0.01 FC 0.06 1.23 12.5 0.01 0.0005 Inv. Example 2411 12.5 FC 2.54 1.13 16.5 0.06 205.7 Inv. Example 2412 1.06 FC 3.4 1.38 10.9 0.71 0.5 Inv. Example 2413 0.04 FC 8.5 1.42 5.6 0.02 1.2 Inv. Example 2414 0.06 FC 7.72 1.38 22.6 0.06 0.02 Inv. Example 2415 9.51 FC 2.77 1.38 20.59 0.81 10.8 Inv. Example 2416 15.5 FC 3.68 1.22 20.59 0.10 152.3 Inv. Example 2417 0.05 FC 10.6 1.13 9.56 0.03 0.5 Inv. Example 2418 8.8 FC 5.7 1.02 5.9 2.51 2.5 Inv. Example 2419 3.54 FC 5.5 1.22 6.54 0.59 5 Inv. Example 2420 10.5 FC 3.2 1.05 21.4 1.05 9 Inv. Example 2421 0.07 FC 4.5 1.24 9.8 0.06 0.1 Inv. Example 2422 15.5 FC 2.54 1.14 6.59 8.16 0.9 Inv. Example 2423 4.05 FC 2.06 1.13 6.54 0.36 10.2 Inv. Example 2424 8.57 FC 4.99 1.02 16.5 0.07 120.5 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 2402 66 alkyl silicate 16 Brushing very good Inv. Example 2403 67 alkali silicate 33 Brushing very good Inv. Example 2404 54 alkyl silicate 8 Brushing good Inv. Example 2405 76 alkyl silicate 5 Spraying very good Inv. Example 2406 49 alkyl silicate 22 Spraying very good Inv. Example 2407 32 alkyl silicate 23 Spraying very good Inv. Example 2408 53 epoxy-based resin 30 Spraying very good Inv. Example 2409 75 alkyl silicate 18 Spraying very good Inv. Example 2410 75 alkali silicate 5 Spraying good Inv. Example 2411 73 alkyl silicate 16 Spraying very good Inv. Example 2412 49 alkyl silicate 8 Spraying very good Inv. Example 2413 40 alkali silicate 2 Spraying very good Inv. Example 2414 36 alkyl silicate 18 Spraying very good Inv. Example 2415 55 alkyl silicate 5 Spraying very good Inv. Example 2416 48 alkyl silicate 22 Spraying very good Inv. Example 2417 67 acryl-based resin 77 Brushing very good Inv. Example 2418 72 urethane-based 54 Brushing very good resin Inv. Example 2419 78 alkyl silicate 18 Spraying very good Inv. Example 2420 34 epoxy-based resin 43 Spraying very good Inv. Example 2421 43 acryl-based resin 52 Brushing very good Inv. Example 2422 45 alkyl silicate 19 Spraying very good Inv. Example 2423 52 polyester resin 8 Spraying very good Inv. Example 2424 61 polyester resin 16 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 74 Zn-Alloy Particle Properties Average Mean Size of Zn Blend Ratio Mg Contents to Fracture Value of Metallic (Zn Alloy Total Metal Mg Facet &/or Mean Size Aspect particle particle:Zn Particle (mass %) Cracks (*1) (μm) Ratio (μm) Metal Particle) (mass %) Inv. Example 2425 5.8 FC 6.4 1.06 7.8 1.66 2.5 Inv. Example 2426 4.59 FC 3.09 1.07 16.5 0.62 6.4 Inv. Example 2427 9.88 FC 4.66 1.42 6.54 0.46 20.4 Inv. Example 2428 4.55 FC 4.09 1.38 8.45 0.48 8.5 Inv. Example 2429 2.36 FC 3.99 1.22 8.5 1.18 1 Inv. Example 2430 0.05 FC 7.72 1.38 13.6 0.05 0.07 Inv. Example 2431 0.04 FC 8.32 1.22 12.33 0.02 1.1 Inv. Example 2432 2.64 FC 4.55 1.11 16.5 0.48 4.5 Inv. Example 2433 0.06 FC 10.6 1.13 7.9 0.04 0.5 Inv. Example 2434 0.18 FC 5.7 1.02 10.5 0.11 0.7 Inv. Example 2435 6.31 FC 3.52 1.27 16.5 4.21 0.5 Inv. Example 2436 5.22 FC 3.55 1.12 10.64 1.49 2.5 Inv. Example 2437 28.5 FC 2.64 1.23 10.5 0.90 30.5 Inv. Example 2438 3.52 FC 3.15 1.36 20.59 2.82 0.25 Inv. Example 2439 9.5 FC 5.2 1.33 8.5 2.79 2.4 Inv. Example 2440 0.04 FC 1.9 1.27 0.5 0.00 7.5 Inv. Example 2441 0.06 FC 10.5 1.12 10.5 0.01 3.5 Inv. Example 2442 0.05 FC 12.5 1.23 11.5 0.01 3.9 Inv. Example 2443 5.6 FC 18.5 1.36 36.5 1.60 2.5 Inv. Example 2444 0.01 FC 11.5 1.11 1.5 0.01 0.7 Inv. Example 2445 0.08 FC 9.6 1.07 8.7 0.03 1.9 Inv. Example 2446 0.03 FC 8.5 1.42 7.8 0.01 4.5 Inv. Example 2447 4.25 FC 2.36 1.33 5.96 3.27 0.3 Coat Properties Ratio of Metal Particle in Dry Coat Result of Coat Thickness Coating Corrosion (mass %) Base Resin (μm) Method Test Inv. Example 2425 77 alkyl silicate 20 Spraying very good Inv. Example 2426 49 alkyl silicate 22 Spraying very good Inv. Example 2427 79 alkyl silicate 18 Spraying very good Inv. Example 2428 76 alkyl silicate 18 Spraying very good Inv. Example 2429 80 alkyl silicate 21 Spraying very good Inv. Example 2430 36 alkyl silicate 19 Brushing very good Inv. Example 2431 32 alkyl silicate 24 Spraying very good Inv. Example 2432 43 alkyl silicate 5 Spraying very good Inv. Example 2433 67 alkyl silicate 7 Spraying very good Inv. Example 2434 72 epoxy-based resin 100 Spraying very good Inv. Example 2435 51 alkyl silicate 21 Spraying very good Inv. Example 2436 55 alkyl silicate 19 Spraying very good Inv. Example 2437 40 alkyl silicate 8 Spraying very good Inv. Example 2438 51 alkyl silicate 16 Spraying very good Inv. Example 2439 53 alkyl silicate 20 Brushing very good Inv. Example 2440 60 polyester resin 200 Brushing very good Inv. Example 2441 77 alkyl silicate 25 Spraying very good Inv. Example 2442 43 alkali silicate 14 Spraying very good Inv. Example 2443 52 urethane-based 112 Spraying very good resin Inv. Example 2444 66 alkali silicate 24 Spraying very good Inv. Example 2445 72 urethane-based 150 Spraying very good resin Inv. Example 2446 40 alkali silicate 18 Spraying very good Inv. Example 2447 44 alkyl silicate 18 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 75 Zn-Alloy Particle Properties Average Mean Size of Zn Blend Ratio Fracture Value of Metallic (Zn Alloy Mg Facet &/or Mean Size Aspect particle particle:Zn (mass %) Cracks (*1) (μm) Ratio (μm) Metal Particle) Inv. Example 2448 0.04 FC 23.5 1.42 0.06 0.04 Inv. Example 2449 0.06 FC 101.5 1.38 0.9 0.06 Inv. Example 2450 0.06 FC 55.4 1.38 3.6 0.06 Inv. Example 2451 0.07 FC 10.5 1.12 10.5 0.02 Inv. Example 2452 0.01 FC 12.5 1.23 0.05 0.01 Inv. Example 2453 0.08 FC 18.5 1.36 2.32 0.04 Inv. Example 2454 0.09 FC 11.5 1.11 20.4 0.08 Inv. Example 2455 0.05 FC 9.6 1.07 7.34 0.01 Inv. Example 2456 0.06 FC 10.05 1.14 9.4 0.02 Inv. Example 2457 29.9 FC 10.5 1.36 16.5 0.15 Inv. Example 2458 16.5 FC 7.5 1.11 7.9 1.03 Inv. Example 2459 12.5 FC 2.6 1.07 10.5 2.08 Inv. Example 2460 9.8 FC 3.5 1.42 16.5 3.92 Inv. Example 2461 9.6 FC 4.5 1.33 8.5 0.12 Inv. Example 2462 7.5 FC 1.6 1.42 10.5 1.25 Inv. Example 2463 4.6 FC 2.5 1.12 5.8 0.40 Inv. Example 2464 3.8 FC 23.5 1.23 1.2 1.09 Inv. Example 2465 0.05 FC 9.8 1.27 15.5 0.03 Coat Properties Mg Contents to Ratio of Metal Total Metal Particle in Dry Coat Result of Particle Coat Thickness Coating Corrosion (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 2448 0.08 44 alkali silicate 38 Spraying very good Inv. Example 2449 0.05 36 alkyl silicate 18 Spraying very good Inv. Example 2450 0.005 76 alkyl silicate 10 Spraying very good Inv. Example 2451 2.8 77 alkyl silicate 37 Spraying very good Inv. Example 2452 0.6 43 alkali silicate 2 Spraying good Inv. Example 2453 1 52 alkyl silicate 160 Brushing very good Inv. Example 2454 0.09 66 alkali silicate 5 Brushing very good Inv. Example 2455 3.4 72 alkyl silicate 56 Brushing very good Inv. Example 2456 1.5 53 urethane-based 99 Spraying very good resin Inv. Example 2457 200 55 urethane-based 700 Spraying very good resin Inv. Example 2458 15 47 alkyl silicate 554 Spraying very good Inv. Example 2459 5 79 urethane-based 688 Brushing very good resin Inv. Example 2460 1.5 42 urethane-based 421 Spraying very good resin Inv. Example 2461 78 36 urethane-based 651 Spraying very good resin Inv. Example 2462 5 53 urethane-based 402 Brushing very good resin Inv. Example 2463 10.5 55 alkali silicate 354 Spraying very good Inv. Example 2464 2.5 42 urethane-based 504 Brushing very good resin Inv. Example 2465 1 76 urethane-based 666 Spraying very good resin (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

Example 6

Zn alloy particles further containing one or both of Al and Si as shown by the chemical ingredients in Tables 76 to 91 were produced. The rest is the same as Example 5.

From Tables 76 to 91, it is learned that the painting test pieces using the Zn alloy particles of the present invention exhibit superior corrosion resistance regardless of the type of base resin, that is, both for inorganic-based and organic-based binders.

TABLE 76 Zn-Alloy Particle Properties Average Mean Size of Blend Ratio Fracture Value of Zn Metallic (Zn Alloy Mg Facet &/or Mean Size Aspect Al Si particle particle:Zn (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) (μm) Metal Particle) Inv. Example 260 12.3 F 0.02 1.05 0.1 0.07 2.02 300:1 Inv. Example 261 0.8 F 27.89 1.12 0.04 0.1 48.05 100:1 Inv. Example 262 1.0 F 0.32 1.23 30.0 0.01 5.41 250:1 Inv. Example 263 2.3 F 158.96 1.36 0.02 3 49.87 150:1 Inv. Example 264 15.6 F 1.05 1.11 8.02 2.04 5.04 170:1 Inv. Example 265 6.7 F 36.47 1.07 15.6 1.27 34.14  80:1 Inv. Example 266 7.5 F 0.51 1.42 10.4 0.57 2.25   1:15 Inv. Example 267 8.4 F 7.72 1.38 4.65 2.67 10.54 200:1 Inv. Example 268 9.3 F 8.32 1.22 24.8 2.4 11.25  65:1 Inv. Example 269 10.4 F 10.05 1.14 4.52 0.57 13.25 300:1 Inv. Example 270 11.2 F 60.08 1.13 17.5 2.45 39.87  70:1 Inv. Example 271 11.7 F 17.89 1.02 745 1.75 24.25  65:1 Inv. Example 272 21.5 F 19.54 1.06 11.05 0.23 10.22  65:1 Inv. Example 273 13.4 F 21.08 1.05 2.65 0.74 5.87 300:1 Inv. Example 274 14.6 F 23.04 1.24 6.45 2.14 19.54 150:1 Inv. Example 275 25.8 F 9.02 1.33 27.6 2.4 15.87 300:1 Inv. Example 276 16.7 F 194.23 1.27 4.32 1.07 48.67  65:1 Coat Properties Mg Contents to Ratio of Metal Total Metal Particle in Dry Coat Result of Particle Coat Thickness Coating Corrosion (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 260 12.26 40 alkali silicate 2 Spraying very good Inv. Example 261 0.79 36 alkyl silicate 35 Spraying very good Inv. Example 262 1.00 32 alkali silicate 15 Spraying very good Inv. Example 263 2.28 53 alkyl silicate 160 Brushing very good Inv. Example 264 15.51 67 alkali silicate 12 Brushing very good Inv. Example 265 6.62 35 alkyl silicate 54 Brushing very good Inv. Example 266 0.47 77 alkali silicate 4 Spraying very good Inv. Example 267 8.36 43 alkyl silicate 16 Spraying very good Inv. Example 268 9.16 52 alkyl silicate 24 Spraying very good Inv. Example 269 10.37 34 epoxy-based resin 15 Brushing very good Inv. Example 270 11.04 43 acryl-based resin 78 Brushing very good Inv. Example 271 11.52 53 urethane-based 22 Brushing very good resin Inv. Example 272 21.17 60 polyester resin 28 Spraying very good Inv. Example 273 13.36 37 epoxy-based resin 32 Spraying very good Inv. Example 274 14.50 42 acryl-based resin 42 Spraying very good Inv. Example 275 25.71 58 urethane-based 15 Brushing very good resin Inv. Example 276 16.45 32 polyester resin 200 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 77 Zn-Alloy Particle Properties Average Mean Size of Blend Ratio Fracture Value of Zn Metallic (Zn Alloy Mg Facet &/or Mean Size Aspect Al Si particle particle:Zn (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) (μm) Metal Particle) Inv. Example 1396 0.15 FC 0.02 1.05 0.1 0.07 2.04  5:2 Inv. Example 1397 0.19 FC 10.5 1.12 0.04 0.1 50.00  7:1 Inv. Example 1398 0.18 FC 12.5 1.23 30.0 0.01 2.45  68:1 Inv. Example 1399 0.11 FC 18.5 1.36 0.02 3 5.33  10:1 Inv. Example 1400 0.15 FC 11.5 1.11 0 0 2.41  25:7 Inv. Example 1401 0.24 FC 9.6 1.07 0 0 23.43 300:9 Inv. Example 1402 0.18 FC 8.5 1.42 10.4 0.57 6.03 180:1 Inv. Example 1403 0.12 FC 7.72 1.38 4.65 2.67 24.5  23:1 Inv. Example 1404 0.19 FC 8.32 1.22 24.8 2.4 5.32 165:1 Inv. Example 1405 0.18 FC 10.05 1.14 4.52 0.57 14.34 300:1 Inv. Example 1406 0.21 FC 10.6 1.13 17.5 2.45 5.04 120:1 Inv. Example 1407 0.76 FC 5.7 1.02 0 0 2.32  2:9 Inv. Example 1408 0.11 FC 6.4 1.06 11.05 0.23 20.34 119:3 Inv. Example 1409 0.14 FC 3.2 1.05 2.65 0.74 12.33 233:1 Inv. Example 1410 15 FC 4.5 1.24 6.45 2.14 17.84   1:132 Inv. Example 1411 14.5 FC 5.2 1.33 0 0 6.66   1:55 Inv. Example 1412 18.5 FC 1.9 1.27 0 0 3.65   1:23 Inv. Example 1413 15.1 FC 0.02 1.05 0.05 0.03 22.62 200:1 Inv. Example 1414 15.6 FC 10.5 1.12 0 0.08 45.33   1:15 Inv. Example 1415 12.5 FC 12.5 1.23 0.05 0 43.22   1:10 Inv. Example 1416 18.7 FC 18.5 1.36 0.44 0.07 12.33  1:6 Inv. Example 1417 14.5 FC 11.5 1.11 0.08 0.07 13.42   1:45 Inv. Example 1418 7.5 FC 9.6 1.07 0.1 0.2 22.32   1:50 Coat Properties Mg Contents to Ratio of Metal Total Metal Particle in Dry Coat Result of Particle Coat Thickness Coating Corrosion (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 1396 0.11 35 alkali silicate 2 Spraying very good Inv. Example 1397 0.17 77 alkyl silicate 37 Spraying very good Inv. Example 1398 0.18 43 alkali silicate 2 Spraying good Inv. Example 1399 0.10 52 alkyl silicate 160 Brushing very good Inv. Example 1400 0.12 66 alkali silicate 5 Brushing very good Inv. Example 1401 0.23 72 alkyl silicate 56 Brushing very good Inv. Example 1402 0.18 40 alkali silicate 2 Spraying very good Inv. Example 1403 0.12 36 alkyl silicate 18 Spraying very good Inv. Example 1404 0.19 32 alkyl silicate 23 Spraying very good Inv. Example 1405 0.18 53 epoxy-based resin 30 Brushing very good Inv. Example 1406 0.21 67 acryl-based resin 77 Brushing very good Inv. Example 1407 0.14 72 urethane-based 54 Brushing very good resin Inv. Example 1408 0.11 77 polyester resin 47 Spraying very good Inv. Example 1409 0.14 34 epoxy-based resin 43 Spraying very good Inv. Example 1410 0.11 43 acryl-based resin 52 Brushing very good Inv. Example 1411 10.24 53 urethane-based 20 Brushing very good resin Inv. Example 1412 0.77 60 polyester resin 200 Brushing very good Inv. Example 1413 15.02 35 alkali silicate 22 Spraying very good Inv. Example 1414 0.98 77 alkyl silicate 25 Spraying very good Inv. Example 1415 1.14 43 alkali silicate 14 Spraying very good Inv. Example 1416 2.67 52 urethane-based 112 Spraying very good resin Inv. Example 1417 0.32 66 alkali silicate 24 Spraying very good Inv. Example 1418 0.15 72 urethane-based 150 Spraying very good resin (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 78 Zn-Alloy Particle Properties Average Mean Size of Blend Ratio Fracture Value of Zn Metallic (Zn Alloy Mg Facet &/or Mean Size Aspect Al Si particle particle:Zn (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) (μm) Metal Particle) Inv. Example 1419 4.5 FC 8.5 1.42 0 0 7.34 1:9 Inv. Example 1420 1.5 FC 7.72 1.38 0 0 44.54 1:7 Inv. Example 1421 4.8 FC 8.32 1.22 0 0.07 32.87 1:4 Inv. Example 1422 9.6 FC 10.05 1.14 0 0.02 20.32  1:14 Inv. Example 1423 11.5 FC 10.6 1.13 25.8 0.05 2.03  1:11 Inv. Example 1424 9.8 FC 5.7 1.02 22.1 0 5.33  1:28 Inv. Example 1425 7.6 FC 6.4 1.06 21.5 0.05 2.33 1:4 Inv. Example 1426 3.2 FC 3.2 1.05 0.05 2.29 27.44 250:1  Inv. Example 1427 1.9 FC 4.5 1.24 0.05 0.03 12.33 1:1 Inv. Example 1428 11.5 FC 5.2 1.33 0 0.08 36.43 1:4 Inv. Example 1429 8.7 FC 1.9 1.27 0 0 12.33  1:12 Inv. Example 1430 9.6 FC 0.02 1.05 0 0 3.21 70:1  Inv. Example 1431 9.4 FC 10.5 1.12 0.08 0.07 26.33 1:3 Inv. Example 1432 10.5 FC 12.5 1.23 0.1 0.2 44.21  1:24 Inv. Example 1433 12.6 FC 18.5 1.36 0.05 0.2 3.43  1:10 Inv. Example 1434 29.5 FC 11.5 1.11 0.07 0 47.32 300:1  Inv. Example 1435 29.4 FC 9.6 1.07 0 0.07 12.33  1:66 Inv. Example 1436 27.5 FC 8.5 1.42 0 0.02 17.44 120:1  Inv. Example 1437 0.8 FC 7.72 1.38 25.8 0.05 42.21 6:5 Inv. Example 1438 1.6 FC 8.32 1.22 22.1 0 12.34 1:1 Inv. Example 1439 22.9 FC 10.05 1.14 21.5 0.05 20.32 1:1 Inv. Example 1440 28.5 FC 10.6 1.13 0.05 2.29 23.44  1:76 Inv. Example 1441 29.5 FC 5.7 1.02 0.1 0.2 23.45 1:6 Coat Properties Mg Contents to Ratio of Metal Total Metal Particle in Dry Coat Result of Particle Coat Thickness Coating Corrosion (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 1419 0.45 40 alkali silicate 18 Spraying very good Inv. Example 1420 0.19 36 alkyl silicate 19 Brushing very good Inv. Example 1421 0.96 32 alkyl silicate 24 Spraying very good Inv. Example 1422 0.64 53 urethane-based 99 Spraying very good resin Inv. Example 1423 0.96 67 alkyl silicate 7 Spraying very good Inv. Example 1424 0.34 72 epoxy-based resin 100 Spraying very good Inv. Example 1425 1.52 77 alkyl silicate 27 Brushing very good Inv. Example 1426 3.19 34 alkali silicate 15 Spraying very good Inv. Example 1427 0.95 43 alkyl silicate 14 Spraying very good Inv. Example 1428 2.30 53 urethane-based 55 Spraying very good resin Inv. Example 1429 0.67 35 alkyl silicate 8 Spraying very good Inv. Example 1430 9.46 77 urethane-based 122 Brushing very good resin Inv. Example 1431 2.35 43 alkyl silicate 54 Spraying very good Inv. Example 1432 0.42 52 alkali silicate 19 Spraying very good Inv. Example 1433 1.15 66 alkyl silicate 25 Brushing very good Inv. Example 1434 29.40 72 alkyl silicate 58 Spraying very good Inv. Example 1435 0.44 40 alkyl silicate 21 Spraying very good Inv. Example 1436 27.27 36 alkali silicate 19 Brushing very good Inv. Example 1437 0.44 32 urethane-based 56 Spraying very good resin Inv. Example 1438 0.80 53 alkyl silicate 77 Spraying very good Inv. Example 1439 11.45 67 alkyl silicate 54 Spraying very good Inv. Example 1440 0.37 72 alkyl silicate 64 Spraying very good Inv. Example 1441 4.21 77 alkyl silicate 34 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 79 Zn-Alloy Particle Properties Average Mean Size of Blend Ratio Fracture Value of Zn Metallic (Zn Alloy Mg Facet &/or Mean Size Aspect Al Si particle particle:Zn (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) (μm) Metal Particle) Inv. Example 1442 18.7 FC 6.4 1.06 0.05 0.2 23.21 1:35 Inv. Example 1443 19.5 FC 3.2 1.05 0.07 0 39.44 1:5  Inv. Example 1444 20.4 FC 4.5 1.24 0 0.07 12.34 1:62 Inv. Example 1445 0.6 FC 5.2 1.33 0 0.02 29.99 1:4  Inv. Example 1446 0.8 FC 1.9 1.27 22.1 0 15.21 5:9  Inv. Example 1447 22.5 FC 0.02 1.05 0.1 0.07 23.34  1:220 Inv. Example 1448 20.6 FC 10.5 1.12 0.04 0.1 2.32 1:80 Inv. Example 1449 21.6 FC 12.5 1.23 30.0 0.01 4.21 1:50 Inv. Example 1450 20.8 FC 7.72 1.38 0 0 15.21 1:10 Inv. Example 1451 23.6 FC 8.32 1.22 0 0 23.34 1:1  Inv. Example 1452 24.5 FC 10.05 1.14 4.52 0.57 2.32 1:78 Inv. Example 1453 18.6 FC 10.6 1.13 17.5 2.45 4.21 1:10 Inv. Example 1454 17.8 FC 5.2 1.33 27.6 2.4 29.99 1:50 Inv. Example 1455 16.5 FC 1.9 1.27 4.32 1.07 15.21 1:10 Inv. Example 1456 14.5 FC 0.02 1.05 0.05 0.03 23.34 1:1  Inv. Example 1457 19 FC 10.5 1.12 0 0.08 2.32 1:3  Inv. Example 1458 15 FC 12.5 1.23 0.05 0 4.21 1:7  Inv. Example 1459 16.4 FC 18.5 1.36 0.44 0.07 15.21 1:50 Inv. Example 1460 13.5 FC 11.5 1.11 0.08 0.07 23.34 1:10 Inv. Example 1461 10.6 FC 11.5 1.11 8.02 2.04 13.45 1:3  Inv. Example 1462 10.7 FC 9.6 1.07 15.6 1.27 2.34 1:10 Inv. Example 1463 10.9 FC 8.5 1.42 10.4 0.57 28.34 1:5  Inv. Example 1464 11.6 FC 7.72 1.38 4.65 2.67 19.87 200:1   Coat Properties Mg Contents to Ratio of Metal Total Metal Particle in Dry Coat Result of Particle Coat Thickness Coating Corrosion (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 1442 0.52 34 alkali silicate 28 Spraying very good Inv. Example 1443 3.25 43 urethane-based 109 Brushing very good resin Inv. Example 1444 0.32 53 alkyl silicate 15 Spraying very good Inv. Example 1445 0.12 72 alkyl silicate 14 Spraying very good Inv. Example 1446 0.29 77 alkyl silicate 18 Spraying very good Inv. Example 1447 0.10 35 alkali silicate 2 Spraying very good Inv. Example 1448 0.25 77 alkyl silicate 37 Spraying very good Inv. Example 1449 0.42 43 alkali silicate 2 Spraying good Inv. Example 1450 1.89 52 alkyl silicate 160 Brushing very good Inv. Example 1451 11.80 66 alkali silicate 5 Brushing very good Inv. Example 1452 0.31 72 alkyl silicate 56 Brushing very good Inv. Example 1453 1.69 40 alkali silicate 2 Spraying very good Inv. Example 1454 0.35 36 alkyl silicate 18 Spraying very good Inv. Example 1455 1.50 32 alkyl silicate 23 Spraying very good Inv. Example 1456 7.25 53 epoxy-based resin 30 Brushing very good Inv. Example 1457 4.75 67 acryl-based resin 77 Brushing very good Inv. Example 1458 1.88 72 urethane-based 54 Brushing very good resin Inv. Example 1459 0.32 77 polyester resin 47 Spraying very good Inv. Example 1460 1.23 34 epoxy-based resin 43 Spraying very good Inv. Example 1461 2.65 43 acryl-based resin 52 Brushing very good Inv. Example 1462 0.97 53 urethane-based 20 Brushing very good resin Inv. Example 1463 1.82 60 polyester resin 200 Brushing very good Inv. Example 1464 11.54 35 alkali silicate 22 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 80 Zn-Alloy Particle Properties Average Mean Size of Blend Ratio Fracture Value of Zn Metallic (Zn Alloy Mg Facet &/or Mean Size Aspect Al Si particle particle:Zn (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) (μm) Metal Particle) Inv. Example 1465 14.7 FC 8.32 1.22 24.8 2.4 39.74 1:8 Inv. Example 1466 19.5 FC 10.05 1.14 4.52 0.57 24.32 1:1 Inv. Example 1467 10.2 FC 10.6 1.13 0 0 22.33 1:7 Inv. Example 1468 4 FC 5.7 1.02 0 0 48.54 1:3 Inv. Example 1469 7.2 FC 6.4 1.06 11.05 0.23 23.75 1:7 Inv. Example 1470 3.6 FC 3.2 1.05 2.65 0.74 15.62 1:2 Inv. Example 1471 26.9 FC 4.5 1.24 6.45 2.14 2.34 117:1  Inv. Example 1472 27.9 FC 5.2 1.33 27.6 2.4 23.04  1:270 Inv. Example 1473 28.9 FC 1.9 1.27 4.32 1.07 3.05  1:117 Inv. Example 1474 23.8 FC 0.02 1.05 0.05 0.03 43.23  1:66 Inv. Example 1475 26.8 FC 10.5 1.12 0 0.08 2.04  1:109 Inv. Example 1476 25.6 FC 12.5 1.23 0.05 0 50.00 250:1  Inv. Example 1477 29.8 FC 18.5 1.36 0.44 0.07 2.45 70:1  Inv. Example 1478 18.9 FC 11.5 1.11 0.08 0.07 5.33  1:15 Inv. Example 1479 5.6 FC 9.6 1.07 0.1 0.2 2.41 1:5 Inv. Example 1480 4.7 FC 8.5 1.42 0.05 0.2 23.43 2:3 Inv. Example 1481 6.8 FC 7.72 1.38 0.07 0 6.03 1:9 Inv. Example 1482 9 FC 8.32 1.22 0 0.07 24.5  1:10 Inv. Example 1483 2.1 FC 10.05 1.14 0 0.02 5.32  1:14 Inv. Example 1484 4.8 FC 10.6 1.13 0 0 14.34 1:7 Inv. Example 1485 4.2 FC 5.7 1.02 0 0 5.04  1:12 Inv. Example 1486 4.3 FC 6.4 1.06 21.5 0.05 2.32 1:3 Inv. Example 1487 4 FC 3.2 1.05 0.05 2.29 20.34 1:7 Coat Properties Mg Contents to Ratio of Metal Total Metal Particle in Dry Coat Result of Particle Coat Thickness Coating Corrosion (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 1465 1.63 77 alkyl silicate 25 Spraying very good Inv. Example 1466 9.75 43 alkali silicate 14 Spraying very good Inv. Example 1467 1.28 52 urethane-based 112 Spraying very good resin Inv. Example 1468 1.00 66 alkali silicate 24 Spraying very good Inv. Example 1469 0.90 72 urethane-based 150 Spraying very good resin Inv. Example 1470 1.20 40 alkali silicate 18 Spraying very good Inv. Example 1471 26.67 36 alkyl silicate 19 Brushing very good Inv. Example 1472 0.10 32 alkyl silicate 24 Spraying very good Inv. Example 1473 0.24 53 urethane-based 99 Spraying very good resin Inv. Example 1474 0.36 67 alkyl silicate 7 Spraying very good Inv. Example 1475 0.24 72 epoxy-based resin 100 Spraying very good Inv. Example 1476 25.50 77 alkyl silicate 27 Brushing very good Inv. Example 1477 29.38 34 alkali silicate 15 Spraying very good Inv. Example 1478 1.18 43 alkyl silicate 14 Spraying very good Inv. Example 1479 0.93 53 urethane-based 55 Spraying very good resin Inv. Example 1480 1.88 35 alkyl silicate 8 Spraying very good Inv. Example 1481 0.68 77 urethane-based 122 Brushing very good resin Inv. Example 1482 0.82 43 alkyl silicate 54 Spraying very good Inv. Example 1483 0.14 52 alkali silicate 19 Spraying very good Inv. Example 1484 0.60 66 alkyl silicate 25 Brushing very good Inv. Example 1485 0.32 72 alkyl silicate 58 Spraying very good Inv. Example 1486 1.08 40 alkyl silicate 21 Spraying very good Inv. Example 1487 0.50 36 alkali silicate 19 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 81 Zn-Alloy Particle Properties Average Mean Size of Blend Ratio Fracture Value of Zn Metallic (Zn Alloy Mg Facet &/or Mean Size Aspect Al Si particle particle:Zn (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) (μm) Metal Particle) Inv. Example 1488 3.7 FC 4.5 1.24 0.05 0.03 12.33  1:10 Inv. Example 1489 6.4 FC 5.2 1.33 0 0.08 17.84 1:1 Inv. Example 1490 6.9 FC 1.9 1.27 0.05 0 6.66 1:3 Inv. Example 1491 16.9 FC 0.02 1.05 0.44 0.07 3.65 2:3 Inv. Example 1492 18.7 FC 10.5 1.12 0.08 0.07 22.62 1:2 Inv. Example 1493 24.4 FC 12.5 1.23 0.1 0.2 45.33 1:4 Inv. Example 1494 10.6 FC 18.5 1.36 0 0 43.22 1:6 Inv. Example 1495 15.8 FC 11.5 1.11 0 0 12.33  1:115 Inv. Example 1496 19.5 FC 9.6 1.07 0 0.07 13.42  1:23 Inv. Example 1497 7.8 FC 8.5 1.42 0 0.02 22.32  1:12 Inv. Example 1498 4.9 FC 7.72 1.38 25.8 0.05 7.34  1:10 Inv. Example 1499 10.8 FC 8.32 1.22 22.1 0 44.54 1:3 Inv. Example 1500 3.8 FC 10.05 1.14 21.5 0.05 32.87 1:5 Inv. Example 1501 22.6 FC 10.6 1.13 0.05 2.29 20.32  1:25 Inv. Example 1502 27.9 FC 5.7 1.02 0 0 2.03 4:5 Inv. Example 1503 24.8 FC 6.4 1.06 0 0 5.33 3:8 Inv. Example 1504 26.8 FC 3.2 1.05 0.07 0 2.33  9:34 Inv. Example 1505 25.9 FC 4.5 1.24 0 0.07 27.44 7:8 Inv. Example 1506 9.8 FC 5.2 1.33 0 0.02 12.33  9:17 Inv. Example 1507 5.6 FC 1.9 1.27 22.1 0 36.43 1:1 Inv. Example 1508 12.3 FC 0.02 1.05 1.24 1.8 11.9  1:31 Inv. Example 1509 0.8 FC 27.89 1.12 1.24 0.9 10.5 1:4 Inv. Example 1510 1 FC 0.32 1.23 0.8 0.7 9.8 1:1 Coat Properties Mg Contents to Ratio of Metal Total Metal Particle in Dry Coat Result of Particle Coat Thickness Coating Corrosion (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 1488 0.34 32 urethane-based 56 Spraying very good resin Inv. Example 1489 3.20 53 alkyl silicate 77 Spraying very good Inv. Example 1490 1.73 67 alkyl silicate 54 Spraying very good Inv. Example 1491 6.76 72 alkyl silicate 64 Spraying very good Inv. Example 1492 6.23 77 alkyl silicate 34 Brushing very good Inv. Example 1493 4.88 34 alkali silicate 28 Spraying very good Inv. Example 1494 1.51 43 urethane-based 109 Brushing very good resin Inv. Example 1495 0.14 53 alkyl silicate 15 Spraying very good Inv. Example 1496 0.81 72 alkyl silicate 14 Spraying very good Inv. Example 1497 0.60 77 alkyl silicate 18 Spraying very good Inv. Example 1498 0.45 77 urethane-based 122 Brushing very good resin Inv. Example 1499 2.70 43 alkyl silicate 54 Spraying very good Inv. Example 1500 0.63 52 alkali silicate 19 Spraying very good Inv. Example 1501 0.87 66 alkyl silicate 25 Brushing very good Inv. Example 1502 12.40 72 alkyl silicate 58 Spraying very good Inv. Example 1503 6.76 40 alkyl silicate 21 Spraying very good Inv. Example 1504 5.61 36 alkali silicate 19 Brushing very good Inv. Example 1505 12.09 32 urethane-based 56 Spraying very good resin Inv. Example 1506 3.39 53 alkyl silicate 77 Spraying very good Inv. Example 1507 2.80 67 alkyl silicate 54 Spraying very good Inv. Example 1508 0.384375 52 alkali silicate 2 Spraying very good Inv. Example 1509 0.16 55 alkali silicate 20 Spraying very good Inv. Example 1510 0.5 69 alkali silicate 5 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 82 Zn-Alloy Particle Properties Average Mean Size of Blend Ratio Fracture Value of Zn Metallic (Zn Alloy Mg Facet &/or Mean Size Aspect Al Si particle particle:Zn (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) (μm) Metal Particle) Inv. Example 1511 2.3 FC 11.44 1.36 0 1.8 7.9 1:7 Inv. Example 1512 15.6 FC 1.05 1.11 1.1 2.41 11.6  1:11 Inv. Example 1513 6.7 FC 36.47 1.07 1.8 0.08 16.9 1:2 Inv. Example 1514 7.5 FC 5.07 1.42 3.8 2.23 20.34 1:7 Inv. Example 1515 8.4 FC 7.72 1.38 2.9 0.06 8.9 1:4 Inv. Example 1516 9.3 FC 8.32 1.22 10.5 0.02 7.5 1:5 Inv. Example 1517 10.4 FC 10.05 1.14 2.9 0.02 10.9  1:10 Inv. Example 1518 11.2 FC 6.08 1.13 16.8 1.37 20.34 1:9 Inv. Example 1519 11.7 FC 17.89 1.02 0 2.43 6.7 240:1  Inv. Example 1520 21.5 FC 19.54 1.06 3.6 0.02 7.9  1:120 Inv. Example 1521 13.4 FC 21.08 1.05 2.1 1.5 5.6 99:1  Inv. Example 1522 14.6 FC 23.04 1.24 0.06 1.3 11.5  1:99 Inv. Example 1523 25.8 FC 9.21 1.33 0.02 1.8 20.34  1:242 Inv. Example 1524 16.7 FC 0.12 1.27 1.6 0.9 10.5 1:6 Inv. Example 1525 17.3 FC 29.24 1.37 3.5 0 7.6 1:1 Inv. Example 1526 18.5 FC 128.74 1.10 9.8 1.8 8.2 1:7 Inv. Example 1527 19.3 FC 33.57 1.04 11.5 0.7 9.1 1:5 Inv. Example 1528 3.5 FC 3.04 1.02 0.4 1.5 10.6 1:2 Inv. Example 1529 22.5 FC 7.54 1.01 0.6 1.3 8.4  1:221 Inv. Example 1530 23.7 FC 6.81 1.08 10.6 1.8 5.3  1:31 Inv. Example 1531 24.2 FC 5.25 1.14 9.5 0 20.34 1:4 Inv. Example 1532 0.2 FC 194.23 1.23 11.04 0.7 7.8 1:1 Coat Properties Mg Contents to Ratio of Metal Total Metal Particle in Dry Coat Result of Particle Coat Thickness Coating Corrosion (mass %) (mass %) Base resin (μm) Method Test Inv. Example 1511 0.2875 78 alkyl silicate 20 Spraying very good Inv. Example 1512 1.3 42 alkali silicate 15 Brushing very good Inv. Example 1513 2.233333333 32 alkyl silicate 57 Brushing very good Inv. Example 1514 0.9375 66 alkali silicate 13 Brushing very good Inv. Example 1515 1.68 67 alkyl silicate 22 Brushing very good Inv. Example 1516 1.55 64 alkali silicate 20 Spraying very good Inv. Example 1517 0.945454545 74 alkyl silicate 27 Spraying very good Inv. Example 1518 1.12 82 alkali silicate 15 Spraying very good Inv. Example 1519 11.65145228 37 alkyl silicate 35 Spraying very good Inv. Example 1520 0.17768595 42 alkali silicate 34 Brushing very good Inv. Example 1521 13.266 66 alkyl silicate 45 Brushing very good Inv. Example 1522 0.146 48 alkali silicate 52 Brushing very good Inv. Example 1523 0.10617284 33 alkyl silicate 23 Brushing very good Inv. Example 1524 2.385714286 75 alkali silicate 5 Spraying very good Inv. Example 1525 8.65 77 alkyl silicate 52 Brushing very good Inv. Example 1526 2.3125 66 alkali silicate 150 Brushing very good Inv. Example 1527 3.216666667 67 alkyl silicate 60 Brushing very good Inv. Example 1528 1.166666667 45 alkali silicate 15 Spraying very good Inv. Example 1529 0.101351351 48 alkyl silicate 24 Spraying very good Inv. Example 1530 0.740625 68 alkali silicate 34 Spraying very good Inv. Example 1531 4.84 35 alkyl silicate 20 Brushing very good Inv. Example 1532 0.1 37 alkali silicate 200 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 83 Zn-Alloy Particle Properties Average Mean Size of Blend Ratio Fracture Value of Zn Metallic (Zn Alloy Mg Facet &/or Mean Size Aspect Al Si particle particle:Zn (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) (μm) Metal Particle) Inv. Example 1533 27.1 FC 28.74 1.33 0.01 1.8 10.5 1:7 Inv. Example 1534 29.3 FC 13.57 1.37 0.07 0.7 20.34 400:1  Inv. Example 1535 0.5 FC 0.65 1.44 1.8 1.5 7.9 1:2 Inv. Example 1536 2.7 FC 4.12 1.21 0 1.3 11.6  1:300 Inv. Example 1537 28.4 FC 0.72 1.22 2.9 1.8 16.9 1:4 Inv. Example 1538 8.7 FC 117.54 1.23 10.5 0.9 10.5 1:5 Inv. Example 1539 9.2 FC 7.81 1.47 2.9 0.7 8.9  1:10 Inv. Example 1540 17.8 FC 80.25 1.01 16.8 1.8 7.5 1:9 Inv. Example 1541 20.2 FC 8.47 1.04 2.7 0.7 10.9 1:1 Inv. Example 1542 0.4 FC 0.87 1.05 0.04 0.7 20.34 130:1  Inv. Example 1543 13.7 FC 25.78 1.12 0 0.04 6.7 130:1  Inv. Example 1544 14.7 FC 93.45 1.11 1.24 0.05 7.9  1:31 Inv. Example 1545 2.4 FC 0.97 1.08 0.05 1.24 5.6 1:1 Inv. Example 1546 4.5 FC 54.89 1.47 1.24 0.06 20.34 2:1 Inv. Example 1547 0.1 FC 10.81 1.50 1.24 0.07 9.9 300:1  Inv. Example 1548 30.0 FC 18.24 1.13 0 0.75 10.5  1:270 Inv. Example 1549 24.5 FC 114.78 1.04 0.9 1.5 7.6  1:115 Inv. Example 1550 27.6 FC 3.87 1.02 0.03 1.3 45.33  1:29 Inv. Example 1551 4.1 FC 11.94 1.08 10.5 1.8 43.22 1:3 Inv. Example 1552 3.2 FC 142.58 1.15 2.9 0.9 10.6 1:9 Inv. Example 1553 2.7 FC 12.5 1.34 16.8 0.7 20.34 1:5 Inv. Example 1554 0.12 FC 31.24 1.25 2.7 1.8 5.3 100:1  Coat Properties Mg Contents to Ratio of Metal Total Metal Particle in Dry Coat Result of Particle Coat Thickness Coating Corrosion (mass %) (mass %) Base resin (μm) Method Test Inv. Example 1533 3.3875 38 alkyl silicate 56 Brushing very good Inv. Example 1534 29.22693267 41 alkali silicate 34 Spraying very good Inv. Example 1535 0.166666667 54 alkyl silicate 2 Spraying very good Inv. Example 1536 0.0089701 57 alkali silicate 15 Spraying very good Inv. Example 1537 5.68 59 alkali silicate 10 Spraying very good Inv. Example 1538 1.45 64 alkyl silicate 125 Brushing very good Inv. Example 1539 0.836363636 66 alkali silicate 24 Brushing very good Inv. Example 1540 1.78 67 alkyl silicate 110 Brushing very good Inv. Example 1541 10.1 34 alkali silicate 24 Brushing very good Inv. Example 1542 0.396946565 54 alkyl silicate 2 Spraying very good Inv. Example 1543 13.59541985 62 alkali silicate 37 Spraying very good Inv. Example 1544 0.459375 66 alkyl silicate 113 Brushing very good Inv. Example 1545 1.2 67 alkali silicate 2 Spraying very good Inv. Example 1546 3 68 alkyl silicate 75 Brushing very good Inv. Example 1547 0.099667774 33 alkali silicate 30 Brushing very good Inv. Example 1548 0.110701107 35 alkyl silicate 34 Brushing very good Inv. Example 1549 0.211206897 43 epoxy-based resin 124 Brushing very good Inv. Example 1550 0.92 44 acryl-based resin 15 Spraying very good Inv. Example 1551 1.025 43 urethane-based 23 Spraying very good resin Inv. Example 1552 0.32 44 polyester resin 157 Brushing very good Inv. Example 1553 0.45 54 epoxy-based resin 26 Spraying very good Inv. Example 1554 0.118811881 79 acryl-based resin 38 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 84 Zn-Alloy Particle Properties Average Mean Size of Blend Ratio Fracture Value of Zn Metallic (Zn Alloy Mg Facet &/or Mean Size Aspect Al Si particle particle:Zn (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) (μm) Metal Particle) Inv. Example 1555 0.22 FC 152.46 1.19 0.02 0.7 10.9 1:1  Inv. Example 1556 0.37 FC 13.4 1.18 0 1.5 7.8 99:1  Inv. Example 1557 1.4 FC 160.57 1.24 7.42 1.3 10.5 1:6  Inv. Example 1558 4.2 FC 14.1 1.11 0.02 1.8 20.34 1:12 Inv. Example 1559 4.8 FC 167.55 1.27 0.04 0.9 7.9 1:5  Inv. Example 1560 8.1 FC 1.45 1.31 17.5 0 11.6 1:33 Inv. Example 1561 7.6 FC 0.15 1.26 0.01 1.8 16.9 1:9  Inv. Example 1562 9.9 FC 13.1 1.14 0.02 0.7 10.5 1:18 Inv. Example 1563 14.8 FC 15.5 1.34 3.8 0 8.9 1:38 Inv. Example 1564 16.7 FC 0.67 1.16 2.9 0 7.5  1:117 Inv. Example 1565 17.9 FC 137.89 1.47 10.5 1.8 20.34 1:42 Inv. Example 1566 19.5 FC 16.3 1.48 2.9 0.9 9.8 1:1  Inv. Example 1567 22.4 FC 110.38 1.49 16.8 0.7 6.7  1:121 Inv. Example 1568 0.17 FC 12.4 1.34 2.7 1.8 45.33 120:1   Inv. Example 1569 8.3 FC 17.2 1.29 0.02 0.7 43.22  1:145 Inv. Example 1570 6.5 FC 105.23 1.18 0.02 0.7 11.5 1:31 Inv. Example 1571 9.7 FC 177.89 1.23 0.04 0.02 9.9 1:95 Inv. Example 1572 11.4 FC 12.2 1.27 0.05 0.02 10.5 1:33 Inv. Example 1573 22.5 FC 1.84 1.17 1.24 1.37 7.6 120:1   Inv. Example 1574 25.7 FC 16.02 1.16 0.05 0.02 8.2 1:28 Inv. Example 1575 17.8 FC 1.75 1.49 1.24 1.37 9.1 1:33 Inv. Example 1576 0.14 FC 198.78 1.34 1.24 1.37 10.6 200:1   Coat Properties Mg Contents to Ratio of Metal Total Metal Particle in Dry Coat Result of Particle Coat Thickness Coating Corrosion (mass %) (mass %) Base resin (μm) Method Test Inv. Example 1555 0.11 73 urethane-based 160 Brushing very good resin Inv. Example 1556 0.3663 69 polyester resin 27 Brushing very good Inv. Example 1557 0.2 63 epoxy-based resin 180 Brushing very good Inv. Example 1558 0.323076923 35 acryl-based resin 26 Spraying very good Inv. Example 1559 0.8 35 urethane-based 180 Brushing very good resin Inv. Example 1560 0.238235294 66 polyester resin 15 Spraying very good Inv. Example 1561 0.76 67 epoxy-based resin 2 Spraying very good Inv. Example 1562 0.521052632 68 acryl-based resin 28 Spraying very good Inv. Example 1563 0.379487179 33 urethane-based 30 Spraying very good resin Inv. Example 1564 0.141525424 35 polyester resin 2 Spraying very good Inv. Example 1565 0.41627907 43 epoxy-based resin 157 Brushing very good Inv. Example 1566 9.75 44 acryl-based resin 28 Brushing very good Inv. Example 1567 0.183606557 42 urethane-based 130 Brushing very good resin Inv. Example 1568 0.168595041 33 polyester resin 29 Brushing very good Inv. Example 1569 0.056849315 30 epoxy-based resin 30 Brushing very good Inv. Example 1570 0.203125 35 acryl-based resin 120 Brushing very good Inv. Example 1571 0.101041667 37 urethane-based 187 Brushing very good resin Inv. Example 1572 0.335294118 77 polyester resin 28 Spraying very good Inv. Example 1573 22.31404959 41 epoxy-based resin 5 Spraying very good Inv. Example 1574 0.886206897 35 acryl-based resin 35 Spraying very good Inv. Example 1575 0.523529412 58 urethane-based 5 Spraying very good resin Inv. Example 1576 0.139303483 37 polyester resin 200 Brushing very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 85 Zn-Alloy Particle Properties Average Mean Size of Blend Ratio Fracture Value of Zn Metallic (Zn Alloy Mg Facet &/or Mean Size Aspect Al Si particle particle:Zn (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) (μm) Metal Particle) Inv. Example 1577 6.7 FC 13.1 1.16 0.8 1.5 8.4 1:4 Inv. Example 1578 7.5 FC 15.5 1.47 0.9 1.3 5.3  1:18 Inv. Example 1579 8.4 FC 0.67 1.48 1.1 1.8 10.9 1:7 Inv. Example 1580 9.3 FC 12.2 1.49 1.8 0.9 7.8  1:11 Inv. Example 1581 1.4 FC 1.84 1.34 3.8 0.7 8.9 1:2 Inv. Example 1582 4.2 FC 16.02 1.29 2.9 1.8 7.5 1:7 Inv. Example 1583 4.8 FC 1.75 1.18 10.5 0.7 10.9 1:2 Inv. Example 1584 8.1 FC 12.4 1.23 2.9 1.5 9.8 1:5 Inv. Example 1585 7.6 FC 17.2 1.27 16.8 1.3 45.33  1:10 Inv. Example 1586 9.9 FC 13.1 1.17 2.7 1.8 43.22 1:9 Inv. Example 1587 0.4 FC 29.9 1.16 3.6 0.9 5.6 240:1  Inv. Example 1588 10.5 FC 0.21 1.27 0 0.7 11.5 120:1  Inv. Example 1589 0.4 FC 0.22 1.17 0.06 1.8 9.9 99:1  Inv. Example 1590 10.5 FC 29.5 1.27 0.02 0.7 10.5  1:99 Inv. Example 1591 0.51 FC 29.9 1.18 1.6 1.5 7.6 1:3 Inv. Example 1592 9.8 FC 0.21 1.23 3.5 0 8.2 1:6 Inv. Example 1593 0.52 FC 0.22 1.27 9.8 1.8 9.1 1:1 Inv. Example 1594 9.9 FC 29.5 1.17 11.5 0.9 10.6  1:7 Inv. Example 1595 14.8 FC 16.02 1.48 0.4 0.7 8.4 1:5 Inv. Example 1596 19.9 FC 1.75 1.49 0.6 1.8 5.3  1:150 Inv. Example 1597 17.9 FC 12.4 1.34 10.6 0.7 10.9  1:55 Inv. Example 1598 19.5 FC 17.2 1.29 9.5 0.7 7.8  1:121 Coat Properties Mg Contents to Ratio of Metal Total Metal Particle in Dry Coat Result of Particle Coat Thickness Coating Corrosion (mass %) (mass %) Base resin (μm) Method Test Inv. Example 1577 1.34 68 alkali silicate 25 Spraying very good Inv. Example 1578 0.394736842 55 alkali silicate 15 Spraying very good Inv. Example 1579 1.05 77 alkyl silicate 20 Spraying very good Inv. Example 1580 0.775 43 alkali silicate 18 Spraying very good Inv. Example 1581 0.466666667 45 alkyl silicate 22 Spraying very good Inv. Example 1582 0.525 66 alkali silicate 19 Spraying very good Inv. Example 1583 2.4 33 alkyl silicate 29 Spraying very good Inv. Example 1584 1.35 66 alkali silicate 23 Spraying very good Inv. Example 1585 0.690909091 55 alkyl silicate 21 Spraying very good Inv. Example 1586 0.99 49 alkali silicate 19 Spraying very good Inv. Example 1587 0.398340249 77 alkyl silicate 15 Spraying very good Inv. Example 1588 10.41322314 41 alkali silicate 18 Spraying very good Inv. Example 1589 0.396 64 alkyl silicate 22 Spraying very good Inv. Example 1590 0.105 58 alkyl silicate 21 Spraying very good Inv. Example 1591 0.1275 33 alkyl silicate 29 Spraying very good Inv. Example 1592 1.4 66 alkali silicate 23 Spraying very good Inv. Example 1593 0.26 55 alkyl silicate 21 Spraying very good Inv. Example 1594 1.2375 49 alkali silicate 19 Spraying very good Inv. Example 1595 2.466666667 77 alkyl silicate 21 Spraying very good Inv. Example 1596 0.131788079 43 alkali silicate 19 Spraying very good Inv. Example 1597 0.319642857 45 alkyl silicate 15 Spraying very good Inv. Example 1598 0.159836066 66 alkali silicate 18 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 86 Zn-Alloy Particle Properties Average Mean Size of Blend Ratio Fracture Value of Zn Metallic (Zn Alloy Mg Facet &/or Mean Size Aspect Al Si particle particle:Zn (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) (μm) Metal Particle) Comp. Example 95 2.3 FC 205.6 1.23 12.5 0.05 10.5 1:5  Comp. Example 96 12.5 FC 0.005 1.36 2.1 0 12.6 1:3  Comp. Example 97 18.9 FC 205.6 1.11 1.5 0.05 7.8 1:19  Comp. Example 98 29.5 FC 0.005 1.07 0.05 2.29 16.8 1:100 Comp. Example 99 14.5 FC 205.6 1.42 0 0 10.5 1:260 Comp. Example 100 12.5 FC 0.005 1.38 0 0 12.6 1:3  Comp. Example 101 18.9 NO 205.6 1.22 0.07 0 7.8 1:19  Comp. Example 102 29.5 NO 0.005 1.14 0 0.07 16.8 1:100 Comp. Example 103 2.3 FC 10.6 1.13 0 0.02 10.5 1:256 Comp. Example 104 12.5 FC 5.7 1.02 22.1 0 12.6 1:200 Comp. Example 105 0.5 NO 6.4 1.06 25.8 0.05 7.8 1:167 Comp. Example 106 29.5 NO 3.2 1.23 22.1 0 16.8 1:300 Comp. Example 107 14.5 NO 4.5 1.36 21.5 0.05 10.5 1:260 Comp. Example 108 9.8 NO 5.2 1.11 0.05 2.29 12.6 1:100 Comp. Example 109 4.6 NO 1.9 1.07 0 0 7.8 1:47  Comp. Example 110 3.2 FC 18.5 1.42 0 0 16.8 1:32  Comp. Example 111 29.9 FC 12.5 1.38 0.07 0 12.6 1:345 Comp. Example 112 7.6 FC 9.8 1.22 0 0.07 7.8 1:390 Comp. Example 113 29.9 FC 7.6 1.14 0 0.007 16.8 1:301 Comp. Example 114 0.6 FC 6.9 1.13 36.5 3.25 10.5 1:333 Comp. Example 115 4.5 FC 10.5 1.02 0.005 0 12.6 1:325 Comp. Example 116 3.7 FC 12.6 1.06 22.1 0 7.8 1:456 Coat Properties Mg Contents to Ratio of Metal Total Metal Particle in Dry Coat Result of Particle Coat Thickness Coating Corrosion (mass %) (mass %) Base resin (μm) Method Test Comp. Example 95 0.383 77 alkyl silicate 25 Spraying poor Comp. Example 96 3.125 77 urethane-based 25 Spraying poor resin Comp. Example 97 0.945 43 alkyl silicate 105 Brushing poor Comp. Example 98 0.292 52 alkali silicate 165 Spraying poor Comp. Example 99 0.056 66 alkyl silicate 25 Spraying poor Comp. Example 100 3.125 72 alkyl silicate 25 Spraying poor Comp. Example 101 0.945 40 alkyl silicate 105 Brushing poor Comp. Example 102 0.292 36 alkali silicate 165 Spraying poor Comp. Example 103 0.009 32 alkyl silicate 25 Spraying poor Comp. Example 104 0.062 53 alkyl silicate 25 Spraying poor Comp. Example 105 0.003 67 alkyl silicate 105 Brushing poor Comp. Example 106 0.098 53 urethane-based 165 Spraying poor resin Comp. Example 107 0.056 67 alkyl silicate 25 Spraying poor Comp. Example 108 0.097 72 alkyl silicate 25 Spraying poor Comp. Example 109 0.096 77 alkyl silicate 105 Brushing poor Comp. Example 110 0.097 34 urethane-based 55 Spraying poor resin Comp. Example 111 0.086 43 alkyl silicate 28 Spraying poor Comp. Example 112 0.019 52 alkyl silicate 15 Spraying poor Comp. Example 113 0.099 66 alkyl silicate 14 Spraying poor Comp. Example 114 0.002 72 urethane-based 118 Brushing poor resin Comp. Example 115 0.014 40 alkyl silicate 22 Spraying poor Comp. Example 116 0.008 36 alkyl silicate 54 Spraying poor (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 87 Zn-Alloy Particle Properties Average Mean Size of Blend Ratio Fracture Value of Zn Metallic (Zn Alloy Mg Facet &/or Mean Size Aspect Al Si particle particle:Zn (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) (μm) Metal Particle) Inv. Example 2467 7.5 FC 5.07 1.42 0 0 23.43 0.65 Inv. Example 2468 8.06 FC 7.72 1.38 0 0 5.96 0.60 Inv. Example 2469 9.3 FC 8.32 1.22 0 0 10.64 3.72 Inv. Example 2470 3.5 FC 3.04 1.02 0 0 16.5 1.84 Inv. Example 2471 2.7 FC 4.12 1.21 0 0 7.95 0.23 Inv. Example 2472 9.2 FC 7.81 1.47 0 0 7.95 0.03 Inv. Example 2473 8.1 FC 1.45 1.31 0 0 9.64 5.40 Inv. Example 2474 7.5 FC 9.6 1.07 0 0 0.96 5.95 Inv. Example 2475 4.5 FC 8.5 1.42 0 0 5.26 3.46 Inv. Example 2476 3.6 FC 3.2 1.05 0 0 13.5 0.90 Inv. Example 2477 4.2 FC 5.7 1.02 1.5 0 13.5 0.20 Inv. Example 2478 4.3 FC 6.4 1.06 5.5 1.6 9.64 0.83 Inv. Example 2479 4 FC 3.2 1.05 0 0 16.5 1.60 Inv. Example 2480 6.4 FC 5.2 1.33 0 0 20.59 1.07 Inv. Example 2481 9.8 FC 5.2 1.33 0 0 0.96 0.59 Inv. Example 2482 7.5 FC 5.07 1.42 0 0 6.54 5.00 Inv. Example 2483 8.4 FC 7.72 1.38 0.5 0 5.26 2.90 Inv. Example 2484 2.7 FC 4.12 1.21 0 0 10.64 1.04 Inv. Example 2485 2.64 FC 5.5 1.22 0 0 9.64 0.75 Inv. Example 2486 1.59 FC 6.7 1.14 0 0 6.9 1.06 Inv. Example 2487 2.58 FC 8.9 1.13 0 0 10.5 0.43 Inv. Example 2488 7.55 FC 2.15 1.14 0 0 13.5 3.43 Coat Properties Mg Contents to Ratio of Metal Total Metal Particle in Dry Coat Result of Particle Coat Thickness Coating Corrosion (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 2467 10.5 74 alkali silicate 24 Brushing very good Inv. Example 2468 12.5 82 alkyl silicate 25 Spraying very good Inv. Example 2469 1.5 37 alkali silicate 14 Spraying very good Inv. Example 2470 0.9 48 alkali silicate 15 Spraying very good Inv. Example 2471 10.5 32 alkali silicate 15 Spraying very good Inv. Example 2472 299.5 45 alkyl silicate 15 Brushing very good Inv. Example 2473 0.5 37 epoxy-based resin 5 Spraying good Inv. Example 2474 0.26 72 urethane-based 150 Spraying very good resin Inv. Example 2475 0.3 40 alkali silicate 18 Spraying very good Inv. Example 2476 3 40 alkali silicate 18 Spraying very good Inv. Example 2477 20.5 72 alkyl silicate 58 Spraying very good Inv. Example 2478 4.2 40 alkyl silicate 21 Spraying very good Inv. Example 2479 1.5 36 alkali silicate 19 Brushing very good Inv. Example 2480 5 53 alkyl silicate 77 Spraying very good Inv. Example 2481 15.6 53 alkyl silicate 77 Spraying very good Inv. Example 2482 0.5 66 alkali silicate 13 Brushing very good Inv. Example 2483 1.9 67 alkyl silicate 22 Brushing very good Inv. Example 2484 1.6 57 alkali silicate 15 Spraying very good Inv. Example 2485 2.5 43 alkyl silicate 16 Spraying very good Inv. Example 2486 0.5 76 alkyl silicate 5 Spraying very good Inv. Example 2487 5 49 alkyl silicate 22 Spraying very good Inv. Example 2488 1.2 75 alkyl silicate 18 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 88 Zn-Alloy Particle Properties Average Mean Size of Blend Ratio Fracture Value of Zn Metallic (Zn Alloy Mg Facet &/or Mean Size Aspect Al Si particle particle:Zn (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) (μm) Metal Particle) Inv. Example 2489 8.01 FC 2.54 1.13 0 0 20.59 0.84 Inv. Example 2490 1.06 FC 3.4 1.38 0 0 7.82 0.34 Inv. Example 2491 2.64 FC 5.5 1.22 0 0 5.26 2.11 Inv. Example 2492 1.59 FC 6.7 1.14 0 0 7.06 0.80 Inv. Example 2493 20.5 FC 2.15 1.14 1.5 0 0.64 5.86 Inv. Example 2494 18.5 FC 2.54 1.13 5.5 1.6 46.8 3.08 Inv. Example 2495 9.51 FC 2.77 1.38 4.5 0 16.5 1.46 Inv. Example 2496 10.01 FC 3.68 1.22 0 1.6 13.5 1.33 Inv. Example 2497 3.54 FC 5.5 1.22 0 0 0.96 1.42 Inv. Example 2498 4.05 FC 2.06 1.13 0 0 0.96 0.68 Inv. Example 2499 8.57 FC 4.99 1.02 0 0 8.45 1.30 Inv. Example 2500 0.02 FC 6.4 1.06 1.2 0.6 2.9 0.02 Inv. Example 2501 25.5 FC 3.09 1.07 0 0 5.4 2.22 Inv. Example 2502 2.36 FC 3.99 1.22 0 0 10.6 1.57 Inv. Example 2503 0.05 FC 7.72 1.38 4.5 0 2.32 0.03 Inv. Example 2504 0.04 FC 8.32 1.22 0.01 0 7.8 0.03 Inv. Example 2505 5.22 FC 3.55 1.12 0 0 7.95 0.45 Inv. Example 2506 4.01 FC 2.64 1.23 0 0 20.59 2.86 Inv. Example 2507 0.05 FC 5.2 1.33 0 0.6 22.5 0.03 Inv. Example 2508 10.5 FC 1.9 1.27 0 1.2 4.6 2.33 Inv. Example 2509 0.05 FC 2.5 1.05 5.5 1.6 4.9 0.05 Inv. Example 2510 10.5 FC 0.09 1.12 0 0.01 10.5 2.33 Inv. Example 2511 2.64 FC 5.5 1.22 0 0.01 8.45 0.88 Coat Properties Mg Contents to Ratio of Metal Total Metal Particle in Dry Coat Result of Particle Coat Thickness Coating Corrosion (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 2489 8.5 73 alkyl silicate 16 Spraying very good Inv. Example 2490 2.1 49 alkyl silicate 8 Spraying very good Inv. Example 2491 0.25 43 alkyl silicate 16 Spraying very good Inv. Example 2492 1 76 alkyl silicate 5 Spraying very good Inv. Example 2493 2.5 75 alkyl silicate 18 Spraying very good Inv. Example 2494 5 73 alkyl silicate 16 Spraying very good Inv. Example 2495 5.5 55 alkyl silicate 5 Spraying very good Inv. Example 2496 6.5 48 alkyl silicate 22 Spraying very good Inv. Example 2497 1.5 78 alkyl silicate 18 Spraying very good Inv. Example 2498 5 52 alkyl silicate 8 Spraying very good Inv. Example 2499 5.6 61 alkyl silicate 16 Spraying very good Inv. Example 2500 0.05 77 polyester resin 47 Spraying very good Inv. Example 2501 10.5 49 alkyl silicate 22 Spraying very good Inv. Example 2502 0.5 80 alkyl silicate 21 Spraying very good Inv. Example 2503 0.75 36 alkyl silicate 19 Brushing very good Inv. Example 2504 0.2 32 alkyl silicate 24 Spraying very good Inv. Example 2505 10.5 55 alkyl silicate 19 Spraying very good Inv. Example 2506 0.4 40 alkyl silicate 8 Spraying very good Inv. Example 2507 0.9 53 urethane-based 20 Brushing very good resin Inv. Example 2508 3.5 60 polyester resin 200 Brushing very good Inv. Example 2509 0.01 38 alkali silicate 19 Spraying very good Inv. Example 2510 3.5 49 alkyl silicate 11 Spraying very good Inv. Example 2511 2 43 alkyl silicate 16 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 89 Zn-Alloy Particle Properties Average Mean Size of Blend Ratio Fracture Value of Zn Metallic (Zn Alloy Mg Facet &/or Mean Size Aspect Al Si particle particle:Zn (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) (μm) Metal Particle) Inv. Example 2512 0.08 FC 5.6 1.36 0.5 0 30.5 0.08 Inv. Example 2513 0.09 FC 11.5 1.11 5.5 1.6 49.5 0.05 Inv. Example 2514 0.05 FC 19.5 1.07 0.5 0 5.9 0.03 Inv. Example 2515 1.59 FC 6.7 1.14 0 0.1 4.52 0.27 Inv. Example 2516 2.58 FC 8.9 1.13 0.01 0 5.96 0.23 Inv. Example 2517 9.8 FC 8.32 1.22 3.2 0.9 5.5 2.18 Inv. Example 2518 0.18 FC 10.05 1.14 0 0.5 3.6 0.09 Inv. Example 2519 7.55 FC 2.15 1.14 0.2 0.1 16.5 1.68 Inv. Example 2520 0.01 FC 0.06 1.23 1.5 0 12.5 0.01 Inv. Example 2521 12.5 FC 2.54 1.13 0.5 0 16.5 0.06 Inv. Example 2522 1.06 FC 3.4 1.38 1.5 0.9 10.9 0.71 Inv. Example 2523 0.04 FC 8.5 1.42 0 0 5.6 0.02 Inv. Example 2524 0.06 FC 7.72 1.38 0 0.5 22.6 0.06 Inv. Example 2525 9.51 FC 2.77 1.38 0 0.01 20.59 0.81 Inv. Example 2526 15.5 FC 3.68 1.22 1.5 0 20.59 0.10 Inv. Example 2527 0.05 FC 10.6 1.13 0 0 9.56 0.03 Inv. Example 2528 8.8 FC 5.7 1.02 0.2 0.1 5.9 2.51 Inv. Example 2529 3.54 FC 5.5 1.22 0 0.1 6.54 0.59 Inv. Example 2530 10.5 FC 3.2 1.05 5.5 1.6 21.4 1.05 Inv. Example 2531 0.07 FC 4.5 1.24 4.5 0 9.8 0.06 Inv. Example 2532 15.5 FC 2.54 1.14 0 0.5 6.59 8.16 Inv. Example 2533 4.05 FC 2.06 1.13 0.2 0.1 6.54 0.36 Coat Properties Mg Contents to Ratio of Metal Total Metal Particle in Dry Coat Result of Particle Coat Thickness Coating Corrosion (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 2512 0.04 66 alkyl silicate 16 Brushing very good Inv. Example 2513 1 67 alkali silicate 33 Brushing very good Inv. Example 2514 0.5 54 alkyl silicate 8 Brushing good Inv. Example 2515 5 76 alkyl silicate 5 Spraying very good Inv. Example 2516 10 49 alkyl silicate 22 Spraying very good Inv. Example 2517 3.5 32 alkyl silicate 23 Spraying very good Inv. Example 2518 0.9 53 epoxy-based resin 30 Spraying very good Inv. Example 2519 3.5 75 alkyl silicate 18 Spraying very good Inv. Example 2520 0.0005 75 alkali silicate 5 Spraying good Inv. Example 2521 205.7 73 alkyl silicate 16 Spraying very good Inv. Example 2522 0.5 49 alkyl silicate 8 Spraying very good Inv. Example 2523 1.2 40 alkali silicate 2 Spraying very good Inv. Example 2524 0.02 36 alkyl silicate 18 Spraying very good Inv. Example 2525 10.8 55 alkyl silicate 5 Spraying very good Inv. Example 2526 152.3 48 alkyl silicate 22 Spraying very good Inv. Example 2527 0.5 67 acryl-based resin 77 Brushing very good Inv. Example 2528 2.5 72 urethane-based 54 Brushing very good resin Inv. Example 2529 5 78 alkyl silicate 18 Spraying very good Inv. Example 2530 9 34 epoxy-based resin 43 Spraying very good Inv. Example 2531 0.1 43 acryl-based resin 52 Brushing very good Inv. Example 2532 0.9 45 alkyl silicate 19 Spraying very good Inv. Example 2533 10.2 52 polyester resin 8 Spraying very good (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 90 Zn-Alloy Particle Properties Average Mean Size of Blend Ratio Fracture Value of Zn Metallic (Zn Alloy Mg Facet &/or Mean Size Aspect Al Si particle particle:Zn (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) (μm) Metal Particle) Inv. Example 2534 8.57 FC 4.99 1.02 1.2 0.6 16.5 0.07 Inv. Example 2535 5.8 FC 6.4 1.06 0 0 7.8 1.66 Inv. Example 2536 4.59 FC 3.09 1.07 1.5 0.9 16.5 0.62 Inv. Example 2537 9.88 FC 4.66 1.42 0 1.2 6.54 0.46 Inv. Example 2538 4.55 FC 4.09 1.38 0 0.6 8.45 0.48 Inv. Example 2539 2.36 FC 3.99 1.22 0 0.01 8.5 1.18 Inv. Example 2540 0.05 FC 7.72 1.38 1.5 0 13.6 0.05 Inv. Example 2541 0.04 FC 8.32 1.22 5.5 1.6 12.33 0.02 Inv. Example 2542 2.64 FC 4.55 1.11 4.5 0 16.5 0.48 Inv. Example 2543 0.06 FC 10.6 1.13 0 0.1 7.9 0.04 Inv. Example 2544 0.18 FC 5.7 1.02 0.01 0 10.5 0.11 Inv. Example 2545 6.31 FC 3.52 1.27 3.2 0.9 16.5 4.21 Inv. Example 2546 5.22 FC 3.55 1.12 0 0.5 10.64 1.49 Inv. Example 2547 28.5 FC 2.64 1.23 0.2 0.1 10.5 0.90 Inv. Example 2548 3.52 FC 3.15 1.36 1.2 0.6 20.59 2.82 Inv. Example 2549 9.5 FC 5.2 1.33 0 0 8.5 2.79 Inv. Example 2550 0.04 FC 1.9 1.27 0 0 0.5 0.00 Inv. Example 2551 0.06 FC 10.5 1.12 0 1.2 10.5 0.01 Inv. Example 2552 0.05 FC 12.5 1.23 0.5 0 11.5 0.01 Inv. Example 2553 5.6 FC 18.5 1.36 3.2 0.9 36.5 1.60 Inv. Example 2554 0.01 FC 11.5 1.11 0.5 0 1.5 0.01 Inv. Example 2555 0.08 FC 9.6 1.07 1.5 0 8.7 0.03 Coat Properties Mg Contents to Ratio of Metal Total Metal Particle in Dry Coat Result of Particle Coat Thickness Coating Corrosion (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 2534 120.5 61 polyester resin 16 Spraying very good Inv. Example 2535 2.5 77 alkyl silicate 20 Spraying very good Inv. Example 2536 6.4 49 alkyl silicate 22 Spraying very good Inv. Example 2537 20.4 79 alkyl silicate 18 Spraying very good Inv. Example 2538 8.5 76 alkyl silicate 18 Spraying very good Inv. Example 2539 1 80 alkyl silicate 21 Spraying very good Inv. Example 2540 0.07 36 alkyl silicate 19 Brushing very good Inv. Example 2541 1.1 32 alkyl silicate 24 Spraying very good Inv. Example 2542 4.5 43 alkyl silicate 5 Spraying very good Inv. Example 2543 0.5 67 alkyl silicate 7 Spraying very good Inv. Example 2544 0.7 72 epoxy-based resin 100 Spraying very good Inv. Example 2545 0.5 51 alkyl silicate 21 Spraying very good Inv. Example 2546 2.5 55 alkyl silicate 19 Spraying very good Inv. Example 2547 30.5 40 alkyl silicate 8 Spraying very good Inv. Example 2548 0.25 51 alkyl silicate 16 Spraying very good Inv. Example 2549 2.4 53 alkyl silicate 20 Brushing very good Inv. Example 2550 7.5 60 polyester resin 200 Brushing very good Inv. Example 2551 3.5 77 alkyl silicate 25 Spraying very good Inv. Example 2552 3.9 43 alkali silicate 14 Spraying very good Inv. Example 2553 2.5 52 urethane-based 112 Spraying very good resin Inv. Example 2554 0.7 66 alkali silicate 24 Spraying very good Inv. Example 2555 1.9 72 urethane-based 150 Spraying very good resin (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 91 Zn-Alloy Particle Properties Average Mean Size of Blend Ratio Fracture Value of Zn Metallic (Zn Alloy Mg Facet &/or Mean Size Aspect Al Si particle particle:Zn (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) (μm) Metal Particle) Inv. Example 2556 0.03 FC 8.5 1.42 4.5 0 7.8 0.01 Inv. Example 2557 4.25 FC 2.36 1.33 0 0.1 5.96 3.27 Inv. Example 2558 0.04 FC 23.5 1.42 1.5 0.9 0.06 0.04 Inv. Example 2559 0.06 FC 101.5 1.38 1.5 0.9 0.9 0.06 Inv. Example 2560 0.06 FC 55.4 1.38 3.2 0.9 3.6 0.06 Inv. Example 2561 0.07 FC 10.5 1.12 0 0.6 10.5 0.02 Inv. Example 2562 0.01 FC 12.5 1.23 1.2 0.6 0.05 0.01 Inv. Example 2563 0.08 FC 18.5 1.36 0.01 0 2.32 0.04 Inv. Example 2564 0.09 FC 11.5 1.11 1.5 0.9 20.4 0.08 Inv. Example 2565 0.05 FC 9.6 1.07 0 1.2 7.34 0.01 Inv. Example 2566 0.06 FC 10.05 1.14 0 0.6 9.4 0.02 Inv. Example 2567 29.9 FC 10.5 1.36 0 0 16.5 0.15 Inv. Example 2568 16.5 FC 7.5 1.11 0.01 0 7.9 1.03 Inv. Example 2569 12.5 FC 2.6 1.07 3.2 0.9 10.5 2.08 Inv. Example 2570 9.8 FC 3.5 1.42 0 0.5 16.5 3.92 Inv. Example 2571 9.6 FC 4.5 1.33 0.2 0.1 8.5 0.12 Inv. Example 2572 7.5 FC 1.6 1.42 0 0.5 10.5 1.25 Inv. Example 2573 4.6 FC 2.5 1.12 5.8 0.1 5.8 0.40 Inv. Example 2574 3.8 FC 23.5 1.23 1.2 0.6 1.2 1.09 Inv. Example 2575 0.05 FC 9.8 1.27 15.5 0 15.5 0.03 Coat Properties Mg Contents to Ratio of Metal Total Metal Particle in Dry Coat Result of Particle Coat Thickness Coating Corrosion (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 2556 4.5 40 alkali silicate 18 Spraying very good Inv. Example 2557 0.3 44 alkyl silicate 18 Spraying very good Inv. Example 2558 0.08 44 alkali silicate 38 Spraying very good Inv. Example 2559 0.05 36 alkyl silicate 18 Spraying very good Inv. Example 2560 0.005 76 alkyl silicate 10 Spraying very good Inv. Example 2561 2.8 77 alkyl silicate 37 Spraying very good Inv. Example 2562 0.6 43 alkali silicate 2 Spraying good Inv. Example 2563 1 52 alkyl silicate 160 Brushing very good Inv. Example 2564 0.09 66 alkali silicate 5 Brushing very good Inv. Example 2565 3.4 72 alkyl silicate 56 Brushing very good Inv. Example 2566 1.5 53 urethane-based 99 Spraying very good resin Inv. Example 2567 200 55 urethane-based 700 Spraying very good resin Inv. Example 2568 15 47 alkyl silicate 554 Spraying very good Inv. Example 2569 5 79 urethane-based 688 Brushing very good resin Inv. Example 2570 1.5 42 urethane-based 421 Spraying very good resin Inv. Example 2571 78 36 urethane-based 651 Spraying very good resin Inv. Example 2572 5 53 urethane-based 402 Brushing very good resin Inv. Example 2573 10.5 55 alkali silicate 354 Spraying very good Inv. Example 2574 2.5 42 urethane-based 504 Brushing very good resin Inv. Example 2575 1 76 urethane-based 666 Spraying very good resin (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

Example 7

Zn alloy particles with the chemical ingredients shown in Tables 92 to 108 were produced in the same way as in Example 5. At the time of preparing the paint, four commercially available organic-based binders were used. The rest is the same as Example 5.

The Mg solid solution phase was identified by the X-ray diffraction method. The Zn—Mg intermetallic compounds were identified by analysis of the ratio of composition of the Mg and Zn at the physical fracture facets or crack surfaces by the X-ray diffraction method or by observation by a scanning electron microscopy with an energy dispersion type X-ray analyzer. The composition was MgZn₂, Mg₂Zn₁₁, Mg₂Zn₃, MgZn, or Mg₇Zn₃.

From Tables 92 to 108, it is learned that due to the surfaces of the particles including fractured parts and/or cracks having a Mg solid solution phase and Zn—Mg intermetallic compounds, the painting test pieces using the Zn alloy particles of the present invention are improved in corrosion resistance and rust protection.

TABLE 92 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg Average Intermetallic Fracture Mean Value of Compounds on Mg Facet &/or Size Aspect Al Si Surface of MgZn₂ or (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ Inv. Example 277 17.3 F 29.24 1.37 11.4 0.24 Existence No Inv. Example 278 18.5 F 1.28 1.10 0.04 0.03 Existence No Inv. Example 279 19.3 F 33.57 1.04 0.25 0.07 Existence No Inv. Example 280 3.5 F 3.04 1.02 5.43 0.65 Existence No Inv. Example 281 22.5 F 7.54 1.01 17.5 2.41 Existence No Inv. Example 282 23.7 F 68.12 1.08 0.01 0.08 Existence No Inv. Example 283 24.2 F 0.52 1.14 0.02 2.23 Existence No Inv. Example 284 0.2 F 0.12 1.23 0.02 0.06 Existence No Inv. Example 285 27.1 F 58.74 1.33 0.04 0.02 Existence No Inv. Example 286 29.3 F 13.57 1.37 0.05 0.02 Existence No Inv. Example 287 0.5 F 6.4 1.44 1.24 1.37 Existence No Inv. Example 288 2.7 F 41.23 1.21 27.5 2.43 Existence No Inv. Example 289 28.4 F 0.72 1.22 0.01 0.02 Existence No Inv. Example 290 8.7 F 1.18 1.23 0.01 0.01 Existence No Inv. Example 291 9.2 F 7.12 1.47 0.02 0.05 Existence No Inv. Example 292 17.8 F 8.01 1.01 0.03 0.04 Existence No Inv. Example 293 20.2 F 0.84 1.04 7.78 0.24 Existence No Inv. Example 294 0.4 F 87.65 1.05 0.04 0.06 Existence No Inv. Example 295 13.7 F 2.59 1.12 11.21 0.74 Existence No Inv. Example 296 14.7 F 93.45 1.11 0.09 0.01 Existence No Inv. Example 297 2.4 F 9.84 1.08 5.41 1.27 Existence No Inv. Example 298 4.5 F 5.45 1.47 0.02 0.03 Existence No Inv. Example 299 0.1 F 1.08 1.50 0.02 0.07 Existence No Inv. Example 300 30.0 F 180.24 1.13 0.03 0.08 Existence Existence Inv. Example 301 24.5 F 11.4 1.04 11.04 0.21 Existence Existence Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in Coat Result of particle Metal Particle Dry Coat Thickness Coating Corrosion (μm) Particle) (mass %) (mass %) Base Resin (μm) Method Test 37.45 300:1 17.24 44 alkali 35 Spraying very good Inv. Example 277 silicate 2.56  65:1 18.22 54 alkyl 15 Spraying very good Inv. Example 278 silicate 17.87 300:1 19.24 79 alkali 45 Spraying very good Inv. Example 279 silicate 6.87  65:1 3.49 73 alkyl 12 Spraying very good Inv. Example 280 silicate 22.54 300:1 22.43 69 alkali 16 Brushing very good Inv. Example 281 silicate 29.54 150:1 23.54 63 alkyl 70 Brushing very good Inv. Example 282 silicate 3.89 300:1 24.12 35 alkali 2 Brushing very good Inv. Example 283 silicate 4.56  65:1 0.20 35 alkyl 65 Brushing very good Inv. Example 284 silicate 35.64 300:1 27.01 72 alkali 29 Spraying very good Inv. Example 285 silicate 26.41 150:1 29.11 46 alkyl 28 Spraying very good Inv. Example 286 silicate 7.89 300:1 0.50 34 alkali 14 Spraying very good Inv. Example 287 silicate 17.54  70:1 2.66 66 alkyl 62 Brushing very good Inv. Example 288 silicate 7.78 300:1 28.31 72 alkali 4 Brushing very good Inv. Example 289 silicate 6.54 100:1 8.61 40 alkyl 6 Brushing very good Inv. Example 290 silicate 10.28 250:1 9.16 36 alkali 15 Spraying very good Inv. Example 291 silicate 9.98 150:1 17.68 32 alkyl 17 Spraying very good Inv. Example 292 silicate 5.64 170:1 20.08 53 alkali 2 Spraying very good Inv. Example 293 silicate 31.24 300:1 0.40 67 alkyl 90 Brushing very good Inv. Example 294 silicate 18.54 200:1 13.63 72 alkali 12 Brushing very good Inv. Example 295 silicate 16.78 300:1 14.65 77 alkyl 110 Brushing very good Inv. Example 296 silicate 3.65 150:1 2.38 54 alkali 27 Spraying very good Inv. Example 297 silicate 8.54 300:1 4.49 62 alkyl 16 Spraying very good Inv. Example 298 silicate 3.45  65:1 0.10 66 alkali 15 Spraying very good Inv. Example 299 silicate 34.87  80:1 29.63 67 alkyl 198 Brushing very good Inv. Example 300 silicate 22.14   1:15 1.53 68 alkali 25 Brushing very good Inv. Example 301 silicate (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 93 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg Average Intermetallic Fracture Mean Value of Compounds on Mg Facet &/or Size Aspect Al Si Surface of MgZn₂ or (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ Inv. Example 302 27.6 F 38.75 1.02 0.01 0.02 Existence Existence Inv. Example 303 4.1 F 119.87 1.08 0.07 0.04 Existence Existence Inv. Example 304 3.2 F 1.42 1.15 0.08 0.01 Existence Existence Inv. Example 305 2.7 F 12.5 1.34 0.04 0.03 Existence Existence Inv. Example 306 0.12 F 31.24 1.25 0.02 0.04 Existence Existence Inv. Example 307 0.22 F 152.46 1.19 0.02 0.02 Existence Existence Inv. Example 308 0.37 F 13.4 1.18 4.12 0.61 Existence Existence Inv. Example 309 1.4 F 1.61 1.24 0.05 0.02 Existence Existence Inv. Example 310 4.2 F 14.1 1.11 2.14 0.74 Existence Existence Inv. Example 311 4.8 F 1.67 1.27 0.03 0.02 Existence Existence Inv. Example 312 8.1 F 1.45 1.31 0.03 0.04 Existence Existence Inv. Example 313 7.6 F 14.8 1.26 0.04 0.05 Existence Existence Inv. Example 314 9.9 F 1.31 1.14 7.54 1.24 Existence Existence Inv. Example 315 14.8 F 15.5 1.34 0.08 0.06 Existence Existence Inv. Example 316 16.7 F 0.67 1.16 0.01 0.07 Existence Existence Inv. Example 317 17.9 F 137.89 1.47 29.8 0.75 Existence Existence Inv. Example 318 19.5 F 1.63 1.48 0.01 0.02 Existence Existence Inv. Example 319 22.4 F 1.12 1.49 0.03 0.01 Existence Existence Inv. Example 320 0.17 F 169.88 1.34 0.02 0.01 Existence Existence Inv. Example 321 8.3 F 1.72 1.29 8.04 1.24 Existence Existence Inv. Example 322 6.5 F 10.5 1.18 0.06 0.04 Existence Existence Inv. Example 323 9.7 F 17.7 1.23 0.08 0.02 Existence Existence Inv. Example 324 11.4 F 122.54 1.27 0.03 0.01 Existence Existence Inv. Example 325 22.5 F 1.84 1.17 0.04 0.03 Existence Existence Inv. Example 326 25.7 F 19.1 1.16 7.42 1.22 Existence Existence Inv. Example 327 17.8 F 1.75 1.49 0.02 0.01 Existence Existence Inv. Example 328 0.14 F 198.78 1.34 0.08 0.02 Existence Existence Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in Coat Result of particle Metal Particle Dry Coat Thickness Coating Corrosion (μm) Particle) (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 302 25.87 200:1  27.46 33 alkyl 45 Brushing very good silicate Inv. Example 303 38.74 65:1 4.04 35 epoxy-based 130 Brushing very good resin Inv. Example 304 3.64 300:1  3.19 43 acryl-based 15 Spraying very good resin Inv. Example 305 24.5 70:1 2.66 44 urethane- 18 Spraying very good based resin Inv. Example 306 38.5 65:1 0.12 42 polyester 41 Spraying very good resin Inv. Example 307 38.42 65:1 0.22 33 epoxy-based 170 Brushing very good resin Inv. Example 308 5.87 50:1 0.36 30 acryl-based 22 Brushing very good resin Inv. Example 309 3.46 30:1 1.35 35 urethane- 6 Brushing very good based resin Inv. Example 310 17.45 20:1 4.00 37 polyester 21 Spraying very good resin Inv. Example 311 3.66 100:1  4.75 30 epoxy-based 7 Spraying very good resin Inv. Example 312 6.45 80:1 8.00 80 acryl-based 5 Spraying very good resin Inv. Example 313 21.7 200:1  7.56 35 urethane- 21 Spraying very good based resin Inv. Example 314 7.74 150:1  9.83 43 polyester 12 Spraying very good resin Inv. Example 315 2.45 85:1 14.63 55 epoxy-based 24 Spraying very good resin Inv. Example 316 8.59 70:1 16.46 76 acryl-based 2 Spraying very good resin Inv. Example 317 24.78  1:99 0.18 65 urethane- 154 Brushing very good based resin Inv. Example 318 3.78  1:60 0.32 73 polyester 12 Brushing very good resin Inv. Example 319 6.54  1:15 1.40 54 epoxy-based 8 Brushing very good resin Inv. Example 320 33.78 90:1 0.17 62 acryl-based 180 Brushing very good resin Inv. Example 321 3.25 120:1  8.23 68 urethane- 5 Spraying very good based resin Inv. Example 322 19.84 100:1  6.44 35 polyester 23 Spraying very good resin Inv. Example 323 26.78  1:60 0.16 37 epoxy-based 35 Spraying very good resin Inv. Example 324 37.54 130:1  11.31 38 acryl-based 138 Brushing very good resin Inv. Example 325 5.47 160:1  22.36 41 urethane- 5 Spraying very good based resin Inv. Example 326 24.51 100:1  25.45 54 polyester 28 Spraying very good resin Inv. Example 327 5.55 50:1 17.45 57 epoxy-based 7 Brushing very good resin Inv. Example 328 38.47  1:80 0.00 33 acryl-based 199 Brushing very good resin (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 94 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg Average Intermetallic Fracture Mean Value of Compounds on Mg Facet &/or Size Aspect Al Si Surface of MgZn₂ or (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ Inv. Example 1599 0.15 FC 0.02 1.05 0.1 0.07 Existence Existence Inv. Example 1600 0.19 FC 10.5 1.12 0.04 0.1 Existence Existence Inv. Example 1601 0.18 FC 12.5 1.23 30.0 0.01 Existence No Inv. Example 1602 0.11 FC 18.5 1.36 0.02 3 Existence Existence Inv. Example 1603 0.15 FC 11.5 1.11 0 0 Existence No Inv. Example 1604 0.24 FC 9.6 1.07 0 0 Existence Existence Inv. Example 1605 0.18 FC 8.5 1.42 10.4 0.57 Existence No Inv. Example 1606 0.12 FC 7.72 1.38 4.65 2.67 Existence Existence Inv. Example 1607 0.19 FC 8.32 1.22 24.8 2.4 Existence No Inv. Example 1608 0.18 FC 10.05 1.14 4.52 0.57 Existence No Inv. Example 1609 0.21 FC 10.6 1.13 17.5 2.45 Existence Existence Inv. Example 1610 0.76 FC 5.7 1.02 0 0 Existence No Inv. Example 1611 0.11 FC 6.4 1.06 11.05 0.23 Existence Existence Inv. Example 1612 0.14 FC 3.2 1.05 2.65 0.74 Existence Existence Inv. Example 1613 15 FC 4.5 1.24 6.45 2.14 Existence No Inv. Example 1614 14.5 FC 5.2 1.33 0 0 Existence No Inv. Example 1615 18.5 FC 1.9 1.27 0 0 Existence Existence Inv. Example 1616 15.1 FC 0.02 1.05 0.05 0.03 Existence No Inv. Example 1617 15.6 FC 10.5 1.12 0 0.08 Existence No Inv. Example 1618 12.5 FC 12.5 1.23 0.05 0 Existence Existence Inv. Example 1619 18.7 FC 18.5 1.36 0.44 0.07 Existence Existence Inv. Example 1620 14.5 FC 11.5 1.11 0.08 0.07 Existence Existence Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in Coat Result of particle Metal Particle Dry Coat Thickness Coating Corrosion (μm) Particle) (mass %) (mass %) Base Resin (μm) Method Test 2.04  5:2 0.11 35 alkali 2 Spraying very good Inv. Example 1599 silicate 50.00  7:1 0.17 77 alkyl 37 Spraying very good Inv. Example 1600 silicate 2.45  68:1 0.16 43 alkali 2 Spraying good Inv. Example 1601 silicate 5.33  10:1 0.10 52 alkyl 160 Brushing very good Inv. Example 1602 silicate 2.41  25:7 0.12 66 alkali 5 Brushing very good Inv. Example 1603 silicate 23.43 300:9 0.23 72 alkyl 56 Brushing very good Inv. Example 1604 silicate 6.03 180:1 0.18 40 alkali 2 Spraying very good Inv. Example 1605 silicate 24.5  23:1 0.12 36 alkyl 18 Spraying very good Inv. Example 1606 silicate 5.32 165:1 0.19 32 alkyl 23 Spraying very good Inv. Example 1607 silicate 14.34 300:1 0.18 53 epoxy-based 30 Brushing very good Inv. Example 1608 resin 5.04 120:1 0.21 67 acryl-based 77 Brushing very good Inv. Example 1609 resin 2.32  2:9 0.14 72 urethane- 54 Brushing very good Inv. Example 1610 based resin 20.34 119:3 0.11 77 polyester 47 Spraying very good Inv. Example 1611 resin 12.33 233:1 0.14 34 epoxy-based 43 Spraying very good Inv. Example 1612 resin 17.84   1:132 0.11 43 acryl-based 52 Brushing very good Inv. Example 1613 resin 6.66   1:55 10.24 53 urethane- 20 Brushing very good Inv. Example 1614 based resin 3.65   1:23 0.77 60 polyester 200 Brushing very good Inv. Example 1615 resin 22.62 200:1 15.02 35 alkali 22 Spraying very good Inv. Example 1616 silicate 45.33   1:15 0.98 77 alkyl 25 Spraying very good Inv. Example 1617 silicate 43.22   1:10 1.14 43 alkali 14 Spraying very good Inv. Example 1618 silicate 12.33  1:6 2.67 52 urethane- 112 Spraying very good Inv. Example 1619 based resin 13.42   1:45 0.32 66 alkali 24 Spraying very good Inv. Example 1620 silicate (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 95 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg Average Intermetallic Fracture Mean Value of Compounds on Mg Facet &/or Size Aspect Al Si Surface of MgZn₂ or (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ Inv. Example 1621 7.5 FC 9.6 1.07 0.1 0.2 Existence No Inv. Example 1622 4.5 FC 8.5 1.42 0 0 Existence Existence Inv. Example 1623 1.5 FC 7.72 1.38 0 0 Existence Existence Inv. Example 1624 4.8 FC 8.32 1.22 0 0.07 Existence Existence Inv. Example 1625 9.6 FC 10.05 1.14 0 0.02 Existence No Inv. Example 1626 11.5 FC 10.6 1.13 25.8 0.05 Existence Existence Inv. Example 1627 9.8 FC 5.7 1.02 22.1 0 Existence Existence Inv. Example 1628 7.6 FC 6.4 1.06 21.5 0.05 Existence Existence Inv. Example 1629 3.2 FC 3.2 1.05 0.05 2.29 Existence No Inv. Example 1630 1.9 FC 4.5 1.24 0.05 0.03 Existence Existence Inv. Example 1631 11.5 FC 5.2 1.33 0 0.08 Existence Existence Inv. Example 1632 8.7 FC 1.9 1.27 0 0 Existence No Inv. Example 1633 9.6 FC 0.02 1.05 0 0 Existence Existence Inv. Example 1634 9.4 FC 10.5 1.12 0.08 0.07 Existence No Inv. Example 1635 10.5 FC 12.5 1.23 0.1 0.2 Existence Existence Inv. Example 1636 12.6 FC 18.5 1.36 0.05 0.2 Existence No Inv. Example 1637 29.5 FC 11.5 1.11 0.07 0 Existence Existence Inv. Example 1638 29.4 FC 9.6 1.07 0 0.07 Existence Existence Inv. Example 1639 27.5 FC 8.5 1.42 0 0.02 Existence Existence Inv. Example 1640 0.8 FC 7.72 1.38 25.8 0.05 Existence Existence Inv. Example 1641 1.6 FC 8.32 1.22 22.1 0 Existence No Inv. Example 1642 22.9 FC 10.05 1.14 21.5 0.05 Existence No Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in Coat Result of particle Metal Particle Dry Coat Thickness Coating Corrosion (μm) Particle) (mass %) (mass %) Base Resin (μm) Method Test 22.32 1:50 0.15 72 urethane- 150 Spraying very good Inv. Example 1621 based resin 7.34 1:9 0.45 40 alkali 18 Spraying very good Inv. Example 1622 silicate 44.54 1:7 0.19 36 alkyl 19 Brushing very good Inv. Example 1623 silicate 32.87 1:4 0.96 32 alkyl 24 Spraying very good Inv. Example 1624 silicate 20.32  1:14 0.64 53 urethane- 99 Spraying very good Inv. Example 1625 based resin 2.03  1:11 0.96 67 alkyl 7 Spraying very good Inv. Example 1626 silicate 5.33  1:28 0.34 72 epoxy-based 100 Spraying very good Inv. Example 1627 resin 2.33 1:4 1.52 77 alkyl 27 Brushing very good Inv. Example 1628 silicate 27.44 250:1  3.19 34 alkali 15 Spraying very good Inv. Example 1629 silicate 12.33 1:1 0.95 43 alkyl 14 Spraying very good Inv. Example 1630 silicate 36.43 1:4 2.30 53 urethane- 55 Spraying very good Inv. Example 1631 based resin 12.33  1:12 0.67 35 alkyl 8 Spraying very good Inv. Example 1632 silicate 3.21 70:1  9.46 77 urethane- 122 Brushing very good Inv. Example 1633 based resin 26.33 1:3 2.35 43 alkyl 54 Spraying very good Inv. Example 1634 silicate 44.21  1:24 0.42 52 alkali 19 Spraying very good Inv. Example 1635 silicate 3.43  1:10 1.15 66 alkyl 25 Brushing very good Inv. Example 1636 silicate 47.32 300:1  29.40 72 alkyl 58 Spraying very good Inv. Example 1637 silicate 12.33  1:66 0.44 40 alkyl 21 Spraying very good Inv. Example 1638 silicate 17.44 120:1  27.27 36 alkali 19 Brushing very good Inv. Example 1639 silicate 42.21 6:5 0.44 32 urethane- 56 Spraying very good Inv. Example 1640 based resin 12.34 1:1 0.80 53 alkyl 77 Spraying very good Inv. Example 1641 silicate 20.32 1:1 11.45 67 alkyl 54 Spraying very good Inv. Example 1642 silicate (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 96 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg Average Intermetallic Fracture Mean Value of Compounds on Mg Facet &/or Size Aspect Al Si Surface of MgZn₂ or (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ Inv. Example 1643 28.5 FC 10.6 1.13 0.05 2.29 Existence No Inv. Example 1644 29.5 FC 5.7 1.02 0.1 0.2 Existence Existence Inv. Example 1645 18.7 FC 6.4 1.06 0.05 0.2 Existence No Inv. Example 1646 19.5 FC 3.2 1.05 0.07 0 Existence Existence Inv. Example 1647 20.4 FC 4.5 1.24 0 0.07 Existence Existence Inv. Example 1648 0.6 FC 5.2 1.33 0 0.02 Existence Existence Inv. Example 1649 0.8 FC 1.9 1.27 22.1 0 Existence Existence Inv. Example 1650 22.5 FC 0.02 1.05 0.1 0.07 Existence Existence Inv. Example 1651 20.6 FC 10.5 1.12 0.04 0.1 Existence Existence Inv. Example 1652 21.6 FC 12.5 1.23 30.0 0.01 Existence No Inv. Example 1653 20.8 FC 7.72 1.38 0 0 Existence Existence Inv. Example 1654 23.6 FC 8.32 1.22 0 0 Existence Existence Inv. Example 1655 24.5 FC 10.05 1.14 4.52 0.57 Existence No Inv. Example 1656 18.6 FC 10.6 1.13 17.5 2.45 Existence Existence Inv. Example 1657 17.8 FC 5.2 1.33 27.6 2.4 Existence No Inv. Example 1658 16.5 FC 1.9 1.27 4.32 1.07 Existence Existence Inv. Example 1659 14.5 FC 0.02 1.05 0.05 0.03 Existence No Inv. Example 1660 19 FC 10.5 1.12 0 0.08 Existence No Inv. Example 1661 15 FC 12.5 1.23 0.05 0 Existence Existence Inv. Example 1662 16.4 FC 18.5 1.36 0.44 0.07 Existence Existence Inv. Example 1663 13.5 FC 11.5 1.11 0.08 0.07 Existence Existence Inv. Example 1664 10.6 FC 11.5 1.11 8.02 2.04 Existence No Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in Coat Result of particle Metal Particle Dry Coat Thickness Coating Corrosion (μm) Particle) (mass %) (mass %) Base Resin (μm) Method Test 23.44 1:76 0.37 72 alkyl 64 Spraying very good Inv. Example 1643 silicate 23.45 1:6  4.21 77 alkyl 34 Brushing very good Inv. Example 1644 silicate 23.21 1:35 0.52 34 alkali 28 Spraying very good Inv. Example 1645 silicate 39.44 1:5  3.25 43 urethane- 109 Brushing very good Inv. Example 1646 based resin 12.34 1:62 0.32 53 alkyl 15 Spraying very good Inv. Example 1647 silicate 29.99 1:4  0.12 72 alkyl 14 Spraying very good Inv. Example 1648 silicate 15.21 5:9  0.29 77 alkyl 18 Spraying very good Inv. Example 1649 silicate 23.34  1:220 0.10 35 alkali 2 Spraying very good Inv. Example 1650 silicate 2.32 1:80 0.25 77 alkyl 37 Spraying very good Inv. Example 1651 silicate 4.21 1:50 0.42 43 alkali 2 Spraying good Inv. Example 1652 silicate 15.21 1:10 1.89 52 alkyl 160 Brushing very good Inv. Example 1653 silicate 23.34 1:1  11.80 66 alkali 5 Brushing very good Inv. Example 1654 silicate 2.32 1:78 0.31 72 alkyl 56 Brushing very good Inv. Example 1655 silicate 4.21 1:10 1.69 40 alkali 2 Spraying very good Inv. Example 1656 silicate 29.99 1:50 0.35 36 alkyl 18 Spraying very good Inv. Example 1657 silicate 15.21 1:10 1.50 32 alkyl 23 Spraying very good Inv. Example 1658 silicate 23.34 1:1  7.25 53 epoxy-based 30 Brushing very good Inv. Example 1659 resin 2.32 1:3  4.75 67 acryl-based 77 Brushing very good Inv. Example 1660 resin 4.21 1:7  1.88 72 urethane- 54 Brushing very good Inv. Example 1661 based resin 15.21 1:50 0.32 77 polyester 47 Spraying very good Inv. Example 1662 resin 23.34 1:10 1.23 34 epoxy-based 43 Spraying very good Inv. Example 1663 resin 13.45 1:3  2.65 43 acryl-based 52 Brushing very good Inv. Example 1664 resin (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 97 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg Average Intermetallic Fracture Mean Value of Compounds on Mg Facet &/or Size Aspect Al Si Surface of MgZn₂ or (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ Inv. Example 1665 10.7 FC 9.6 1.07 15.6 1.27 Existence Existence Inv. Example 1666 10.9 FC 8.5 1.42 10.4 0.57 Existence No Inv. Example 1667 11.6 FC 7.72 1.38 4.65 2.67 Existence Existence Inv. Example 1668 14.7 FC 8.32 1.22 24.8 2.4 Existence No Inv. Example 1669 19.5 FC 10.05 1.14 4.52 0.57 Existence No Inv. Example 1670 10.2 FC 10.6 1.13 0 0 Existence Existence Inv. Example 1671 4 FC 5.7 1.02 0 0 Existence No Inv. Example 1672 7.2 FC 6.4 1.06 11.05 0.23 Existence Existence Inv. Example 1673 3.6 FC 3.2 1.05 2.65 0.74 Existence Existence Inv. Example 1674 26.9 FC 4.5 1.24 6.45 2.14 Existence No Inv. Example 1675 27.9 FC 5.2 1.33 27.6 2.4 Existence No Inv. Example 1676 28.9 FC 1.9 1.27 4.32 1.07 Existence Existence Inv. Example 1677 23.8 FC 0.02 1.05 0.05 0.03 Existence No Inv. Example 1678 26.8 FC 10.5 1.12 0 0.08 Existence No Inv. Example 1679 25.6 FC 12.5 1.23 0.05 0 Existence Existence Inv. Example 1680 29.8 FC 18.5 1.36 0.44 0.07 Existence Existence Inv. Example 1681 18.9 FC 11.5 1.11 0.08 0.07 Existence Existence Inv. Example 1682 5.6 FC 9.6 1.07 0.1 0.2 Existence No Inv. Example 1683 4.7 FC 8.5 1.42 0.05 0.2 Existence Existence Inv. Example 1684 6.8 FC 7.72 1.38 0.07 0 Existence Existence Inv. Example 1685 9 FC 8.32 1.22 0 0.07 Existence Existence Inv. Example 1686 2.1 FC 10.05 1.14 0 0.02 Existence No Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in Coat Result of particle Metal Particle Dry Coat Thickness Coating Corrosion (μm) Particle) (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 1665 2.34  1:10 0.97 53 urethane- 20 Brushing very good based resin Inv. Example 1666 28.34 1:5 1.82 60 polyester 200 Brushing very good resin Inv. Example 1667 19.87 200:1  11.54 35 alkali 22 Spraying very good silicate Inv. Example 1668 39.74 1:8 1.63 77 alkyl 25 Spraying very good silicate Inv. Example 1669 24.32 1:1 9.75 43 alkali 14 Spraying very good silicate Inv. Example 1670 22.33 1:7 1.28 52 urethane- 112 Spraying very good based resin Inv. Example 1671 48.54 1:3 1.00 66 alkali 24 Spraying very good silicate Inv. Example 1672 23.75 1:7 0.90 72 urethane- 150 Spraying very good based resin Inv. Example 1673 15.62 1:2 1.20 40 alkali 18 Spraying very good silicate Inv. Example 1674 2.34 117:1  26.67 36 alkyl 19 Brushing very good silicate Inv. Example 1675 23.04  1:270 0.10 32 alkyl 24 Spraying very good silicate Inv. Example 1676 3.05  1:117 0.24 53 urethane- 99 Spraying very good based resin Inv. Example 1677 43.23  1:66 0.36 67 alkyl 7 Spraying very good silicate Inv. Example 1678 2.04  1:109 0.24 72 epoxy-based 100 Spraying very good resin Inv. Example 1679 50.00 250:1  25.50 77 alkyl 27 Brushing very good silicate Inv. Example 1680 2.45 70:1  29.38 34 alkali 15 Spraying very good silicate Inv. Example 1681 5.33  1:15 1.18 43 alkyl 14 Spraying very good silicate Inv. Example 1682 2.41 1:5 0.93 53 urethane- 55 Spraying very good based resin Inv. Example 1683 23.43 2:3 1.88 35 alkyl 8 Spraying very good silicate Inv. Example 1684 6.03 1:9 0.68 77 urethane- 122 Brushing very good based resin Inv. Example 1685 24.5  1:10 0.82 43 alkyl 54 Spraying very good silicate Inv. Example 1686 5.32  1:14 0.14 52 alkali 19 Spraying very good silicate (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 98 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg Average Intermetallic Fracture Mean Value of Compounds on Mg Facet &/or Size Aspect Al Si Surface of MgZn₂ or (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ Inv. Example 1687 4.8 FC 10.6 1.13 0 0 Existence Existence Inv. Example 1688 4.2 FC 5.7 1.02 0 0 Existence Existence Inv. Example 1689 4.3 FC 6.4 1.06 21.5 0.05 Existence Existence Inv. Example 1690 4 FC 3.2 1.05 0.05 2.29 Existence No Inv. Example 1691 3.7 FC 4.5 1.24 0.05 0.03 Existence Existence Inv. Example 1692 6.4 FC 5.2 1.33 0 0.08 Existence Existence Inv. Example 1693 6.9 FC 1.9 1.27 0.05 0 Existence No Inv. Example 1694 16.9 FC 0.02 1.05 0.44 0.07 Existence Existence Inv. Example 1695 18.7 FC 10.5 1.12 0.08 0.07 Existence No Inv. Example 1696 24.4 FC 12.5 1.23 0.1 0.2 Existence Existence Inv. Example 1697 10.6 FC 18.5 1.36 0 0 Existence No Inv. Example 1698 15.8 FC 11.5 1.11 0 0 Existence Existence Inv. Example 1699 19.5 FC 9.6 1.07 0 0.07 Existence Existence Inv. Example 1700 7.8 FC 8.5 1.42 0 0.02 Existence Existence Inv. Example 1701 4.9 FC 7.72 1.38 25.8 0.05 Existence Existence Inv. Example 1702 10.8 FC 8.32 1.22 22.1 0 Existence No Inv. Example 1703 3.8 FC 10.05 1.14 21.5 0.05 Existence No Inv. Example 1704 22.6 FC 10.6 1.13 0.05 2.29 Existence No Inv. Example 1705 27.9 FC 5.7 1.02 0 0 Existence Existence Inv. Example 1706 24.8 FC 6.4 1.06 0 0 Existence No Inv. Example 1707 26.8 FC 3.2 1.05 0.07 0 Existence Existence Inv. Example 1708 25.9 FC 4.5 1.24 0 0.07 Existence Existence Inv. Example 1709 9.8 FC 5.2 1.33 0 0.02 Existence Existence Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in Coat Result of particle Metal Particle Dry Coat Thickness Coating Corrosion (μm) Particle) (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 1687 14.34 1:7 0.60 66 alkyl 25 Brushing very good silicate Inv. Example 1688 5.04  1:12 0.32 72 alkyl 58 Spraying very good silicate Inv. Example 1689 2.32 1:3 1.08 40 alkyl 21 Spraying very good silicate Inv. Example 1690 20.34 1:7 0.50 36 alkali 19 Brushing very good silicate Inv. Example 1691 12.33  1:10 0.34 32 urethane- 56 Spraying very good based resin Inv. Example 1692 17.84 1:1 3.20 53 alkyl 77 Spraying very good silicate Inv. Example 1693 6.66 1:3 1.73 67 alkyl 54 Spraying very good silicate Inv. Example 1694 3.65 2:3 6.76 72 alkyl 64 Spraying very good silicate Inv. Example 1695 22.62 1:2 6.23 77 alkyl 34 Brushing very good silicate Inv. Example 1696 45.33 1:4 4.88 34 alkali 28 Spraying very good silicate Inv. Example 1697 43.22 1:6 1.51 43 urethane- 109 Brushing very good based resin Inv. Example 1698 12.33  1:115 0.14 53 alkyl 15 Spraying very good silicate Inv. Example 1699 13.42  1:23 0.81 72 alkyl 14 Spraying very good silicate Inv. Example 1700 22.32  1:12 0.60 77 alkyl 18 Spraying very good silicate Inv. Example 1701 7.34  1:10 0.45 77 urethane- 122 Brushing very good based resin Inv. Example 1702 44.54 1:3 2.70 43 alkyl 54 Spraying very good silicate Inv. Example 1703 32.87 1:5 0.63 52 alkali 19 Spraying very good silicate Inv. Example 1704 20.32  1:25 0.87 66 alkyl 25 Brushing very good silicate Inv. Example 1705 2.03 4:5 12.40 72 alkyl 58 Spraying very good silicate Inv. Example 1706 5.33 3:8 6.76 40 alkyl 21 Spraying very good silicate Inv. Example 1707 2.33  9:34 5.61 36 alkali 19 Brushing very good silicate Inv. Example 1708 27.44 7:8 12.09 32 urethane- 56 Spraying very good based resin Inv. Example 1709 12.33  9:17 3.39 53 alkyl 77 Spraying very good silicate (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 99 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg Average Intermetallic Fracture Mean Value of Compounds on Mg Facet &/or Size Aspect Al Si Surface of MgZn₂ or (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ Inv. Example 1710 5.6 FC 1.9 1.27 22.1 0 Existence Existence Inv. Example 1711 12.3 FC 0.02 1.05 1.24 1.8 Existence Existence Inv. Example 1712 0.8 FC 27.89 1.12 1.24 0.9 Existence Existence Inv. Example 1713 1 FC 0.32 1.23 0.8 0.7 Existence No Inv. Example 1714 2.3 FC 11.44 1.36 0 1.8 Existence Existence Inv. Example 1715 15.6 FC 1.05 1.11 1.1 2.41 Existence Existence Inv. Example 1716 6.7 FC 36.47 1.07 1.8 0.08 Existence Existence Inv. Example 1717 7.5 FC 5.07 1.42 3.8 2.23 Existence No Inv. Example 1718 8.4 FC 7.72 1.38 2.9 0.06 Existence Existence Inv. Example 1719 9.3 FC 8.32 1.22 10.5 0.02 Existence Existence Inv. Example 1720 10.4 FC 10.05 1.14 2.9 0.02 Existence Existence Inv. Example 1721 11.2 FC 6.08 1.13 16.8 1.37 Existence No Inv. Example 1722 11.7 FC 17.89 1.02 0 2.43 Existence Existence Inv. Example 1723 21.5 FC 19.54 1.06 3.6 0.02 Existence Existence Inv. Example 1724 13.4 FC 21.08 1.05 2.1 1.5 Existence No Inv. Example 1725 14.6 FC 23.04 1.24 0.06 1.3 Existence Existence Inv. Example 1726 25.8 FC 9.21 1.33 0.02 1.8 Existence Existence Inv. Example 1727 16.7 FC 0.12 1.27 1.6 0.9 Existence Existence Inv. Example 1728 17.3 FC 29.24 1.37 3.5 0 Existence Existence Inv. Example 1729 18.5 FC 128.74 1.10 9.8 1.8 Existence No Inv. Example 1730 19.3 FC 33.57 1.04 11.5 0.7 Existence Existence Inv. Example 1731 3.5 FC 3.04 1.02 0.4 1.5 Existence Existence Inv. Example 1732 22.5 FC 7.54 1.01 0.6 1.3 Existence Existence Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in Coat Result of particle Metal Particle Dry Coat Thickness Coating Corrosion (μm) Particle) (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 1710 36.43 1:1 2.80 67 alkyl 54 Spraying very good silicate Inv. Example 1711 11.9  1:31 0.38 52 alkali 2 Spraying very good silicate Inv. Example 1712 10.5 1:4 0.16 55 alkali 20 Spraying very good silicate Inv. Example 1713 9.8 1:1 0.50 69 alkali 5 Spraying very good silicate Inv. Example 1714 7.9 1:7 0.29 78 alkyl 20 Spraying very good silicate Inv. Example 1715 11.6  1:11 1.30 42 alkali 15 Brushing very good silicate Inv. Example 1716 16.9 1:2 2.23 32 alkyl 57 Brushing very good silicate Inv. Example 1717 20.34 1:7 0.94 66 alkali 13 Brushing very good silicate Inv. Example 1718 8.9 1:4 1.68 67 alkyl 22 Brushing very good silicate Inv. Example 1719 7.5 1:5 1.55 64 alkali 20 Spraying very good silicate Inv. Example 1720 10.9  1:10 0.95 74 alkyl 27 Spraying very good silicate Inv. Example 1721 20.34 1:9 1.12 82 alkali 15 Spraying very good silicate Inv. Example 1722 6.7 240:1  11.65 37 alkyl 35 Spraying very good silicate Inv. Example 1723 7.9  1:120 0.18 42 alkali 34 Brushing very good silicate Inv. Example 1724 5.6 99:1  13.27 66 alkyl 45 Brushing very good silicate Inv. Example 1725 11.5  1:99 0.15 48 alkali 52 Brushing very good silicate Inv. Example 1726 20.34  1:242 0.11 33 alkyl 23 Brushing very good silicate Inv. Example 1727 10.5 1:6 2.39 75 alkali 5 Spraying very good silicate Inv. Example 1728 7.6 1:1 8.65 77 alkyl 52 Brushing very good silicate Inv. Example 1729 8.2 1:7 2.31 66 alkali 150 Brushing very good silicate Inv. Example 1730 9.1 1:5 3.22 67 alkyl 60 Brushing very good silicate Inv. Example 1731 10.6 1:2 1.17 45 alkali 15 Spraying very good silicate Inv. Example 1732 8.4  1:221 0.10 48 alkyl 24 Spraying very good silicate (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 100 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg Average Intermetallic Fracture Mean Value of Compounds on Mg Facet &/or Size Aspect Al Si Surface of MgZn₂ or (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ Inv. Example 1733 23.7 FC 6.81 1.08 10.6 1.8 Existence No Inv. Example 1734 24.2 FC 5.25 1.14 9.5 0 Existence Existence Inv. Example 1735 0.2 FC 194.23 1.23 11.04 0.7 Existence Existence Inv. Example 1736 27.1 FC 28.74 1.33 0.01 1.8 Existence Existence Inv. Example 1737 29.3 FC 13.57 1.37 0.07 0.7 Existence Existence Inv. Example 1738 0.5 FC 0.65 1.44 1.8 1.5 Existence Existence Inv. Example 1739 2.7 FC 4.12 1.21 0 1.3 Existence Existence Inv. Example 1740 28.4 FC 0.72 1.22 2.9 1.8 Existence Existence Inv. Example 1741 8.7 FC 117.54 1.23 10.5 0.9 Existence Existence Inv. Example 1742 9.2 FC 7.81 1.47 2.9 0.7 Existence Existence Inv. Example 1743 17.8 FC 80.25 1.01 16.8 1.8 Existence No Inv. Example 1744 20.2 FC 8.47 1.04 2.7 0.7 Existence Existence Inv. Example 1745 0.4 FC 0.87 1.05 0.04 0.7 Existence Existence Inv. Example 1746 13.7 FC 25.78 1.12 0 0.04 Existence Existence Inv. Example 1747 14.7 FC 93.45 1.11 1.24 0.05 Existence Existence Inv. Example 1748 2.4 FC 0.97 1.08 0.05 1.24 Existence Existence Inv. Example 1749 4.5 FC 54.89 1.47 1.24 0.06 Existence Existence Inv. Example 1750 0.1 FC 10.81 1.50 1.24 0.07 Existence Existence Inv. Example 1751 30.0 FC 18.24 1.13 0 0.75 Existence Existence Inv. Example 1752 24.5 FC 114.78 1.04 0.9 1.5 Existence Existence Inv. Example 1753 27.6 FC 3.87 1.02 0.03 1.3 Existence Existence Inv. Example 1754 4.1 FC 11.94 1.08 10.5 1.8 Existence No Inv. Example 1755 3.2 FC 142.58 1.15 2.9 0.9 Existence Existence Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in Coat Result of particle Metal Particle Dry Coat Thickness Coating Corrosion (μm) Particle) (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 1733 5.3  1:31 0.74 68 alkali 34 Spraying very good silicate Inv. Example 1734 20.34 1:4 4.84 35 alkyl 20 Brushing very good silicate Inv. Example 1735 7.8 1:1 0.10 37 alkali 200 Brushing very good silicate Inv. Example 1736 10.5 1:7 3.39 38 alkyl 56 Brushing very good silicate Inv. Example 1737 20.34 400:1  29.23 41 alkali 34 Spraying very good silicate Inv. Example 1738 7.9 1:2 0.17 54 alkyl 2 Spraying very good silicate Inv. Example 1739 11.6  1:300 0.01 57 alkali 15 Spraying very good silicate Inv. Example 1740 16.9 1:4 5.68 59 alkali 10 Spraying very good silicate Inv. Example 1741 10.5 1:5 1.45 64 alkyl 125 Brushing very good silicate Inv. Example 1742 8.9  1:10 0.84 66 alkali 24 Brushing very good silicate Inv. Example 1743 7.5 1:9 1.78 67 alkyl 110 Brushing very good silicate Inv. Example 1744 10.9 1:1 10.10 34 alkali 24 Brushing very good silicate Inv. Example 1745 20.34 130:1  0.40 54 alkyl 2 Spraying very good silicate Inv. Example 1746 6.7 130:1  13.60 62 alkali 37 Spraying very good silicate Inv. Example 1747 7.9  1:31 0.46 66 alkyl 113 Brushing very good silicate Inv. Example 1748 5.6 1:1 1.20 67 alkali 2 Spraying very good silicate Inv. Example 1749 20.34 2:1 3.00 68 alkyl 75 Brushing very good silicate Inv. Example 1750 9.9 300:1  0.10 33 alkali 30 Brushing very good silicate Inv. Example 1751 10.5  1:270 0.11 35 alkyl 34 Brushing very good silicate Inv. Example 1752 7.6  1:115 0.21 43 epoxy-based 124 Brushing very good resin Inv. Example 1753 45.33  1:29 0.92 44 acryl-based 15 Spraying very good resin Inv. Example 1754 43.22 1:3 1.03 43 urethane- 23 Spraying very good based resin Inv. Example 1755 10.6 1:9 0.32 44 polyester 157 Brushing very good resin (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 101 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg Average Intermetallic Fracture Mean value of Compounds on Mg Facet &/or Size Aspect Al Si Surface of MgZn₂ or (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ Inv. Example 1756 2.7 FC 12.5 1.34 16.8 0.7 Existence Existence Inv. Example 1757 0.12 FC 31.24 1.25 2.7 1.8 Existence Existence Inv. Example 1758 0.22 FC 152.46 1.19 0.02 0.7 Existence Existence Inv. Example 1759 0.37 FC 13.4 1.18 0 1.5 Existence Existence Inv. Example 1760 1.4 FC 160.57 1.24 7.42 1.3 Existence Existence Inv. Example 1761 4.2 FC 14.1 1.11 0.02 1.8 Existence Existence Inv. Example 1762 4.8 FC 167.55 1.27 0.04 0.9 Existence Existence Inv. Example 1763 8.1 FC 1.45 1.31 17.5 0 Existence Existence Inv. Example 1764 7.6 FC 0.15 1.26 0.01 1.8 Existence Existence Inv. Example 1765 9.9 FC 13.1 1.14 0.02 0.7 Existence Existence Inv. Example 1766 14.8 FC 15.5 1.34 3.8 0 Existence Existence Inv. Example 1767 16.7 FC 0.67 1.16 2.9 0 Existence Existence Inv. Example 1768 17.9 FC 137.89 1.47 10.5 1.8 Existence Existence Inv. Example 1769 19.5 FC 16.3 1.48 2.9 0.9 Existence Existence Inv. Example 1770 22.4 FC 110.38 1.49 16.8 0.7 Existence Existence Inv. Example 1771 0.17 FC 12.4 1.34 2.7 1.8 Existence Existence Inv. Example 1772 8.3 FC 17.2 1.29 0.02 0.7 Existence No Inv. Example 1773 6.5 FC 105.23 1.18 0.02 0.7 Existence Existence Inv. Example 1774 9.7 FC 177.89 1.23 0.04 0.02 Existence Existence Inv. Example 1775 11.4 FC 12.2 1.27 0.05 0.02 Existence Existence Inv. Example 1776 22.5 FC 1.84 1.17 1.24 1.37 Existence Existence Inv. Example 1777 25.7 FC 16.02 1.16 0.05 0.02 Existence Existence Inv. Example 1778 17.8 FC 1.75 1.49 1.24 1.37 Existence Existence Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in Coat Result of particle Metal Particle Dry Coat Thickness Coating Corrosion (μm) Particle) (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 1756 20.34 1:5 0.45 54 epoxy-based 26 Spraying very good resin Inv. Example 1757 5.3 100:1  0.12 79 acryl-based 38 Spraying very good resin Inv. Example 1758 10.9 1:1 0.11 73 urethane- 160 Brushing very good based resin Inv. Example 1759 7.8 99:1  0.37 69 polyester 27 Brushing very good resin Inv. Example 1760 10.5 1:6 0.20 63 epoxy-based 180 Brushing very good resin Inv. Example 1761 20.34  1:12 0.32 35 acryl-based 26 Spraying very good resin Inv. Example 1762 7.9 1:5 0.80 35 urethane- 180 Brushing very good based resin Inv. Example 1763 11.6  1:33 0.24 66 polyester 15 Spraying very good resin Inv. Example 1764 16.9 1:9 0.76 67 epoxy-based 2 Spraying very good resin Inv. Example 1765 10.5  1:18 0.52 68 acryl-based 28 Spraying very good resin Inv. Example 1766 8.9  1:38 0.38 33 urethane- 30 Spraying very good based resin Inv. Example 1767 7.5  1:117 0.14 35 polyester 2 Spraying very good resin Inv. Example 1768 20.34  1:42 0.42 43 epoxy-based 157 Brushing very good resin Inv. Example 1769 9.8 1:1 9.75 44 acryl-based 28 Brushing very good resin Inv. Example 1770 6.7  1:121 0.18 42 urethane- 130 Brushing very good based resin Inv. Example 1771 45.33 120:1  0.17 33 polyester 29 Brushing very good resin Inv. Example 1772 43.22  1:145 0.06 30 epoxy-based 30 Brushing very good resin Inv. Example 1773 11.5  1:31 0.20 35 acryl-based 120 Brushing very good resin Inv. Example 1774 9.9  1:95 0.10 37 urethane- 187 Brushing very good based resin Inv. Example 1775 10.5  1:33 0.34 77 polyester 28 Spraying very good resin Inv. Example 1776 7.6 120:1  22.31 41 epoxy-based 5 Spraying very good resin Inv. Example 1777 8.2  1:28 0.89 35 acryl-based 35 Spraying very good resin Inv. Example 1778 9.1  1:33 0.52 58 urethane- 5 Spraying very good based resin (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 102 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg Average Intermetallic Fracture Mean Value of Compounds on Mg Facet &/or Size Aspect Al Si Surface of MgZn₂ or (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ Inv. Example 1779 0.14 FC 198.78 1.34 1.24 1.37 Existence Existence Inv. Example 1780 6.7 FC 13.1 1.16 0.8 1.5 Existence Existence Inv. Example 1781 7.5 FC 15.5 1.47 0.9 1.3 Existence Existence Inv. Example 1782 8.4 FC 0.67 1.48 1.1 1.8 Existence No Inv. Example 1783 9.3 FC 12.2 1.49 1.8 0.9 Existence Existence Inv. Example 1784 1.4 FC 1.84 1.34 3.8 0.7 Existence Existence Inv. Example 1785 4.2 FC 16.02 1.29 2.9 1.8 Existence Existence Inv. Example 1786 4.8 FC 1.75 1.18 10.5 0.7 Existence Existence Inv. Example 1787 8.1 FC 12.4 1.23 2.9 1.5 Existence Existence Inv. Example 1788 7.6 FC 17.2 1.27 16.8 1.3 Existence Existence Inv. Example 1789 9.9 FC 13.1 1.17 2.7 1.8 Existence Existence Inv. Example 1790 0.4 FC 29.9 1.16 3.6 0.9 Existence Existence Inv. Example 1791 10.5 FC 0.21 1.27 0 0.7 Existence Existence Inv. Example 1792 0.4 FC 0.22 1.17 0.06 1.8 Existence Existence Inv. Example 1793 10.5 FC 29.5 1.27 0.02 0.7 Existence Existence Inv. Example 1794 0.51 FC 29.9 1.18 1.6 1.5 Existence Existence Inv. Example 1795 9.8 FC 0.21 1.23 3.5 0 Existence Existence Inv. Example 1796 0.52 FC 0.22 1.27 9.8 1.8 Existence Existence Inv. Example 1797 9.9 FC 29.5 1.17 11.5 0.9 Existence No Inv. Example 1798 14.8 FC 16.02 1.48 0.4 0.7 Existence Existence Inv. Example 1799 19.9 FC 1.75 1.49 0.6 1.8 Existence Existence Inv. Example 1800 17.9 FC 12.4 1.34 10.6 0.7 Existence Existence Inv. Example 1801 19.5 FC 17.2 1.29 9.5 0.7 Existence Existence Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in Coat Result of particle Metal Particle Dry Coat Thickness Coating Corrosion (μm) Particle) (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 1779 10.6 200:1  0.14 37 polyester 200 Brushing very good resin Inv. Example 1780 8.4 1:4 1.34 68 alkali 25 Spraying very good silicate Inv. Example 1781 5.3  1:18 0.39 55 alkali 15 Spraying very good silicate Inv. Example 1782 10.9 1:7 1.05 77 alkyl 20 Spraying very good silicate Inv. Example 1783 7.8  1:11 0.78 43 alkali 18 Spraying very good silicate Inv. Example 1784 8.9 1:2 0.47 45 alkyl 22 Spraying very good silicate Inv. Example 1785 7.5 1:7 0.53 66 alkali 19 Spraying very good silicate Inv. Example 1786 10.9 1:2 2.40 33 alkyl 29 Spraying very good silicate Inv. Example 1787 9.8 1:5 1.35 66 alkali 23 Spraying very good silicate Inv. Example 1788 45.33  1:10 0.69 55 alkyl 21 Spraying very good silicate Inv. Example 1789 43.22 1:9 0.99 49 alkali 19 Spraying very good silicate Inv. Example 1790 5.6 240:1  0.40 77 alkyl 15 Spraying very good silicate Inv. Example 1791 11.5 120:1  10.41 41 alkali 18 Spraying very good silicate Inv. Example 1792 9.9 99:1  0.40 64 alkyl 22 Spraying very good silicate Inv. Example 1793 10.5  1:99 0.11 58 alkyl 21 Spraying very good silicate Inv. Example 1794 7.6 1:3 0.13 33 alkyl 29 Spraying very good silicate Inv. Example 1795 8.2 1:6 1.40 66 alkali 23 Spraying very good silicate Inv. Example 1796 9.1 1:1 0.26 55 alkyl 21 Spraying very good silicate Inv. Example 1797 10.6 1:7 1.24 49 alkali 19 Spraying very good silicate Inv. Example 1798 8.4 1:5 2.47 77 alkyl 21 Spraying very good silicate Inv. Example 1799 5.3  1:150 0.13 43 alkali 19 Spraying very good silicate Inv. Example 1800 10.9  1:55 0.32 45 alkyl 15 Spraying very good silicate Inv. Example 1801 7.8  1:121 0.16 66 alkali 18 Spraying very good silicate (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 103 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg Average Intermetallic Fracture Mean Value of Compounds on Mg Facet &/or Size Aspect Al Si Surface of MgZn₂ or (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ Comp. Example 117 2.3 FC 205.6 1.23 12.5 0.05 Existence No Comp. Example 118 12.5 FC 0.005 1.36 2.1 0 Existence Existence Comp. Example 119 18.9 FC 205.6 1.11 1.5 0.05 Existence Existence Comp. Example 120 29.5 FC 0.005 1.07 0.05 2.29 Existence Existence Comp. Example 121 14.5 FC 205.6 1.42 0 0 Existence Existence Comp. Example 122 12.5 FC 0.005 1.38 0 0 Existence No Comp. Example 123 18.9 FC 205.6 1.22 0.07 0 Existence Existence Comp. Example 124 29.5 FC 0.005 1.14 0 0.07 Existence No Comp. Example 125 2.3 FC 10.6 1.13 0 0.02 Existence Existence Comp. Example 126 12.5 FC 5.7 1.02 22.1 0 Existence Existence Comp. Example 127 0.5 FC 6.4 1.06 25.8 0.05 Existence No Comp. Example 128 29.5 FC 3.2 1.23 22.1 0 Existence Existence Comp. Example 129 14.5 FC 4.5 1.36 21.5 0.05 Existence Existence Comp. Example 130 9.8 FC 5.2 1.11 0.05 2.29 No No Comp. Example 131 4.6 NO 1.9 1.07 0 0 Existence Existence Comp. Example 132 3.2 FC 18.5 1.42 0 0 Existence No Comp. Example 133 29.9 FC 12.5 1.38 0.07 0 Existence Existence Comp. Example 134 7.6 NO 9.8 1.22 0 0.07 Existence Existence Comp. Example 135 29.9 FC 7.6 1.14 0 0.007 Existence Existence Comp. Example 136 0.6 FC 6.9 1.13 36.5 3.25 Existence Existence Comp. Example 137 4.5 FC 10.5 1.02 0.005 0 Existence Existence Comp. Example 138 3.7 FC 12.6 1.06 22.1 0 Existence Existence Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in Coat Result of particle Metal Particle Dry Coat Thickness Coating Corrosion (μm) Particle) (mass %) (mass %) Base Resin (μm) Method Test Comp. Example 117 10.5 1:5 0.38 77 alkyl 25 Spraying poor silicate Comp. Example 118 12.6 1:3 3.13 77 urethane- 25 Spraying poor based resin Comp. Example 119 7.8 1:19 0.95 43 alkyl 105 Brushing poor silicate Comp. Example 120 16.8 1:100 0.29 52 alkali 165 Spraying poor silicate Comp. Example 121 10.5 1:260 0.06 66 alkyl 25 Spraying poor silicate Comp. Example 122 12.6 1:3 3.13 72 alkyl 25 Spraying poor silicate Comp. Example 123 7.8 1:19 0.95 40 alkyl 105 Brushing poor silicate Comp. Example 124 16.8 1:100 0.29 36 alkali 165 Spraying poor silicate Comp. Example 125 10.5 1:256 0.01 32 alkyl 25 Spraying poor silicate Comp. Example 126 12.6 1:200 0.06 53 alkyl 25 Spraying poor silicate Comp. Example 127 7.8 1:167 0.00 67 alkyl 105 Brushing poor silicate Comp. Example 128 16.8 1:300 0.10 53 urethane- 165 Spraying poor based resin Comp. Example 129 10.5 1:260 0.06 67 alkyl 25 Spraying poor silicate Comp. Example 130 12.6 1:100 0.10 72 alkyl 25 Spraying poor silicate Comp. Example 131 7.8 1:47 0.10 77 alkyl 105 Brushing poor silicate Comp. Example 132 16.8 1:32 0.10 34 urethane- 55 Spraying poor based resin Comp. Example 133 12.6 1:345 0.09 43 alkyl 28 Spraying poor silicate Comp. Example 134 7.8 1:390 0.02 52 alkyl 15 Spraying poor silicate Comp. Example 135 16.8 1:301 0.10 66 alkyl 14 Spraying poor silicate Comp. Example 136 10.5 1:333 0.00 72 urethane- 118 Brushing poor based resin Comp. Example 137 12.6 1:325 0.01 40 alkyl 22 Spraying poor silicate Comp. Example 138 7.8 1:456 0.01 36 alkyl 54 Spraying poor silicate (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 104 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg MgZn₂, Average Intermetallic Mg₂Zn₁₁, Fracture Mean Value of Compounds on Mg₂Zn₃, Mg Facet &/or Size Aspect Al Si Surface of MgZn, or (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₇Zn₃ Inv. Example 2576 7.5 FC 5.07 1.42 0 0 Existence Existence Inv. Example 2577 8.06 FC 7.72 1.38 0 0 Existence Existence Inv. Example 2578 9.3 FC 8.32 1.22 0 0 Existence No Inv. Example 2579 3.5 FC 3.04 1.02 0 0 Existence Existence Inv. Example 2580 2.7 FC 4.12 1.21 0 0 Existence No Inv. Example 2581 9.2 FC 7.81 1.47 0 0 Existence Existence Inv. Example 2582 8.1 FC 1.45 1.31 0 0 Existence No Inv. Example 2583 7.5 FC 9.6 1.07 0 0 Existence Existence Inv. Example 2584 4.5 FC 8.5 1.42 0 0 Existence No Inv. Example 2585 3.6 FC 3.2 1.05 0 0 Existence No Inv. Example 2586 4.2 FC 5.7 1.02 1.5 0 Existence Existence Inv. Example 2587 4.3 FC 6.4 1.06 5.5 1.6 Existence No Inv. Example 2588 4 FC 3.2 1.05 0 0 Existence Existence Inv. Example 2589 6.4 FC 5.2 1.33 0 0 Existence Existence Inv. Example 2590 9.8 FC 5.2 1.33 0 0 Existence No Inv. Example 2591 7.5 FC 5.07 1.42 0 0 Existence No Inv. Example 2592 8.4 FC 7.72 1.38 0.5 0 Existence Existence Inv. Example 2593 2.7 FC 4.12 1.21 0 0 Existence No Inv. Example 2594 2.64 FC 5.5 1.22 0 0 Existence No Inv. Example 2595 1.59 FC 6.7 1.14 0 0 Existence Existence Inv. Example 2596 2.58 FC 8.9 1.13 0 0 Existence Existence Inv. Example 2597 7.55 FC 2.15 1.14 0 0 Existence Existence Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in Coat Result of particle Metal Particle Dry Coat Thickness Coating Corrosion (μm) Particle) (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 2576 23.43 0.71 10.5 74 alkali 24 Brushing very good silicate Inv. Example 2577 5.96 0.64 12.5 82 alkyl 25 Spraying very good silicate Inv. Example 2578 10.64 6.20 1.5 37 alkali 14 Spraying very good silicate Inv. Example 2579 16.5 3.89 0.9 48 alkali 15 Spraying very good silicate Inv. Example 2580 7.95 0.26 10.5 32 alkali 15 Spraying very good silicate Inv. Example 2581 7.95 0.03 299.5 45 alkyl 15 Brushing very good silicate Inv. Example 2582 9.64 16.20 0.5 37 epoxy-based 5 Spraying good resin Inv. Example 2583 0.96 28.85 0.26 72 urethane- 150 Spraying very good based resin Inv. Example 2584 5.26 15.00 0.3 40 alkali 18 Spraying very good silicate Inv. Example 2585 13.5 1.20 3 40 alkali 18 Spraying very good silicate Inv. Example 2586 13.5 0.20 20.5 72 alkyl 58 Spraying very good silicate Inv. Example 2587 9.64 1.02 4.2 40 alkyl 21 Spraying very good silicate Inv. Example 2588 16.5 2.67 1.5 36 alkali 19 Brushing very good silicate Inv. Example 2589 20.59 1.28 5 53 alkyl 77 Spraying very good silicate Inv. Example 2590 0.96 0.63 15.6 53 alkyl 77 Spraying very good silicate Inv. Example 2591 6.54 15.00 0.5 66 alkali 13 Brushing very good silicate Inv. Example 2592 5.26 4.42 1.9 67 alkyl 22 Brushing very good silicate Inv. Example 2593 10.64 1.69 1.6 57 alkali 15 Spraying very good silicate Inv. Example 2594 9.64 1.06 2.5 43 alkyl 16 Spraying very good silicate Inv. Example 2595 6.9 3.18 0.5 76 alkyl 5 Spraying very good silicate Inv. Example 2596 10.5 0.52 5 49 alkyl 22 Spraying very good silicate Inv. Example 2597 13.5 6.29 1.2 75 alkyl 18 Spraying very good silicate (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 105 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg MgZn₂, Average Intermetallic Mg₂Zn₁₁, Fracture Mean Value of Compounds on Mg₂Zn₃, Mg Facet &/or Size Aspect Al Si Surface of MgZn, or (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₇Zn₃ Inv. Example 2598 8.01 FC 2.54 1.13 0 0 Existence No Inv. Example 2599 1.06 FC 3.4 1.38 0 0 Existence Existence Inv. Example 2600 2.64 FC 5.5 1.22 0 0 Existence Existence Inv. Example 2601 1.59 FC 6.7 1.14 0 0 Existence Existence Inv. Example 2602 20.5 FC 2.15 1.14 1.5 0 Existence No Inv. Example 2603 18.5 FC 2.54 1.13 5.5 1.6 Existence Existence Inv. Example 2604 9.51 FC 2.77 1.38 4.5 0 Existence Existence Inv. Example 2605 10.01 FC 3.68 1.22 0 1.6 Existence Existence Inv. Example 2606 3.54 FC 5.5 1.22 0 0 Existence No Inv. Example 2607 4.05 FC 2.06 1.13 0 0 Existence Existence Inv. Example 2608 8.57 FC 4.99 1.02 0 0 Existence Existence Inv. Example 2609 0.02 FC 6.4 1.06 0 0 Existence No Inv. Example 2610 25.5 FC 3.09 1.07 0 0 Existence Existence Inv. Example 2611 2.36 FC 3.99 1.22 0 0 Existence No Inv. Example 2612 0.05 FC 7.72 1.38 0 0 Existence Existence Inv. Example 2613 0.04 FC 8.32 1.22 0 0 Existence No Inv. Example 2614 5.22 FC 3.55 1.12 0 0 Existence Existence Inv. Example 2615 4.01 FC 2.64 1.23 0 0 Existence Existence Inv. Example 2616 0.05 FC 5.2 1.33 0 0 Existence Existence Inv. Example 2617 10.5 FC 1.9 1.27 0 0 Existence Existence Inv. Example 2618 0.05 FC 2.5 1.05 0 1.2 Existence No Inv. Example 2619 10.5 FC 0.09 1.12 0 0.6 Existence No Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in Coat Result of particle Metal Particle Dry Coat Thickness Coating Corrosion (μm) Particle) (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 2598 20.59 0.94 8.5 73 alkyl 16 Spraying very good silicate Inv. Example 2599 7.82 0.50 2.1 49 alkyl 8 Spraying very good silicate Inv. Example 2600 5.26 10.56 0.25 43 alkyl 16 Spraying very good silicate Inv. Example 2601 7.06 1.59 1 76 alkyl 5 Spraying very good silicate Inv. Example 2602 0.64 8.20 2.5 75 alkyl 18 Spraying very good silicate Inv. Example 2603 46.8 3.70 5 73 alkyl 16 Spraying very good silicate Inv. Example 2604 16.5 1.73 5.5 55 alkyl 5 Spraying very good silicate Inv. Example 2605 13.5 1.54 6.5 48 alkyl 22 Spraying very good silicate Inv. Example 2606 0.96 2.36 1.5 78 alkyl 18 Spraying very good silicate Inv. Example 2607 0.96 0.81 5 52 alkyl 8 Spraying very good silicate Inv. Example 2608 8.45 1.53 5.6 61 alkyl 16 Spraying very good silicate Inv. Example 2609 2.9 0.20 0.05 77 polyester 47 Spraying very good resin Inv. Example 2610 5.4 2.43 10.5 49 alkyl 22 Spraying very good silicate Inv. Example 2611 10.6 4.72 0.5 80 alkyl 21 Spraying very good silicate Inv. Example 2612 2.32 0.07 0.75 36 alkyl 19 Brushing very good silicate Inv. Example 2613 7.8 0.20 0.2 32 alkyl 24 Spraying very good silicate Inv. Example 2614 7.95 0.50 10.5 55 alkyl 19 Spraying very good silicate Inv. Example 2615 20.59 10.03 0.4 40 alkyl 8 Spraying very good silicate Inv. Example 2616 22.5 0.06 0.9 53 urethane- 20 Brushing very good based resin Inv. Example 2617 4.6 0.08 3.5 60 polyester 200 Brushing very good resin Inv. Example 2618 4.9 5.00 0.01 38 alkali 19 Spraying very good silicate Inv. Example 2619 10.5 0.08 3.5 49 alkyl 11 Spraying very good silicate (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 106 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg MgZn₂, Average Intermetallic Mg₂Zn₁₁, Fracture Mean Value of Compounds on Mg₂Zn₃, Mg Facet &/or Size Aspect Al Si Surface of MgZn, or (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₇Zn₃ Inv. Example 2620 2.64 FC 5.5 1.22 0 0.01 Existence No Inv. Example 2621 0.08 FC 5.6 1.36 1.5 0 Existence Existence Inv. Example 2622 0.09 FC 11.5 1.11 5.5 1.6 Existence No Inv. Example 2623 0.05 FC 19.5 1.07 4.5 0 Existence Existence Inv. Example 2624 1.59 FC 6.7 1.14 0 0.1 Existence Existence Inv. Example 2625 2.58 FC 8.9 1.13 0.01 0 Existence Existence Inv. Example 2626 9.8 FC 8.32 1.22 3.2 0.9 Existence Existence Inv. Example 2627 0.18 FC 10.05 1.14 0 0.5 Existence Existence Inv. Example 2628 7.55 FC 2.15 1.14 0.2 0.1 Existence Existence Inv. Example 2629 0.01 FC 0.06 1.23 1.2 0.6 Existence No Inv. Example 2630 12.5 FC 2.54 1.13 0.5 0 Existence Existence Inv. Example 2631 1.06 FC 3.4 1.38 1.5 0.9 Existence Existence Inv. Example 2632 0.04 FC 8.5 1.42 0 1.2 Existence No Inv. Example 2633 0.06 FC 7.72 1.38 0 0.6 Existence Existence Inv. Example 2634 9.51 FC 2.77 1.38 0 0.01 Existence No Inv. Example 2635 15.5 FC 3.68 1.22 1.5 0 Existence Existence Inv. Example 2636 0.05 FC 10.6 1.13 5.5 1.6 Existence No Inv. Example 2637 8.8 FC 5.7 1.02 4.5 0 Existence No Inv. Example 2638 3.54 FC 5.5 1.22 0 0.1 Existence Existence Inv. Example 2639 10.5 FC 3.2 1.05 0.01 0 Existence Existence Inv. Example 2640 0.07 FC 4.5 1.24 3.2 0.9 Existence Existence Inv. Example 2641 15.5 FC 2.54 1.14 0 0.5 Existence No Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in Coat Result of particle Metal Particle Dry Coat Thickness Coating Corrosion (μm) Particle) (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 2620 8.45 1.32 2 43 alkyl 16 Spraying very good silicate Inv. Example 2621 30.5 2.00 0.04 66 alkyl 16 Brushing very good silicate Inv. Example 2622 49.5 0.09 1 67 alkali 33 Brushing very good silicate Inv. Example 2623 5.9 0.10 0.5 54 alkyl 8 Brushing good silicate Inv. Example 2624 4.52 0.32 5 76 alkyl 5 Spraying very good silicate Inv. Example 2625 5.96 0.26 10 49 alkyl 22 Spraying very good silicate Inv. Example 2626 5.5 0.15 3.5 32 alkyl 23 Spraying very good silicate Inv. Example 2627 3.6 0.20 0.9 53 epoxy-based 30 Spraying very good resin Inv. Example 2628 16.5 2.16 3.5 75 alkyl 18 Spraying very good silicate Inv. Example 2629 12.5 20.00 0.0005 75 alkali 5 Spraying good silicate Inv. Example 2630 16.5 0.06 205.7 73 alkyl 16 Spraying very good silicate Inv. Example 2631 10.9 2.12 0.5 49 alkyl 8 Spraying very good silicate Inv. Example 2632 5.6 0.03 1.2 40 alkali 2 Spraying very good silicate Inv. Example 2633 22.6 3.00 0.02 36 alkyl 18 Spraying very good silicate Inv. Example 2634 20.59 0.88 10.8 55 alkyl 5 Spraying very good silicate Inv. Example 2635 20.59 0.10 152.3 48 alkyl 22 Spraying very good silicate Inv. Example 2636 9.56 0.10 0.5 67 acryl-based 77 Brushing very good resin Inv. Example 2637 5.9 0.12 2.5 72 urethane- 54 Brushing very good based resin Inv. Example 2638 6.54 0.71 5 78 alkyl 18 Spraying very good silicate Inv. Example 2639 21.4 0.20 9 34 epoxy-based 43 Spraying very good resin Inv. Example 2640 9.8 0.70 0.1 43 acryl-based 52 Brushing very good resin Inv. Example 2641 6.59 17.22 0.9 45 alkyl 19 Spraying very good silicate (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 107 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg MgZn₂, Average Intermetallic Mg₂Zn₁₁, Fracture Mean Value of Compounds on Mg₂Zn₃, Mg Facet &/or Size Aspect Al Si Surface of MgZn, or (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₇Zn₃ Inv. Example 2642 4.05 FC 2.06 1.13 0.2 0.1 Existence Existence Inv. Example 2643 8.57 FC 4.99 1.02 1.2 0.6 Existence No Inv. Example 2644 5.8 FC 6.4 1.06 0.5 0 Existence Existence Inv. Example 2645 4.59 FC 3.09 1.07 1.5 0.9 Existence No Inv. Example 2646 9.88 FC 4.66 1.42 0 1.2 Existence No Inv. Example 2647 4.55 FC 4.09 1.38 0 0.6 Existence Existence Inv. Example 2648 2.36 FC 3.99 1.22 0 0.01 Existence No Inv. Example 2649 0.05 FC 7.72 1.38 1.5 0 Existence Existence Inv. Example 2650 0.04 FC 8.32 1.22 5.5 1.6 Existence Existence Inv. Example 2651 2.64 FC 4.55 1.11 4.5 0 Existence No Inv. Example 2652 0.06 FC 10.6 1.13 0 0.1 Existence No Inv. Example 2653 0.18 FC 5.7 1.02 0.01 0 Existence Existence Inv. Example 2654 6.31 FC 3.52 1.27 3.2 0.9 Existence No Inv. Example 2655 5.22 FC 3.55 1.12 0 0.5 Existence No Inv. Example 2656 28.5 FC 2.64 1.23 0.2 0.1 Existence Existence Inv. Example 2657 3.52 FC 3.15 1.36 1.2 0.6 Existence Existence Inv. Example 2658 9.5 FC 5.2 1.33 0.5 0 Existence Existence Inv. Example 2659 0.04 FC 1.9 1.27 1.5 0.9 Existence No Inv. Example 2660 0.06 FC 10.5 1.12 0 1.2 Existence Existence Inv. Example 2661 0.05 FC 12.5 1.23 0 0.6 Existence Existence Inv. Example 2662 5.6 FC 18.5 1.36 0 0.01 Existence Existence Inv. Example 2663 0.01 FC 11.5 1.11 1.5 0 Existence No Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in Coat Result of particle Metal Particle Dry Coat Thickness Coating Corrosion (μm) Particle) (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 2642 6.54 0.40 10.2 52 polyester 8 Spraying very good resin Inv. Example 2643 16.5 0.07 120.5 61 polyester 16 Spraying very good resin Inv. Example 2644 7.8 0.05 2.5 77 alkyl 20 Spraying very good silicate Inv. Example 2645 16.5 0.72 6.4 49 alkyl 22 Spraying very good silicate Inv. Example 2646 6.54 0.48 20.4 79 alkyl 18 Spraying very good silicate Inv. Example 2647 8.45 0.54 8.5 76 alkyl 18 Spraying very good silicate Inv. Example 2648 8.5 2.36 1 80 alkyl 21 Spraying very good silicate Inv. Example 2649 13.6 0.71 0.07 36 alkyl 19 Brushing very good silicate Inv. Example 2650 12.33 0.04 1.1 32 alkyl 24 Spraying very good silicate Inv. Example 2651 16.5 0.59 4.5 43 alkyl 5 Spraying very good silicate Inv. Example 2652 7.9 0.12 0.5 67 alkyl 7 Spraying very good silicate Inv. Example 2653 10.5 0.26 0.7 72 epoxy-based 100 Spraying very good resin Inv. Example 2654 16.5 12.62 0.5 51 alkyl 21 Spraying very good silicate Inv. Example 2655 10.64 2.09 2.5 55 alkyl 19 Spraying very good silicate Inv. Example 2656 10.5 0.93 30.5 40 alkyl 8 Spraying very good silicate Inv. Example 2657 20.59 14.08 0.25 51 alkyl 16 Spraying very good silicate Inv. Example 2658 8.5 5.00 2.4 53 alkyl 20 Brushing very good silicate Inv. Example 2659 0.5 0.01 7.5 60 polyester 200 Brushing very good resin Inv. Example 2660 10.5 0.02 3.5 77 alkyl 25 Spraying very good silicate Inv. Example 2661 11.5 0.01 3.9 43 alkali 14 Spraying very good silicate Inv. Example 2662 36.5 0.09 2.5 52 urethane- 112 Spraying very good based resin Inv. Example 2663 1.5 0.01 0.7 66 alkali 24 Spraying very good silicate (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 108 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg MgZn₂, Average Intermetallic Mg₂Zn₁₁, Fracture Mean Value of Compounds on Mg₂Zn₃, Mg Facet &/or Size Aspect Al Si Surface of MgZn, or (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₇Zn₃ Inv. Example 2664 0.08 FC 9.6 1.07 5.5 1.6 Existence Existence Inv. Example 2665 0.03 FC 8.5 1.42 4.5 0 Existence Existence Inv. Example 2666 4.25 FC 2.36 1.33 0 0.1 Existence Existence Inv. Example 2667 0.04 FC 23.5 1.42 0.01 0 Existence No Inv. Example 2668 0.06 FC 101.5 1.38 3.2 0.9 Existence Existence Inv. Example 2669 0.06 FC 55.4 1.38 0 0.5 Existence Existence Inv. Example 2670 0.07 FC 10.5 1.12 0.2 0.1 Existence No Inv. Example 2671 0.01 FC 12.5 1.23 1.2 0.6 Existence Existence Inv. Example 2672 0.08 FC 18.5 1.36 0.5 0 Existence No Inv. Example 2673 0.09 FC 11.5 1.11 1.5 0.9 Existence Existence Inv. Example 2674 0.05 FC 9.6 1.07 0.5 0 Existence No Inv. Example 2675 0.06 FC 10.05 1.14 1.5 0.9 Existence Existence Inv. Example 2676 29.9 FC 10.5 1.36 0 0 Existence Existence Inv. Example 2677 16.5 FC 7.5 1.11 0.01 0 Existence Existence Inv. Example 2678 12.5 FC 2.6 1.07 3.2 0.9 Existence No Inv. Example 2679 9.8 FC 3.5 1.42 0 0.5 Existence Existence Inv. Example 2680 9.6 FC 4.5 1.33 0.2 0.1 Existence No Inv. Example 2681 7.5 FC 1.6 1.42 0 0.5 Existence Existence Inv. Example 2682 4.6 FC 2.5 1.12 5.8 0.1 Existence Existence Inv. Example 2683 3.8 FC 23.5 1.23 1.2 0.6 Existence Existence Inv. Example 2684 0.05 FC 9.8 1.27 15.5 0 Existence Existence Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in Coat Result of particle Metal Particle Dry Coat Thickness Coating Corrosion (μm) Particle) (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 2664 8.7 0.04 1.9 72 urethane- 150 Spraying very good based resin Inv. Example 2665 7.8 0.01 4.5 40 alkali 18 Spraying very good silicate Inv. Example 2666 5.96 14.17 0.3 44 alkyl 18 Spraying very good silicate Inv. Example 2667 0.06 0.50 0.08 44 alkali 38 Spraying very good silicate Inv. Example 2668 0.9 1.20 0.05 36 alkyl 18 Spraying very good silicate Inv. Example 2669 3.6 12.00 0.005 76 alkyl 10 Spraying very good silicate Inv. Example 2670 10.5 0.03 2.8 77 alkyl 37 Spraying very good silicate Inv. Example 2671 0.05 0.02 0.6 43 alkali 2 Spraying good silicate Inv. Example 2672 2.32 0.08 1 52 alkyl 160 Brushing very good silicate Inv. Example 2673 20.4 1.00 0.09 66 alkali 5 Brushing very good silicate Inv. Example 2674 7.34 0.01 3.4 72 alkyl 56 Brushing very good silicate Inv. Example 2675 9.4 0.04 1.5 53 urethane- 99 Spraying very good based resin Inv. Example 2676 16.5 0.15 200 55 urethane- 700 Spraying very good based resin Inv. Example 2677 7.9 1.10 15 47 alkyl 554 Spraying very good silicate Inv. Example 2678 10.5 2.50 5 79 urethane- 688 Brushing very good based resin Inv. Example 2679 16.5 6.53 1.5 42 urethane- 421 Spraying very good based resin Inv. Example 2680 8.5 0.12 78 36 urethane- 651 Spraying very good based resin Inv. Example 2681 10.5 1.50 5 53 urethane- 402 Brushing very good based resin Inv. Example 2682 5.8 0.44 10.5 55 alkali 354 Spraying very good silicate Inv. Example 2683 1.2 1.52 2.5 42 urethane- 504 Brushing very good based resin Inv. Example 2684 15.5 0.05 1 76 urethane- 666 Spraying very good based resin (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

Example 8

Zn alloy particles with the chemical ingredients shown in Tables 109 to 125 were produced in the same way as in Example 5. The rest is the same as Example 5.

MgZn₂, Mg₂Zn₁₁, Mg₂Zn₃, MgZn, and Mg₇Zn₃ were identified by analysis of the ratio of composition of the Mg and Zn at the physical fracture facets or crack surfaces by the X-ray diffraction method or by observation by a scanning electron microscopy with an energy dispersion type X-ray analyzer.

The number of facets of the Zn alloy particles was identified by observation of 50 to 100 randomly extracted particles using a scan type electron microscope.

From Tables 109 to 125, it is learned that due to the surfaces of the particles including fractured parts and/or cracks having as intermetallic compounds one or more types of compounds of MgZn₂, Mg₂Zn₁₁, Mg₂Zn₃, MgZn, and Mg₇Zn₃ or due to the number of facets being two facets or more, the painting test pieces using the Zn alloy particles and Zn metal particles of the present invention are improved in corrosion resistance and rust protection regardless of the type of base resin, that is, both for inorganic-based and organic-based binders.

TABLE 109 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg Average Intermetallic Fracture Mean Value of Compounds on Mg Facet &/or Size Aspect Al Si Surface of MgZn₂ or # of (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ facets Inv. Example 329 17.3 F 29.24 1.37 11.4 0.24 Existence No 6 Inv. Example 330 18.5 F 1.28 1.10 0.04 0.03 Existence No 7 Inv. Example 331 19.3 F 33.57 1.04 0.25 0.07 Existence No 7 Inv. Example 332 3.5 F 3.04 1.02 5.43 0.65 Existence No 6 Inv. Example 333 22.5 F 7.54 1.01 17.5 2.41 Existence No 6 Inv. Example 334 23.7 F 68.12 1.08 0.01 0.08 Existence No 6 Inv. Example 335 24.2 F 0.52 1.14 0.02 2.23 Existence No 6 Inv. Example 336 0.2 F 0.12 1.23 0.02 0.06 Existence No 7 Inv. Example 337 27.1 F 58.74 1.33 0.04 0.02 Existence No 6 Inv. Example 338 29.3 F 13.57 1.37 0.05 0.02 Existence No 7 Inv. Example 339 0.5 F 6.4 1.44 1.24 1.37 Existence No 7 Inv. Example 340 2.7 F 41.23 1.21 27.5 2.43 Existence No 6 Inv. Example 341 28.4 F 0.72 1.22 0.01 0.02 Existence No 7 Inv. Example 342 8.7 F 1.18 1.23 0.01 0.01 Existence No 6 Inv. Example 343 9.2 F 7.12 1.47 0.02 0.05 Existence No 7 Inv. Example 344 17.8 F 8.01 1.01 0.03 0.04 Existence No 6 Inv. Example 345 20.2 F 0.84 1.04 7.78 0.24 Existence No 7 Inv. Example 346 0.4 F 87.65 1.05 0.04 0.06 Existence No 6 Inv. Example 347 13.7 F 2.59 1.12 11.21 0.74 Existence No 6 Inv. Example 348 14.7 F 93.45 1.11 0.09 0.01 Existence No 7 Inv. Example 349 2.4 F 9.84 1.08 5.41 1.27 Existence No 6 Inv. Example 350 4.5 F 5.45 1.47 0.02 0.03 Existence No 6 Inv. Example 351 0.1 F 1.08 1.50 0.02 0.07 Existence No 6 Inv. Example 352 30.0 F 180.24 1.13 0.03 0.08 Existence Existence 7 Inv. Example 353 24.5 F 11.4 1.04 11.04 0.21 Existence Existence 6 Inv. Example 354 27.6 F 38.75 1.02 0.01 0.02 Existence Existence 6 Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in Coat Result of particle Metal Particle Dry Coat Thickness Coating Corrosion (μm) Particle) (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 329 18.54 70:1 17.06 52 alkali 30 Spraying very good silicate Inv. Example 330 5.42 300:1  18.44 34 alkyl 15 Spraying very good silicate Inv. Example 331 7.54 100:1  19.11 43 alkali 42 Brushing very good silicate Inv. Example 332 2.04 250:1  3.49 53 alkyl 5 Brushing very good silicate Inv. Example 333 8.54 50:1 22.06 60 alkali 12 Brushing very good silicate Inv. Example 334 38.54 30:1 22.94 68 alkyl 75 Brushing very good silicate Inv. Example 335 2.05 20:1 23.05 61 alkali 2 Spraying very good silicate Inv. Example 336 6.04 65:1 0.20 59 alkyl 10 Spraying very good silicate Inv. Example 337 27.85 300:1  27.01 39 alkali 75 Brushing very good silicate Inv. Example 338 5.44 150:1  29.11 42 alkyl 20 Spraying very good silicate Inv. Example 339 7.55 70:1 0.49 48 alkali 18 Spraying very good silicate Inv. Example 340 31.47 65:1 2.66 44 alkyl 52 Brushing very good silicate Inv. Example 341 3.24 65:1 27.97 72 alkali 5 Spraying very good silicate Inv. Example 342 6.54 160:1  8.65 40 alkyl 13 Spraying very good silicate Inv. Example 343 13.45 100:1  9.11 36 alkali 24 Spraying very good silicate Inv. Example 344 5.64 50:1 17.45 32 alkyl 19 Spraying very good silicate Inv. Example 345 3.48 85:1 19.97 53 alkali 6 Spraying very good silicate Inv. Example 346 35.47 70:1 0.39 67 alkyl 95 Brushing very good silicate Inv. Example 347 7.44  1:99 0.14 72 alkali 15 Brushing very good silicate Inv. Example 348 6.21  1:60 0.24 73 alkyl 100 Brushing very good silicate Inv. Example 349 3.33  1:15 0.15 54 alkali 20 Brushing very good silicate Inv. Example 350 4.56 90:1 4.45 62 alkyl 18 Spraying very good silicate Inv. Example 351 4.57 120:1  0.10 68 alkali 13 Spraying very good silicate Inv. Example 352 33.47 100:1  29.70 35 alkyl 11 Spraying very good silicate Inv. Example 353 7.41  1:99 0.25 37 alkali 23 Spraying very good silicate Inv. Example 354 12.54  1:60 0.45 38 alkyl 45 Brushing very good silicate (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 110 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg Average Intermetallic Fracture Mean Value of Compounds on Mg Facet &/or Size Aspect Al Si Surface of MgZn₂ or # of (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ facets Inv. Example 355 4.1 F 119.87 1.08 0.07 0.04 Existence Existence 6 Inv. Example 356 3.2 F 1.42 1.15 0.08 0.01 Existence Existence 7 Inv. Example 357 2.7 F 12.5 1.34 0.04 0.03 Existence Existence 6 Inv. Example 358 0.12 F 31.24 1.25 0.02 0.04 Existence Existence 6 Inv. Example 359 0.22 F 152.46 1.19 0.02 0.02 Existence Existence 6 Inv. Example 360 0.37 F 13.4 1.18 4.12 0.61 Existence Existence 6 Inv. Example 361 1.4 F 1.61 1.24 0.05 0.02 Existence Existence 6 Inv. Example 362 4.2 F 14.1 1.11 2.14 0.74 Existence Existence 7 Inv. Example 363 4.8 F 1.67 1.27 0.03 0.02 Existence Existence 6 Inv. Example 364 8.1 F 1.45 1.31 0.03 0.04 Existence Existence 6 Inv. Example 365 7.6 F 14.8 1.26 0.04 0.05 Existence Existence 7 Inv. Example 366 9.9 F 1.31 1.14 7.54 1.24 Existence Existence 6 Inv. Example 367 14.8 F 15.5 1.34 0.08 0.06 Existence Existence 6 Inv. Example 368 16.7 F 0.67 1.16 0.01 0.07 Existence Existence 6 Inv. Example 369 17.9 F 137.89 1.47 29.8 0.75 Existence Existence 7 Inv. Example 370 19.5 F 1.63 1.48 0.01 0.02 Existence Existence 6 Inv. Example 371 22.4 F 1.12 1.49 0.03 0.01 Existence Existence 7 Inv. Example 372 0.17 F 169.88 1.34 0.02 0.01 Existence Existence 6 Inv. Example 373 8.3 F 1.72 1.29 8.04 1.24 Existence Existence 6 Inv. Example 374 6.5 F 10.5 1.18 0.06 0.04 Existence Existence 6 Inv. Example 375 9.7 F 17.7 1.23 0.08 0.02 Existence Existence 6 Inv. Example 376 11.4 F 122.54 1.27 0.03 0.01 Existence Existence 6 Inv. Example 377 22.5 F 1.84 1.17 0.04 0.03 Existence Existence 6 Inv. Example 378 25.7 F 19.1 1.16 7.42 1.22 Existence Existence 7 Inv. Example 379 17.8 F 1.75 1.49 0.02 0.01 Existence Existence 6 Inv. Example 380 0.14 F 198.78 1.34 0.08 0.02 Existence Existence 6 Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in Coat Result of particle Metal Particle Dry Coat Thickness Coating Corrosion (μm) Particle) (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 355 2.37   1:15 0.26 35 alkali 130 Brushing very good silicate Inv. Example 356 6.65  90:1 3.16 37 alkyl 17 Brushing very good silicate Inv. Example 357 8.14 120:1 2.68 38 alkali 19 Brushing very good silicate Inv. Example 358 8.88 100:1 0.12 41 alkyl 45 Brushing very good silicate Inv. Example 359 24.78   1:60 0.00 54 epoxy-based 160 Brushing very good resin Inv. Example 360 9.54 130:1 0.37 57 acryl-based 21 Spraying very good resin Inv. Example 361 3.54 160:1 1.39 59 urethane- 15 Spraying very good based resin Inv. Example 362 4.11 100:1 4.16 64 polyester 7 Spraying very good resin Inv. Example 363 3.87  50:1 4.71 66 epoxy-based 12 Spraying very good resin Inv. Example 364 5.54   1:80 0.10 67 acryl-based 19 Spraying very good resin Inv. Example 365 11.14   1:60 0.12 75 urethane- 25 Spraying very good based resin Inv. Example 366 5.78   1:15 0.62 74 polyester 18 Spraying very good resin Inv. Example 367 22.14  90:1 14.64 77 epoxy-based 30 Spraying very good resin Inv. Example 368 2.04 120:1 16.56 41 acryl-based 2 Brushing very good resin Inv. Example 369 38.47 100:1 17.72 34 urethane- 157 Brushing very good based resin Inv. Example 370 6.47 170:1 19.39 43 polyester 13 Brushing very good resin Inv. Example 371 5.22 300:1 22.33 53 epoxy-based 24 Brushing very good resin Inv. Example 372 32.14 200:1 0.17 60 acryl-based 180 Brushing very good resin Inv. Example 373 5.22 300:1 8.27 35 urethane- 14 Brushing very good based resin Inv. Example 374 10.45 150:1 6.46 37 polyester 22 Brushing very good resin Inv. Example 375 6.87  65:1 9.55 30 epoxy-based 27 Brushing very good resin Inv. Example 376 24.45 300:1 11.36 80 acryl-based 135 Brushing very good resin Inv. Example 377 4.47 150:1 22.35 35 urethane- 28 Spraying very good based resin Inv. Example 378 12.47  70:1 25.34 42 polyester 31 Spraying very good resin Inv. Example 379 6.45 300:1 17.74 66 epoxy-based 16 Spraying very good resin Inv. Example 380 39.45 100:1 0.14 35 acryl-based 199 Brushing very good resin (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 111 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg Average Intermetallic Fracture Mean Value of Compounds on Mg Facet &/or Size Aspect Al Si Surface of MgZn₂ or # of (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ facets Inv. Example 1802 0.15 FC 0.02 1.05 0.1 0.07 Existence Existence 6 Inv. Example 1803 0.19 FC 10.5 1.12 0.04 0.1 Existence Existence 6 Inv. Example 1804 0.18 FC 12.5 1.23 30.0 0.01 Existence No 7 Inv. Example 1805 0.11 FC 18.5 1.36 0.02 3 Existence Existence 7 Inv. Example 1806 0.15 FC 11.5 1.11 0 0 Existence No 6 Inv. Example 1807 0.24 FC 9.6 1.07 0 0 Existence Existence 6 Inv. Example 1808 0.18 FC 8.5 1.42 10.4 0.57 Existence No 6 Inv. Example 1809 0.12 FC 7.72 1.38 4.65 2.67 Existence Existence 7 Inv. Example 1810 0.19 FC 8.32 1.22 24.8 2.4 Existence No 6 Inv. Example 1811 0.18 FC 10.05 1.14 4.52 0.57 Existence No 6 Inv. Example 1812 0.21 FC 10.6 1.13 17.5 2.45 Existence Existence 6 Inv. Example 1813 0.76 FC 5.7 1.02 0 0 Existence No 7 Inv. Example 1814 0.11 FC 6.4 1.06 11.05 0.23 Existence Existence 6 Inv. Example 1815 0.14 FC 3.2 1.05 2.65 0.74 Existence Existence 7 Inv. Example 1816 15 FC 4.5 1.24 6.45 2.14 Existence No 6 Inv. Example 1817 14.5 FC 5.2 1.33 0 0 Existence No 6 Inv. Example 1818 18.5 FC 1.9 1.27 0 0 Existence Existence 6 Inv. Example 1819 15.1 FC 0.02 1.05 0.05 0.03 Existence No 7 Inv. Example 1820 15.6 FC 10.5 1.12 0 0.08 Existence No 6 Inv. Example 1821 12.5 FC 12.5 1.23 0.05 0 Existence Existence 6 Inv. Example 1822 18.7 FC 18.5 1.36 0.44 0.07 Existence Existence 7 Inv. Example 1823 14.5 FC 11.5 1.11 0.08 0.07 Existence Existence 6 Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in Coat Result of particle Metal Particle Dry Coat Thickness Coating Corrosion (μm) Particle) (mass %) (mass %) Base Resin (μm) Method Test Inv. Example 1802 2.04 5:2 0.11 35 alkali 2 Spraying very good silicate Inv. Example 1803 50.00 7:1 0.17 77 alkyl 37 Spraying very good silicate Inv. Example 1804 2.45 68:1  0.18 43 alkali 2 Spraying good silicate Inv. Example 1805 5.33 10:1  0.10 52 alkyl 160 Brushing very good silicate Inv. Example 1806 2.41 25:7  0.12 66 alkali 5 Brushing very good silicate Inv. Example 1807 23.43 300:9  0.23 72 alkyl 56 Brushing very good silicate Inv. Example 1808 6.03 180:1  0.18 40 alkali 2 Spraying very good silicate Inv. Example 1809 24.5 23:1  0.12 36 alkyl 18 Spraying very good silicate Inv. Example 1810 5.32 165:1  0.19 32 alkyl 23 Spraying very good silicate Inv. Example 1811 14.34 300:1  0.18 53 epoxy-based 30 Brushing very good resin Inv. Example 1812 5.04 120:1  0.21 67 acryl-based 77 Brushing very good resin Inv. Example 1813 2.32 2:9 0.14 72 urethane- 54 Brushing very good based resin Inv. Example 1814 20.34 119:3  0.11 77 polyester 47 Spraying very good resin Inv. Example 1815 12.33 233:1  0.14 34 epoxy-based 43 Spraying very good resin Inv. Example 1816 17.84  1:132 0.11 43 acryl-based 52 Brushing very good resin Inv. Example 1817 6.66  1:55 10.24 53 urethane- 20 Brushing very good based resin Inv. Example 1818 3.65  1:23 0.77 60 polyester 200 Brushing very good resin Inv. Example 1819 22.62 200:1  15.02 35 alkali 22 Spraying very good silicate Inv. Example 1820 45.33  1:15 0.98 77 alkyl 25 Spraying very good silicate Inv. Example 1821 43.22  1:10 1.14 43 alkali 14 Spraying very good silicate Inv. Example 1822 12.33 1:6 2.67 52 urethane- 112 Spraying very good based resin Inv. Example 1823 13.42  1:45 0.32 66 alkali 24 Spraying very good silicate (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 112 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg Average Intermetallic Fracture Mean Value of Compounds on Mg Facet &/or Size Aspect Al Si Surface of MgZn₂ or # of (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ facets Inv. Example 1824 7.5 FC 9.6 1.07 0.1 0.2 Existence No 7 Inv. Example 1825 4.5 FC 8.5 1.42 0 0 Existence Existence 6 Inv. Example 1826 1.5 FC 7.72 1.38 0 0 Existence Existence 6 Inv. Example 1827 4.8 FC 8.32 1.22 0 0.07 Existence Existence 6 Inv. Example 1828 9.6 FC 10.05 1.14 0 0.02 Existence No 6 Inv. Example 1829 11.5 FC 10.6 1.13 25.8 0.05 Existence Existence 7 Inv. Example 1830 9.8 FC 5.7 1.02 22.1 0 Existence Existence 6 Inv. Example 1831 7.6 FC 6.4 1.06 21.5 0.05 Existence Existence 6 Inv. Example 1832 3.2 FC 3.2 1.05 0.05 2.29 Existence No 6 Inv. Example 1833 1.9 FC 4.5 1.24 0.05 0.03 Existence Existence 7 Inv. Example 1834 11.5 FC 5.2 1.33 0 0.08 Existence Existence 6 Inv. Example 1835 8.7 FC 1.9 1.27 0 0 Existence No 6 Inv. Example 1836 9.6 FC 0.02 1.05 0 0 Existence Existence 7 Inv. Example 1837 9.4 FC 10.5 1.12 0.08 0.07 Existence No 6 Inv. Example 1838 10.5 FC 12.5 1.23 0.1 0.2 Existence Existence 6 Inv. Example 1839 12.6 FC 18.5 1.36 0.05 0.2 Existence No 6 Inv. Example 1840 29.5 FC 11.5 1.11 0.07 0 Existence Existence 7 Inv. Example 1841 29.4 FC 9.6 1.07 0 0.07 Existence Existence 7 Inv. Example 1842 27.5 FC 8.5 1.42 0 0.02 Existence Existence 6 Inv. Example 1843 0.8 FC 7.72 1.38 25.8 0.05 Existence Existence 6 Inv. Example 1844 1.6 FC 8.32 1.22 22.1 0 Existence No 7 Inv. Example 1845 22.9 FC 10.05 1.14 21.5 0.05 Existence No 6 Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in Coat Result of particle Metal Particle Dry Coat Thickness Corrosion (μm) Particle) (mass %) (mass %) Base Resin (μm) Coating Method Test Inv. Example 1824 22.32  1:50 0.15 72 urethane- 150 Spraying very good based resin Inv. Example 1825 7.34 1:9 0.45 40 alkali 18 Spraying very good silicate Inv. Example 1826 44.54 1:7 0.19 36 alkyl 19 Brushing very good silicate Inv. Example 1827 32.87 1:4 0.96 32 alkyl 24 Spraying very good silicate Inv. Example 1828 20.32  1:14 0.64 53 urethane- 99 Spraying very good based resin Inv. Example 1829 2.03  1:11 0.96 67 alkyl 7 Spraying very good silicate Inv. Example 1830 5.33  1:28 0.34 72 epoxy-based 100 Spraying very good resin Inv. Example 1831 2.33 1:4 1.52 77 alkyl 27 Brushing very good silicate Inv. Example 1832 27.44 250:1  3.19 34 alkali 15 Spraying very good silicate Inv. Example 1833 12.33 1:1 0.95 43 alkyl 14 Spraying very good silicate Inv. Example 1834 36.43 1:4 2.30 53 urethane- 55 Spraying very good based resin Inv. Example 1835 12.33  1:12 0.67 35 alkyl 8 Spraying very good silicate Inv. Example 1836 3.21 70:1  9.46 77 urethane- 122 Brushing very good based resin Inv. Example 1837 26.33 1:3 2.35 43 alkyl 54 Spraying very good silicate Inv. Example 1838 44.21  1:24 0.42 52 alkali 19 Spraying very good silicate Inv. Example 1839 3.43  1:10 1.15 66 alkyl 25 Brushing very good silicate Inv. Example 1840 47.32 300:1  29.40 72 alkyl 58 Spraying very good silicate Inv. Example 1841 12.33  1:66 0.44 40 alkyl 21 Spraying very good silicate Inv. Example 1842 17.44 120:1  27.27 36 alkali 19 Brushing very good silicate Inv. Example 1843 42.21 6:5 0.44 32 urethane- 56 Spraying very good based resin Inv. Example 1844 12.34 1:1 0.80 53 alkyl 77 Spraying very good silicate Inv. Example 1845 20.32 1:1 11.45 67 alkyl 54 Spraying very good silicate (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 113 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg Average Intermetallic Fracture Mean Value of Compounds on Mg Facet &/or Size Aspect Al Si Surface of MgZn₂ or # of (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ facets Inv. Example 1846 28.5 FC 10.6 1.13 0.05 2.29 Existence No 6 Inv. Example 1847 29.5 FC 5.7 1.02 0.1 0.2 Existence Existence 6 Inv. Example 1848 18.7 FC 6.4 1.06 0.05 0.2 Existence No 7 Inv. Example 1849 19.5 FC 3.2 1.05 0.07 0 Existence Existence 6 Inv. Example 1850 20.4 FC 4.5 1.24 0 0.07 Existence Existence 6 Inv. Example 1851 0.6 FC 5.2 1.33 0 0.02 Existence Existence 6 Inv. Example 1852 0.8 FC 1.9 1.27 22.1 0 Existence Existence 7 Inv. Example 1853 22.5 FC 0.02 1.05 0.1 0.07 Existence Existence 6 Inv. Example 1854 20.6 FC 10.5 1.12 0.04 0.1 Existence Existence 6 Inv. Example 1855 21.6 FC 12.5 1.23 30.0 0.01 Existence No 7 Inv. Example 1856 20.8 FC 7.72 1.38 0 0 Existence Existence 7 Inv. Example 1857 23.6 FC 8.32 1.22 0 0 Existence Existence 6 Inv. Example 1858 24.5 FC 10.05 1.14 4.52 0.57 Existence No 6 Inv. Example 1859 18.6 FC 10.6 1.13 17.5 2.45 Existence Existence 7 Inv. Example 1860 17.8 FC 5.2 1.33 27.6 2.4 Existence No 6 Inv. Example 1861 16.5 FC 1.9 1.27 4.32 1.07 Existence Existence 6 Inv. Example 1862 14.5 FC 0.02 1.05 0.05 0.03 Existence No 7 Inv. Example 1863 19 FC 10.5 1.12 0 0.08 Existence No 6 Inv. Example 1864 15 FC 12.5 1.23 0.05 0 Existence Existence 6 Inv. Example 1865 16.4 FC 18.5 1.36 0.44 0.07 Existence Existence 7 Inv. Example 1866 13.5 FC 11.5 1.11 0.08 0.07 Existence Existence 6 Inv. Example 1867 10.6 FC 11.5 1.11 8.02 2.04 Existence No 6 Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in Coat Result of particle Metal Particle Dry Coat Thickness Corrosion (μm) Particle) (mass %) (mass %) Base Resin (μm) Coating Method Test Inv. Example 1846 23.44  1:76 0.37 72 alkyl 64 Spraying very good silicate Inv. Example 1847 23.45 1:6 4.21 77 alkyl 34 Brushing very good silicate Inv. Example 1848 23.21  1:35 0.52 34 alkali 28 Spraying very good silicate Inv. Example 1849 39.44 1:5 3.25 43 urethane- 109 Brushing very good based resin Inv. Example 1850 12.34  1:62 0.32 53 alkyl 15 Spraying very good silicate Inv. Example 1851 29.99 1:4 0.12 72 alkyl 14 Spraying very good silicate Inv. Example 1852 15.21 5:9 0.29 77 alkyl 18 Spraying very good silicate Inv. Example 1853 23.34  1:220 0.10 35 alkali 2 Spraying very good silicate Inv. Example 1854 2.32  1:80 0.25 77 alkyl 37 Spraying very good silicate Inv. Example 1855 4.21  1:50 0.42 43 alkali 2 Spraying good silicate Inv. Example 1856 15.21  1:10 1.89 52 alkyl 160 Brushing very good silicate Inv. Example 1857 23.34 1:1 11.80 66 alkali 5 Brushing very good silicate Inv. Example 1858 2.32  1:78 0.31 72 alkyl 56 Brushing very good silicate Inv. Example 1859 4.21  1:10 1.69 40 alkali 2 Spraying very good silicate Inv. Example 1860 29.99  1:50 0.35 36 alkyl 18 Spraying very good silicate Inv. Example 1861 15.21  1:10 1.50 32 alkyl 23 Spraying very good silicate Inv. Example 1862 23.34 1:1 7.25 53 epoxy-based 30 Brushing very good resin Inv. Example 1863 2.32 1:3 4.75 67 acryl-based 77 Brushing very good resin Inv. Example 1864 4.21 1:7 1.88 72 urethane- 54 Brushing very good based resin Inv. Example 1865 15.21  1:50 0.32 77 polyester 47 Spraying very good resin Inv. Example 1866 23.34  1:10 1.23 34 epoxy-based 43 Spraying very good resin Inv. Example 1867 13.45 1:3 2.65 43 acryl-based 52 Brushing very good resin (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 114 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg Average Intermetallic Fracture Mean Value of Compounds on Mg Facet &/or Size Aspect Al Si Surface of MgZn₂ or # of (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ facets Inv. Example 1868 10.7 FC 9.6 1.07 15.6 1.27 Existence Existence 6 Inv. Example 1869 10.9 FC 8.5 1.42 10.4 0.57 Existence No 6 Inv. Example 1870 11.6 FC 7.72 1.38 4.65 2.67 Existence Existence 7 Inv. Example 1871 14.7 FC 8.32 1.22 24.8 2.4 Existence No 6 Inv. Example 1872 19.5 FC 10.05 1.14 4.52 0.57 Existence No 6 Inv. Example 1873 10.2 FC 10.6 1.13 0 0 Existence Existence 6 Inv. Example 1874 4 FC 5.7 1.02 0 0 Existence No 7 Inv. Example 1875 7.2 FC 6.4 1.06 11.05 0.23 Existence Existence 6 Inv. Example 1876 3.6 FC 3.2 1.05 2.65 0.74 Existence Existence 7 Inv. Example 1877 26.9 FC 4.5 1.24 6.45 2.14 Existence No 6 Inv. Example 1878 27.9 FC 5.2 1.33 27.6 2.4 Existence No 6 Inv. Example 1879 28.9 FC 1.9 1.27 4.32 1.07 Existence Existence 6 Inv. Example 1880 23.8 FC 0.02 1.05 0.05 0.03 Existence No 7 Inv. Example 1881 26.8 FC 10.5 1.12 0 0.08 Existence No 6 Inv. Example 1882 25.6 FC 12.5 1.23 0.05 0 Existence Existence 6 Inv. Example 1883 29.8 FC 18.5 1.36 0.44 0.07 Existence Existence 7 Inv. Example 1884 18.9 FC 11.5 1.11 0.08 0.07 Existence Existence 6 Inv. Example 1885 5.6 FC 9.6 1.07 0.1 0.2 Existence No 7 Inv. Example 1886 4.7 FC 8.5 1.42 0.05 0.2 Existence Existence 6 Inv. Example 1887 6.8 FC 7.72 1.38 0.07 0 Existence Existence 6 Inv. Example 1888 9 FC 8.32 1.22 0 0.07 Existence Existence 6 Inv. Example 1889 2.1 FC 10.05 1.14 0 0.02 Existence No 6 Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in Coat Result of particle Metal Particle Dry Coat Thickness Corrosion (μm) Particle) (mass %) (mass %) Base Resin (μm) Coating Method Test Inv. Example 1868 2.34  1:10 0.97 53 urethane- 20 Brushing very good based resin Inv. Example 1869 28.34 1:5 1.82 60 polyester 200 Brushing very good resin Inv. Example 1870 19.87 200:1  11.54 35 alkali 22 Spraying very good silicate Inv. Example 1871 39.74 1:8 1.63 77 alkyl 25 Spraying very good silicate Inv. Example 1872 24.32 1:1 9.75 43 alkali 14 Spraying very good silicate Inv. Example 1873 22.33 1:7 1.28 52 urethane- 112 Spraying very good based resin Inv. Example 1874 48.54 1:3 1.00 66 alkali 24 Spraying very good silicate Inv. Example 1875 23.75 1:7 0.90 72 urethane- 150 Spraying very good based resin Inv. Example 1876 15.62 1:2 1.20 40 alkali 18 Spraying very good silicate Inv. Example 1877 2.34 117:1  26.67 36 alkyl 19 Brushing very good silicate Inv. Example 1878 23.04  1:270 0.10 32 alkyl 24 Spraying very good silicate Inv. Example 1879 3.05  1:117 0.24 53 urethane- 99 Spraying very good based resin Inv. Example 1880 43.23  1:66 0.36 67 alkyl 7 Spraying very good silicate Inv. Example 1881 2.04  1:109 0.24 72 epoxy-based 100 Spraying very good resin Inv. Example 1882 50.00 250:1  25.50 77 alkyl 27 Brushing very good silicate Inv. Example 1883 2.45 70:1  29.38 34 alkali 15 Spraying very good silicate Inv. Example 1884 5.33  1:15 1.18 43 alkyl 14 Spraying very good silicate Inv. Example 1885 2.41 1:5 0.93 53 urethane- 55 Spraying very good based resin Inv. Example 1886 23.43 2:3 1.88 35 alkyl 8 Spraying very good silicate Inv. Example 1887 6.03 1:9 0.68 77 urethane- 122 Brushing very good based resin Inv. Example 1888 24.5  1:10 0.82 43 alkyl 54 Spraying very good silicate Inv. Example 1889 5.32  1:14 0.14 52 alkali 19 Spraying very good silicate (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 115 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg Average Intermetallic Fracture Mean Value of Compounds on Mg Facet &/or Size Aspect Al Si Surface of MgZn₂ or # of (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ facets Inv. Example 1890 4.8 FC 10.6 1.13 0 0 Existence Existence 7 Inv. Example 1891 4.2 FC 5.7 1.02 0 0 Existence Existence 6 Inv. Example 1892 4.3 FC 6.4 1.06 21.5 0.05 Existence Existence 6 Inv. Example 1893 4 FC 3.2 1.05 0.05 2.29 Existence No 6 Inv. Example 1894 3.7 FC 4.5 1.24 0.05 0.03 Existence Existence 7 Inv. Example 1895 6.4 FC 5.2 1.33 0 0.08 Existence Existence 6 Inv. Example 1896 6.9 FC 1.9 1.27 0.05 0 Existence No 6 Inv. Example 1897 16.9 FC 0.02 1.05 0.44 0.07 Existence Existence 7 Inv. Example 1898 18.7 FC 10.5 1.12 0.08 0.07 Existence No 6 Inv. Example 1899 24.4 FC 12.5 1.23 0.1 0.2 Existence Existence 6 Inv. Example 1900 10.6 FC 18.5 1.36 0 0 Existence No 6 Inv. Example 1901 15.8 FC 11.5 1.11 0 0 Existence Existence 7 Inv. Example 1902 19.5 FC 9.6 1.07 0 0.07 Existence Existence 7 Inv. Example 1903 7.8 FC 8.5 1.42 0 0.02 Existence Existence 6 Inv. Example 1904 4.9 FC 7.72 1.38 25.8 0.05 Existence Existence 6 Inv. Example 1905 10.8 FC 8.32 1.22 22.1 0 Existence No 7 Inv. Example 1906 3.8 FC 10.05 1.14 21.5 0.05 Existence No 6 Inv. Example 1907 22.6 FC 10.6 1.13 0.05 2.29 Existence No 6 Inv. Example 1908 27.9 FC 5.7 1.02 0 0 Existence Existence 6 Inv. Example 1909 24.8 FC 6.4 1.06 0 0 Existence No 7 Inv. Example 1910 26.8 FC 3.2 1.05 0.07 0 Existence Existence 6 Inv. Example 1911 25.9 FC 4.5 1.24 0 0.07 Existence Existence 6 Inv. Example 1912 9.8 FC 5.2 1.33 0 0.02 Existence Existence 6 Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in Coat Result of particle Metal Particle Dry Coat Thickness Corrosion (μm) Particle) (mass %) (mass %) Base Resin (μm) Coating Method Test Inv. Example 1890 14.34 1:7 0.60 66 alkyl 25 Brushing very good silicate Inv. Example 1891 5.04  1:12 0.32 72 alkyl 58 Spraying very good silicate Inv. Example 1892 2.32 1:3 1.08 40 alkyl 21 Spraying very good silicate Inv. Example 1893 20.34 1:7 0.50 36 alkali 19 Brushing very good silicate Inv. Example 1894 12.33  1:10 0.34 32 urethane- 56 Spraying very good based resin Inv. Example 1895 17.84 1:1 3.20 53 alkyl 77 Spraying very good silicate Inv. Example 1896 6.66 1:3 1.73 67 alkyl 54 Spraying very good silicate Inv. Example 1897 3.65 2:3 6.76 72 alkyl 64 Spraying very good silicate Inv. Example 1898 22.62 1:2 6.23 77 alkyl 34 Brushing very good silicate Inv. Example 1899 45.33 1:4 4.88 34 alkali 28 Spraying very good silicate Inv. Example 1900 43.22 1:6 1.51 43 urethane- 109 Brushing very good based resin Inv. Example 1901 12.33  1:115 0.14 53 alkyl 15 Spraying very good silicate Inv. Example 1902 13.42  1:23 0.81 72 alkyl 14 Spraying very good silicate Inv. Example 1903 22.32  1:12 0.60 77 alkyl 18 Spraying very good silicate Inv. Example 1904 7.34  1:10 0.45 77 urethane- 122 Brushing very good based resin Inv. Example 1905 44.54 1:3 2.70 43 alkyl 54 Spraying very good silicate Inv. Example 1906 32.87 1:5 0.63 52 alkali 19 Spraying very good silicate Inv. Example 1907 20.32  1:25 0.87 66 alkyl 25 Brushing very good silicate Inv. Example 1908 2.03 4:5 12.40 72 alkyl 58 Spraying very good siliate Inv. Example 1909 5.33 3:8 6.76 40 alkyl 21 Spraying very good silicate Inv. Example 1910 2.33  9:34 5.61 36 alkali 19 Brushing very good silicate Inv. Example 1911 27.44 7:8 12.09 32 urethane- 56 Spraying very good based resin Inv. Example 1912 12.33  9:17 3.39 53 alkyl 77 Spraying very good silicate (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 116 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg Average Intermetallic Fracture Mean Value of Compounds on Mg Facet &/or Size Aspect Al Si Surface of MgZn₂ or # of (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ facets Inv. Example 1913 5.6 FC 1.9 1.27 22.1 0 Existence Existence 7 Inv. Example 1914 12.3 FC 0.02 1.05 1.24 1.8 Existence Existence 7 Inv. Example 1915 0.8 FC 27.89 1.12 1.24 0.9 Existence Existence 6 Inv. Example 1916 1 FC 0.32 1.23 0.8 0.7 Existence No 7 Inv. Example 1917 2.3 FC 11.44 1.36 0 1.8 Existence Existence 6 Inv. Example 1918 15.6 FC 1.05 1.11 1.1 2.41 Existence Existence 6 Inv. Example 1919 6.7 FC 36.47 1.07 1.8 0.08 Existence Existence 6 Inv. Example 1920 7.5 FC 5.07 1.42 3.8 2.23 Existence No 6 Inv. Example 1921 8.4 FC 7.72 1.38 2.9 0.06 Existence Existence 7 Inv. Example 1922 9.3 FC 8.32 1.22 10.5 0.02 Existence Existence 6 Inv. Example 1923 10.4 FC 10.05 1.14 2.9 0.02 Existence Existence 6 Inv. Example 1924 11.2 FC 6.08 1.13 16.8 1.37 Existence No 7 Inv. Example 1925 11.7 FC 17.89 1.02 0 2.43 Existence Existence 6 Inv. Example 1926 21.5 FC 19.54 1.06 3.6 0.02 Existence Existence 6 Inv. Example 1927 13.4 FC 21.08 1.05 2.1 1.5 Existence No 6 Inv. Example 1928 14.6 FC 23.04 1.24 0.06 1.3 Existence Existence 6 Inv. Example 1929 25.8 FC 9.21 1.33 0.02 1.8 Existence Existence 7 Inv. Example 1930 16.7 FC 0.12 1.27 1.6 0.9 Existence Existence 6 Inv. Example 1931 17.3 FC 29.24 1.37 3.5 0 Existence Existence 6 Inv. Example 1932 18.5 FC 128.74 1.10 9.8 1.8 Existence No 7 Inv. Example 1933 19.3 FC 33.57 1.04 11.5 0.7 Existence Existence 6 Inv. Example 1934 3.5 FC 3.04 1.02 0.4 1.5 Existence Existence 6 Inv. Example 1935 22.5 FC 7.54 1.01 0.6 1.3 Existence Existence 6 Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in particle Metal Particle Dry Coat Coat Thickness Coating Result of (μm) Particle) (mass %) (mass %) Base Resin (μm) Method Corrosion Test Inv. Example 1913 36.43 1:1 2.80 67 alkyl 54 Spraying very good silicate Inv. Example 1914 11.9  1:31 0.38 52 alkali 2 Spraying very good silicate Inv. Example 1915 10.5 1:4 0.16 55 alkali 20 Spraying very good silicate Inv. Example 1916 9.8 1:1 0.50 69 alkali 5 Spraying very good silicate Inv. Example 1917 7.9 1:7 0.29 78 alkyl 20 Spraying very good silicate Inv. Example 1918 11.6  1:11 1.30 42 alkali 15 Brushing very good silicate Inv. Example 1919 16.9 1:2 2.23 32 alkyl 57 Brushing very good silicate Inv. Example 1920 20.34 1:7 0.94 66 alkali 13 Brushing very good silicate Inv. Example 1921 8.9 1:4 1.68 67 alkyl 22 Brushing very good silicate Inv. Example 1922 7.5 1:5 1.55 64 alkali 20 Spraying very good silicate Inv. Example 1923 10.9  1:10 0.95 74 alkyl 27 Spraying very good silicate Inv. Example 1924 20.34 1:9 1.12 82 alkali 15 Spraying very good silicate Inv. Example 1925 6.7 240:1  11.65 37 alkyl 35 Spraying very good silicate Inv. Example 1926 7.9  1:120 0.18 42 alkali 34 Brushing very good silicate Inv. Example 1927 5.6 99:1  13.27 66 alkyl 45 Brushing very good silicate Inv. Example 1928 11.5  1:99 0.15 48 alkali 52 Brushing very good silicate Inv. Example 1929 20.34  1:242 0.11 33 alkyl 23 Brushing very good silicate Inv. Example 1930 10.5 1:6 2.39 75 alkali 5 Spraying very good silicate Inv. Example 1931 7.6 1:1 8.65 77 alkyl 52 Brushing very good silicate Inv. Example 1932 8.2 1:7 2.31 66 alkali 150 Brushing very good silicate Inv. Example 1933 9.1 1:5 3.22 67 alkyl 60 Brushing very good silicate Inv. Example 1934 10.6 1:2 1.17 45 alkali 15 Spraying very good silicate Inv. Example 1935 8.4  1:221 0.10 48 alkyl 24 Spraying very good silicate (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 117 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg Average Intermetallic Fracture Mean Value of Compounds on Mg Facet &/or Size Aspect Al Si Surface of MgZn₂ or # of (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ facets Inv. Example 1936 23.7 FC 6.81 1.08 10.6 1.8 Existence No 6 Inv. Example 1937 24.2 FC 5.25 1.14 9.5 0 Existence Existence 7 Inv. Example 1938 0.2 FC 194.23 1.23 11.04 0.7 Existence Existence 6 Inv. Example 1939 27.1 FC 28.74 1.33 0.01 1.8 Existence Existence 6 Inv. Example 1940 29.3 FC 13.57 1.37 0.07 0.7 Existence Existence 7 Inv. Example 1941 0.5 FC 0.65 1.44 1.8 1.5 Existence Existence 6 Inv. Example 1942 2.7 FC 4.12 1.21 0 1.3 Existence Existence 6 Inv. Example 1943 28.4 FC 0.72 1.22 2.9 1.8 Existence Existence 6 Inv. Example 1944 8.7 FC 117.54 1.23 10.5 0.9 Existence Existence 6 Inv. Example 1945 9.2 FC 7.81 1.47 2.9 0.7 Existence Existence 7 Inv. Example 1946 17.8 FC 80.25 1.01 16.8 1.8 Existence No 6 Inv. Example 1947 20.2 FC 8.47 1.04 2.7 0.7 Existence Existence 6 Inv. Example 1948 0.4 FC 0.87 1.05 0.04 0.7 Existence Existence 7 Inv. Example 1949 13.7 FC 25.78 1.12 0 0.04 Existence Existence 6 Inv. Example 1950 14.7 FC 93.45 1.11 1.24 0.05 Existence Existence 6 Inv. Example 1951 2.4 FC 0.97 1.08 0.05 1.24 Existence Existence 6 Inv. Example 1952 4.5 FC 54.89 1.47 1.24 0.06 Existence Existence 6 Inv. Example 1953 0.1 FC 10.81 1.50 1.24 0.07 Existence Existence 7 Inv. Example 1954 30.0 FC 18.24 1.13 0 0.75 Existence Existence 6 Inv. Example 1955 24.5 FC 114.78 1.04 0.9 1.5 Existence Existence 6 Inv. Example 1956 27.6 FC 3.87 1.02 0.03 1.3 Existence Existence 7 Inv. Example 1957 4.1 FC 11.94 1.08 10.5 1.8 Existence No 6 Inv. Example 1958 3.2 FC 142.58 1.15 2.9 0.9 Existence Existence 6 Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in particle Metal Particle Dry Coat Coat Thickness Coating Result of (μm) Particle) (mass %) (mass %) Base Resin (μm) Method Corrosion Test Inv. Example 1936 5.3  1:31 0.74 68 alkali 34 Spraying very good silicate Inv. Example 1937 20.34 1:4 4.84 35 alkyl 20 Brushing very good silicate Inv. Example 1938 7.8 1:1 0.10 37 alkali 200 Brushing very good silicate Inv. Example 1939 10.5 1:7 3.39 38 alkyl 56 Brushing very good silicate Inv. Example 1940 20.34 400:1  29.23 41 alkali 34 Spraying very good silicate Inv. Example 1941 7.9 1:2 0.17 54 alkyl 2 Spraying very good silicate Inv. Example 1942 11.6  1:300 0.01 57 alkali 15 Spraying very good silicate Inv. Example 1943 16.9 1:4 5.68 59 alkali 10 Spraying very good silicate Inv. Example 1944 10.5 1:5 1.45 64 alkyl 125 Brushing very good silicate Inv. Example 1945 8.9  1:10 0.84 66 alkali 24 Brushing very good silicate Inv. Example 1946 7.5 1:9 1.78 67 alkyl 110 Brushing very good silicate Inv. Example 1947 10.9 1:1 10.10 34 alkali 24 Brushing very good silicate Inv. Example 1948 20.34 130:1  0.40 54 alkyl 2 Spraying very good silicate Inv. Example 1949 6.7 130:1  13.60 62 alkali 37 Spraying very good silicate Inv. Example 1950 7.9  1:31 0.46 66 alkyl 113 Brushing very good silicate Inv. Example 1951 5.6 1:1 1.20 67 alkali 2 Spraying very good silicate Inv. Example 1952 20.34 2:1 3.00 68 alkyl 75 Brushing very good silicate Inv. Example 1953 9.9 300:1  0.10 33 alkali 30 Brushing very good silicate Inv. Example 1954 10.5  1:270 0.11 35 alkyl 34 Brushing very good silicate Inv. Example 1955 7.6  1:115 0.21 43 epoxy-based 124 Brushing very good resin Inv. Example 1956 45.33  1:29 0.92 44 acryl-based 15 Spraying very good resin Inv. Example 1957 43.22 1:3 1.03 43 urethane- 23 Spraying very good based resin Inv. Example 1958 10.6 1:9 0.32 44 polyester 157 Brushing very good resin (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 118 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg Average Intermetallic Fracture Mean Value of Compounds on Mg Facet &/or Size Aspect Al Si Surface of MgZn₂ or # of (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ facets Inv. Example 1959 2.7 FC 12.5 1.34 16.8 0.7 Existence Existence 6 Inv. Example 1960 0.12 FC 31.24 1.25 2.7 1.8 Existence Existence 6 Inv. Example 1961 0.22 FC 152.46 1.19 0.02 0.7 Existence Existence 7 Inv. Example 1962 0.37 FC 13.4 1.18 0 1.5 Existence Existence 6 Inv. Example 1963 1.4 FC 160.57 1.24 7.42 1.3 Existence Existence 6 Inv. Example 1964 4.2 FC 14.1 1.11 0.02 1.8 Existence Existence 7 Inv. Example 1965 4.8 FC 167.55 1.27 0.04 0.9 Existence Existence 6 Inv. Example 1966 8.1 FC 1.45 1.31 17.5 0 Existence Existence 6 Inv. Example 1967 7.6 FC 0.15 1.26 0.01 1.8 Existence Existence 6 Inv. Example 1968 9.9 FC 13.1 1.14 0.02 0.7 Existence Existence 6 Inv. Example 1969 14.8 FC 15.5 1.34 3.8 0 Existence Existence 7 Inv. Example 1970 16.7 FC 0.67 1.16 2.9 0 Existence Existence 6 Inv. Example 1971 17.9 FC 137.89 1.47 10.5 1.8 Existence Existence 6 Inv. Example 1972 19.5 FC 16.3 1.48 2.9 0.9 Existence Existence 7 Inv. Example 1973 22.4 FC 110.38 1.49 16.8 0.7 Existence Existence 6 Inv. Example 1974 0.17 FC 12.4 1.34 2.7 1.8 Existence Existence 6 Inv. Example 1975 8.3 FC 17.2 1.29 0.02 0.7 Existence No 6 Inv. Example 1976 6.5 FC 105.23 1.18 0.02 0.7 Existence Existence 6 Inv. Example 1977 9.7 FC 177.89 1.23 0.04 0.02 Existence Existence 7 Inv. Example 1978 11.4 FC 12.2 1.27 0.05 0.02 Existence Existence 6 Inv. Example 1979 22.5 FC 1.84 1.17 1.24 1.37 Existence Existence 6 Inv. Example 1980 25.7 FC 16.02 1.16 0.05 0.02 Existence Existence 7 Inv. Example 1981 17.8 FC 1.75 1.49 1.24 1.37 Existence Existence 6 Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in particle Metal Particle Dry Coat Coat Thickness Coating Result of (μm) Particle) (mass %) (mass %) Base Resin (μm) Method Corrosion Test Inv. Example 1959 20.34 1:5 0.45 54 epoxy-based 26 Spraying very good resin Inv. Example 1960 5.3 100:1  0.12 79 acryl-based 38 Spraying very good resin Inv. Example 1961 10.9 1:1 0.11 73 urethane- 160 Brushing very good based resin Inv. Example 1962 7.8 99:1  0.37 69 polyester 27 Brushing very good resin Inv. Example 1963 10.5 1:6 0.20 63 epoxy-based 180 Brushing very good resin Inv. Example 1964 20.34  1:12 0.32 35 acryl-based 26 Spraying very good resin Inv. Example 1965 7.9 1:5 0.80 35 urethane- 180 Brushing very good based resin Inv. Example 1966 11.6  1:33 0.24 66 polyester 15 Spraying very good resin Inv. Example 1967 16.9 1:9 0.76 67 epoxy-based 2 Spraying very good resin Inv. Example 1968 10.5  1:18 0.52 68 acryl-based 28 Spraying very good resin Inv. Example 1969 8.9  1:38 0.38 33 urethane- 30 Spraying very good based resin Inv. Example 1970 7.5  1:117 0.14 35 polyester 2 Spraying very good resin Inv. Example 1971 20.34  1:42 0.42 43 epoxy-based 157 Brushing very good resin Inv. Example 1972 9.8 1:1 9.75 44 acryl-based 28 Brushing very good resin Inv. Example 1973 6.7  1:121 0.18 42 urethane- 130 Brushing very good based resin Inv. Example 1974 45.33 120:1  0.17 33 polyester 29 Brushing very good resin Inv. Example 1975 43.22  1:145 0.06 30 epoxy-based 30 Brushing very good resin Inv. Example 1976 11.5  1:31 0.20 35 acryl-based 120 Brushing very good resin Inv. Example 1977 9.9  1:95 0.10 37 urethane- 187 Brushing very good based resin Inv. Example 1978 10.5  1:33 0.34 77 polyester 28 Spraying very good resin Inv. Example 1979 7.6 120:1  22.31 41 epoxy-based 5 Spraying very good resin Inv. Example 1980 8.2  1:28 0.89 35 acryl-based 35 Spraying very good resin Inv. Example 1981 9.1  1:33 0.52 58 urethane- 5 Spraying very good based resin (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 119 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg Average Intermetallic Fracture Mean Value of Compounds on Mg Facet &/or Size Aspect Al Si Surface of MgZn₂ or # of (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ facets Inv. Example 1982 0.14 FC 198.78 1.34 1.24 1.37 Existence Existence 6 Inv. Example 1983 6.7 FC 13.1 1.16 0.8 1.5 Existence Existence 6 Inv. Example 1984 7.5 FC 15.5 1.47 0.9 1.3 Existence Existence 6 Inv. Example 1985 8.4 FC 0.67 1.48 1.1 1.8 Existence No 7 Inv. Example 1986 9.3 FC 12.2 1.49 1.8 0.9 Existence Existence 6 Inv. Example 1987 1.4 FC 1.84 1.34 3.8 0.7 Existence Existence 6 Inv. Example 1988 4.2 FC 16.02 1.29 2.9 1.8 Existence Existence 7 Inv. Example 1989 4.8 FC 1.75 1.18 10.5 0.7 Existence Existence 6 Inv. Example 1990 8.1 FC 12.4 1.23 2.9 1.5 Existence Existence 6 Inv. Example 1991 7.6 FC 17.2 1.27 16.8 1.3 Existence Existence 6 Inv. Example 1992 9.9 FC 13.1 1.17 2.7 1.8 Existence Existence 6 Inv. Example 1993 0.4 FC 29.9 1.16 3.6 0.9 Existence Existence 7 Inv. Example 1994 10.5 FC 0.21 1.27 0 0.7 Existence Existence 6 Inv. Example 1995 0.4 FC 0.22 1.17 0.06 1.8 Existence Existence 7 Inv. Example 1996 10.5 FC 29.5 1.27 0.02 0.7 Existence Existence 6 Inv. Example 1997 0.51 FC 29.9 1.18 1.6 1.5 Existence Existence 6 Inv. Example 1998 9.8 FC 0.21 1.23 3.5 0 Existence Existence 6 Inv. Example 1999 0.52 FC 0.22 1.27 9.8 1.8 Existence Existence 6 Inv. Example 2000 9.9 FC 29.5 1.17 11.5 0.9 Existence No 7 Inv. Example 2001 14.8 FC 16.02 1.48 0.4 0.7 Existence Existence 6 Inv. Example 2002 19.9 FC 1.75 1.49 0.6 1.8 Existence Existence 6 Inv. Example 2003 17.9 FC 12.4 1.34 10.6 0.7 Existence Existence 7 Inv. Example 2004 19.5 FC 17.2 1.29 9.5 0.7 Existence Existence 6 Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in particle Metal Particle Dry Coat Coat Thickness Coating Result of (μm) Particle) (mass %) (mass %) Base Resin (μm) Method Corrosion Test Inv. Example 1982 10.6 200:1  0.14 37 polyester 200 Brushing very good resin Inv. Example 1983 8.4 1:4 1.34 68 alkali 25 Spraying very good silicate Inv. Example 1984 5.3  1:18 0.39 55 alkali 15 Spraying very good silicate Inv. Example 1985 10.9 1:7 1.05 77 alkyl 20 Spraying very good silicate Inv. Example 1986 7.8  1:11 0.78 43 alkali 18 Spraying very good silicate Inv. Example 1987 8.9 1:2 0.47 45 alkyl 22 Spraying very good silicate Inv. Example 1988 7.5 1:7 0.53 66 alkali 19 Spraying very good silicate Inv. Example 1989 10.9 1:2 2.40 33 alkyl 29 Spraying very good silicate Inv. Example 1990 9.8 1:5 1.35 66 alkali 23 Spraying very good silicate Inv. Example 1991 45.33  1:10 0.69 55 alkyl 21 Spraying very good silicate Inv. Example 1992 43.22 1:9 0.99 49 alkali 19 Spraying very good silicate Inv. Example 1993 5.6 240:1  0.40 77 alkyl 15 Spraying very good silicate Inv. Example 1994 11.5 120:1  10.41 41 alkali 18 Spraying very good silicate Inv. Example 1995 9.9 99:1  0.40 64 alkyl 22 Spraying very good silicate Inv. Example 1996 10.5  1:99 0.11 58 alkyl 21 Spraying very good silicate Inv. Example 1997 7.6 1:3 0.13 33 alkyl 29 Spraying very good silicate Inv. Example 1998 8.2 1:6 1.40 66 alkali 23 Spraying very good silicate Inv. Example 1999 9.1 1:1 0.26 55 alkyl 21 Spraying very good silicate Inv. Example 2000 10.6 1:7 1.24 49 alkali 19 Spraying very good silicate Inv. Example 2001 8.4 1:5 2.47 77 alkyl 21 Spraying very good silicate Inv. Example 2002 5.3  1:150 0.13 43 alkali 19 Spraying very good silicate Inv. Example 2003 10.9  1:55 0.32 45 alkyl 15 Spraying very good silicate Inv. Example 2004 7.8  1:121 0.16 66 alkali 18 Spraying very good silicate (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 120 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg Average Intermetallic Fracture Mean Value of Compounds on Mg Facet &/or Size Aspect Al Si Surface of MgZn₂ or # of (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₂Zn₁₁ facets Comp. Example 119 2.3 FC 205.6 1.23 12.5 0.05 Existence No 6 Comp. Example 120 12.5 FC 0.005 1.36 2.1 0 Existence Existence 6 Comp. Example 121 18.9 FC 205.6 1.11 1.5 0.05 Existence Existence 7 Comp. Example 122 29.5 FC 0.005 1.07 0.05 2.29 Existence Existence 6 Comp. Example 123 14.5 FC 205.6 1.42 0 0 Existence Existence 7 Comp. Example 124 12.5 FC 0.005 1.38 0 0 Existence No 6 Comp. Example 125 18.9 FC 205.6 1.22 0.07 0 Existence Existence 6 Comp. Example 126 29.5 FC 0.005 1.14 0 0.07 Existence No 6 Comp. Example 127 2.3 NO 10.6 1.13 0 0.02 Existence Existence 7 Comp. Example 128 12.5 FC 5.7 1.02 22.1 0 Existence Existence 6 Comp. Example 129 0.5 FC 6.4 1.06 25.8 0.05 Existence No 6 Comp. Example 130 29.5 FC 3.2 1.23 22.1 0 Existence Existence 7 Comp. Example 131 14.5 NO 4.5 1.36 21.5 0.05 Existence Existence 6 Comp. Example 132 9.8 FC 5.2 1.11 0.05 2.29 No No 7 Comp. Example 133 4.6 FC 1.9 1.07 0 0 Existence Existence 6 Comp. Example 134 3.2 FC 18.5 1.42 0 0 Existence No 6 Comp. Example 135 29.9 FC 12.5 1.38 0.07 0 Existence Existence 6 Comp. Example 136 7.6 FC 9.8 1.22 0 0.07 Existence Existence 7 Comp. Example 137 29.9 FC 7.6 1.14 0 0.007 Existence Existence 6 Comp. Example 138 0.6 FC 6.9 1.13 36.5 3.25 Existence Existence 6 Comp. Example 139 4.5 FC 10.5 1.02 0.005 0 Existence Existence 7 Comp. Example 140 3.7 FC 12.6 1.06 22.1 0 Existence Existence 6 Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in particle Metal Particle Dry Coat Coat Thickness Coating Result of (μm) Particle) (mass %) (mass %) Base Resin (μm) Method Corrosion Test Comp. Example 119 10.5 1:5  0.38 77 alkyl 25 Spraying poor silicate Comp. Example 120 12.6 1:3  3.13 77 urethane- 25 Spraying poor based resin Comp. Example 121 7.8 1:19  0.95 43 alkyl 105 Brushing poor silicate Comp. Example 122 16.8 1:100 0.29 52 alkali 165 Spraying poor silicate Comp. Example 123 10.5 1:260 0.06 66 alkyl 25 Spraying poor silicate Comp. Example 124 12.6 1:3  3.13 72 alkyl 25 Spraying poor silicate Comp. Example 125 7.8 1:19  0.95 40 alkyl 105 Brushing poor silicate Comp. Example 126 16.8 1:100 0.29 36 alkali 165 Spraying poor silicate Comp. Example 127 10.5 1:256 0.01 32 alkyl 25 Spraying poor silicate Comp. Example 128 12.6 1:200 0.06 53 alkyl 25 Spraying poor silicate Comp. Example 129 7.8 1:167 0.00 67 alkyl 105 Brushing poor silicate Comp. Example 130 16.8 1:300 0.10 53 urethane- 165 Spraying poor based resin Comp. Example 131 10.5 1:260 0.06 67 alkyl 25 Spraying poor silicate Comp. Example 132 12.6 1:100 0.10 72 alkyl 25 Spraying poor silicate Comp. Example 133 7.8 1:47  0.10 77 alkyl 105 Brushing poor silicate Comp. Example 134 16.8 1:32  0.10 34 urethane- 55 Spraying poor based resin Comp. Example 135 12.6 1:345 0.09 43 alkyl 28 Spraying poor silicate Comp. Example 136 7.8 1:390 0.02 52 alkyl 15 Spraying poor silicate Comp. Example 137 16.8 1:301 0.10 66 alkyl 14 Spraying poor silicate Comp. Example 138 10.5 1:333 0.00 72 urethane- 118 Brushing poor based resin Comp. Example 139 12.6 1:325 0.01 40 alkyl 22 Spraying poor silicate Comp. Example 140 7.8 1:456 0.01 36 alkyl 54 Spraying poor silicate (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 121 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg MgZn₂, Average Intermetallic Mg₂Zn₁₁, Fracture Mean Value of Compounds on Mg₂Zn₃, Mg Facet &/or Size Aspect Al Si Surface of MgZn or # of (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₁Zn₃ facets Inv. Example 2689 7.5 FC 5.07 1.42 0 0 Existence Existence 2 Inv. Example 2690 8.06 FC 7.72 1.38 0 0 Existence Existence 2 Inv. Example 2691 9.3 FC 8.32 1.22 0 0 Existence No 2 Inv. Example 2692 3.5 FC 3.04 1.02 0 0 Existence Existence 2 Inv. Example 2693 2.7 FC 4.12 1.21 0 0 Existence No 6 Inv. Example 2694 9.2 FC 7.81 1.47 0 0 Existence Existence 6 Inv. Example 2695 8.1 FC 1.45 1.31 0 0 Existence No 7 Inv. Example 2696 7.5 FC 9.6 1.07 0 0 Existence Existence 6 Inv. Example 2697 4.5 FC 8.5 1.42 0 0 Existence No 2 Inv. Example 2698 3.6 FC 3.2 1.05 0 0 Existence No 7 Inv. Example 2699 4.2 FC 5.7 1.02 1.5 0 Existence Existence 2 Inv. Example 2700 4.3 FC 6.4 1.06 5.5 1.6 Existence No 6 Inv. Example 2701 4 FC 3.2 1.05 0 0 Existence Existence 6 Inv. Example 2702 6.4 FC 5.2 1.33 0 0 Existence Existence 2 Inv. Example 2703 9.8 FC 5.2 1.33 0 0 Existence No 2 Inv. Example 2704 7.5 FC 5.07 1.42 0 0 Existence No 7 Inv. Example 2705 8.4 FC 7.72 1.38 0.5 0 Existence Existence 6 Inv. Example 2706 2.7 FC 4.12 1.21 0 0 Existence No 7 Inv. Example 2707 2.64 FC 5.5 1.22 0 0 Existence No 2 Inv. Example 2708 1.59 FC 6.7 1.14 0 0 Existence Existence 7 Inv. Example 2709 2.58 FC 8.9 1.13 0 0 Existence Existence 6 Inv. Example 2710 7.55 FC 2.15 1.14 0 0 Existence Existence 7 Inv. Example 2711 8.01 FC 2.54 1.13 0 0 Existence No 6 Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in Coat Result of particle Metal Particle Dry Coat Thickness Corrosion (μm) Particle) (mass %) (mass %) Base Resin (μm) Coating Method Test Inv. Example 2689 23.43 0.71 10.5 74 alkali 24 Brushing very good silicate Inv. Example 2690 5.96 0.64 12.5 82 alkyl 25 Spraying very good silicate Inv. Example 2691 10.64 6.20 1.5 37 alkali 14 Spraying very good silicate Inv. Example 2692 16.5 3.89 0.9 48 alkali 15 Spraying very good silicate Inv. Example 2693 7.95 0.26 10.5 32 alkali 15 Spraying very good silicate Inv. Example 2694 7.95 0.03 299.5 45 alkyl 15 Brushing very good silicate Inv. Example 2695 9.64 16.20 0.5 37 epoxy-based 5 Spraying good resin Inv. Example 2696 0.96 28.85 0.26 72 urethane- 150 Spraying very good based resin Inv. Example 2697 5.26 15.00 0.3 40 alkali 18 Spraying very good silicate Inv. Example 2698 13.5 1.20 3 40 alkali 18 Spraying very good silicate Inv. Example 2699 13.5 0.20 20.5 72 alkyl 58 Spraying very good silicate Inv. Example 2700 9.64 1.02 4.2 40 alkyl 21 Spraying very good silicate Inv. Example 2701 16.5 2.67 1.5 36 alkali 19 Brushing very good silicate Inv. Example 2702 20.59 1.28 5 53 alkyl 77 Spraying very good silicate Inv. Example 2703 0.96 0.63 15.6 53 alkyl 77 Spraying very good silicate Inv. Example 2704 6.54 15.00 0.5 66 alkali 13 Brushing very good silicate Inv. Example 2705 5.26 4.42 1.9 67 alkyl 22 Brushing very good silicate Inv. Example 2706 10.64 1.69 1.6 57 alkali 15 Spraying very good silicate Inv. Example 2707 9.64 1.06 2.5 43 alkyl 16 Spraying very good silicate Inv. Example 2708 6.9 3.18 0.5 76 alkyl 5 Spraying very good silicate Inv. Example 2709 10.5 0.52 5 49 alkyl 22 Spraying very good silicate Inv. Example 2710 13.5 6.29 1.2 75 alkyl 18 Spraying very good silicate Inv. Example 2711 20.59 0.94 8.5 73 alkyl 16 Spraying very good silicate (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 122 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg MgZn₂, Average Intermetallic Mg₂Zn₁₁, Fracture Mean Value of Compounds on Mg₂Zn₃, Mg Facet &/or Size Aspect Al Si Surface of MgZn, or # of (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₇Zn₃ facets Inv. Example 2712 1.06 FC 3.4 1.38 0 0 Existence Existence 7 Inv. Example 2713 2.64 FC 5.5 1.22 0 0 Existence Existence 6 Inv. Example 2714 1.59 FC 6.7 1.14 0 0 Existence Existence 2 Inv. Example 2715 20.5 FC 2.15 1.14 1.5 0 Existence No 7 Inv. Example 2716 18.5 FC 2.54 1.13 5.5 1.6 Existence Existence 6 Inv. Example 2717 9.51 FC 2.77 1.38 4.5 0 Existence Existence 6 Inv. Example 2718 10.01 FC 3.68 1.22 0 1.6 Existence Existence 6 Inv. Example 2719 3.54 FC 5.5 1.22 0 0 Existence No 2 Inv. Example 2720 4.05 FC 2.06 1.13 0 0 Existence Existence 6 Inv. Example 2721 8.57 FC 4.99 1.02 0 0 Existence Existence 7 Inv. Example 2722 0.02 FC 6.4 1.06 0 0 Existence No 2 Inv. Example 2723 25.5 FC 3.09 1.07 0 0 Existence Existence 6 Inv. Example 2724 2.36 FC 3.99 1.22 0 0 Existence No 2 Inv. Example 2725 0.05 FC 7.72 1.38 0 0 Existence Existence 6 Inv. Example 2726 0.04 FC 8.32 1.22 0 0 Existence No 7 Inv. Example 2727 5.22 FC 3.55 1.12 0 0 Existence Existence 7 Inv. Example 2728 4.01 FC 2.64 1.23 0 0 Existence Existence 2 Inv. Example 2729 0.05 FC 5.2 1.33 0 0 Existence Existence 2 Inv. Example 2730 10.5 FC 1.9 1.27 0 0 Existence Existence 6 Inv. Example 2731 0.05 FC 2.5 1.05 0 1.2 Existence No 7 Inv. Example 2732 10.5 FC 0.09 1.12 0 0.6 Existence No 6 Inv. Example 2733 2.64 FC 5.5 1.22 0 0.01 Existence No 7 Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in Coat Result of particle Metal Particle Dry Coat Thickness Corrosion (μm) Particle) (mass %) (mass %) Base Resin (μm) Coating Method Test Inv. Example 2712 7.82 0.50 2.1 49 alkyl 8 Spraying very good silicate Inv. Example 2713 5.26 10.56 0.25 43 alkyl 16 Spraying very good silicate Inv. Example 2714 7.06 1.59 1 76 alkyl 5 Spraying very good silicate Inv. Example 2715 0.64 8.20 2.5 75 alkyl 18 Spraying very good silicate Inv. Example 2716 46.8 3.70 5 73 alkyl 16 Spraying very good silicate Inv. Example 2717 16.5 1.73 5.5 55 alkyl 5 Spraying very good silicate Inv. Example 2718 13.5 1.54 6.5 48 alkyl 22 Spraying very good silicate Inv. Example 2719 0.96 2.36 1.5 78 alkyl 18 Spraying very good silicate Inv. Example 2720 0.96 0.81 5 52 alkyl 8 Spraying very good silicate Inv. Example 2721 8.45 1.53 5.6 61 alkyl 16 Spraying very good silicate Inv. Example 2722 2.9 0.20 0.05 77 polyester 47 Spraying very good resin Inv. Example 2723 5.4 2.43 10.5 49 alkyl 22 Spraying very good silicate Inv. Example 2724 10.6 4.72 0.5 80 alkyl 21 Spraying very good silicate Inv. Example 2725 2.32 0.07 0.75 36 alkyl 19 Brushing very good silicate Inv. Example 2726 7.8 0.20 0.2 32 alkyl 24 Spraying very good silicate Inv. Example 2727 7.95 0.50 10.5 55 alkyl 19 Spraying very good silicate Inv. Example 2728 20.59 10.03 0.4 40 alkyl 8 Spraying very good silicate Inv. Example 2729 22.5 0.06 0.9 53 urethane- 20 Brushing very good based resin Inv. Example 2730 4.6 0.08 3.5 60 polyester 200 Brushing very good resin Inv. Example 2731 4.9 5.00 0.01 38 alkali 19 Spraying very good silicate Inv. Example 2732 10.5 0.08 3.5 49 alkyl 11 Spraying very good silicate Inv. Example 2733 8.45 1.32 2 43 alkyl 16 Spraying very good silicate (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 123 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg MgZn₂, Average Intermetallic Mg₂Zn₁₁, Fracture Mean Value of Compounds on Mg₂Zn₃, Mg Facet &/or Size Aspect Al Si Surface of MgZn, or # of (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₇Zn₃ facets Inv. Example 2734 0.08 FC 5.6 1.36 1.5 0 Existence Existence 6 Inv. Example 2735 0.09 FC 11.5 1.11 5.5 1.6 Existence No 2 Inv. Example 2736 0.05 FC 19.5 1.07 4.5 0 Existence Existence 2 Inv. Example 2737 1.59 FC 6.7 1.14 0 0.1 Existence Existence 6 Inv. Example 2738 2.58 FC 8.9 1.13 0.01 0 Existence Existence 7 Inv. Example 2739 9.8 FC 8.32 1.22 3.2 0.9 Existence Existence 6 Inv. Example 2740 0.18 FC 10.05 1.14 0 0.5 Existence Existence 6 Inv. Example 2741 7.55 FC 2.15 1.14 0.2 0.1 Existence Existence 2 Inv. Example 2742 0.01 FC 0.06 1.23 1.2 0.6 Existence No 7 Inv. Example 2743 12.5 FC 2.54 1.13 0.5 0 Existence Existence 2 Inv. Example 2744 1.06 FC 3.4 1.38 1.5 0.9 Existence Existence 2 Inv. Example 2745 0.04 FC 8.5 1.42 0 1.2 Existence No 6 Inv. Example 2746 0.06 FC 7.72 1.38 0 0.6 Existence Existence 7 Inv. Example 2747 9.51 FC 2.77 1.38 0 0.01 Existence No 7 Inv. Example 2748 15.5 FC 3.68 1.22 1.5 0 Existence Existence 6 Inv. Example 2749 0.05 FC 10.6 1.13 5.5 1.6 Existence No 7 Inv. Example 2750 8.8 FC 5.7 1.02 4.5 0 Existence No 7 Inv. Example 2751 3.54 FC 5.5 1.22 0 0.1 Existence Existence 6 Inv. Example 2752 10.5 FC 3.2 1.05 0.01 0 Existence Existence 7 Inv. Example 2753 0.07 FC 4.5 1.24 3.2 0.9 Existence Existence 2 Inv. Example 2754 15.5 FC 2.54 1.14 0 0.5 Existence No 7 Inv. Example 2755 4.05 FC 2.06 1.13 0.2 0.1 Existence Existence 7 Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in Coat Result of particle Metal Particle Dry Coat Thickness Corrosion (μm) Particle) (mass %) (mass %) Base Resin (μm) Coating Method Test Inv. Example 2734 30.5 2.00 0.04 66 alkyl 16 Brushing very good silicate Inv. Example 2735 49.5 0.09 1 67 alkali 33 Brushing very good silicate Inv. Example 2736 5.9 0.10 0.5 54 alkyl 8 Brushing good silicate Inv. Example 2737 4.52 0.32 5 76 alkyl 5 Spraying very good silicate Inv. Example 2738 5.96 0.26 10 49 alkyl 22 Spraying very good silicate Inv. Example 2739 5.5 0.15 3.5 32 alkyl 23 Spraying very good silicate Inv. Example 2740 3.6 0.20 0.9 53 epoxy-based 30 Spraying very good resin Inv. Example 2741 16.5 2.16 3.5 75 alkyl 18 Spraying very good silicate Inv. Example 2742 12.5 20.00 0.0005 75 alkali 5 Spraying good silicate Inv. Example 2743 16.5 0.06 205.7 73 alkyl 16 Spraying very good silicate Inv. Example 2744 10.9 2.12 0.5 49 alkyl 8 Spraying very good silicate Inv. Example 2745 5.6 0.03 1.2 40 alkali 2 Spraying very good silicate Inv. Example 2746 22.6 3.00 0.02 36 alkyl 18 Spraying very good silicate Inv. Example 2747 20.59 0.88 10.8 55 alkyl 5 Spraying very good silicate Inv. Example 2748 20.59 0.10 152.3 48 alkyl 22 Spraying very good silicate Inv. Example 2749 9.56 0.10 0.5 67 acryl-based 77 Brushing very good resin Inv. Example 2750 5.9 0.12 2.5 72 urethane- 54 Brushing very good based resin Inv. Example 2751 6.54 0.71 5 78 alkyl 18 Spraying very good silicate Inv. Example 2752 21.4 0.20 9 34 epoxy-based 43 Spraying very good resin Inv. Example 2753 9.8 0.70 0.1 43 acryl-based 52 Brushing very good resin Inv. Example 2754 6.59 17.22 0.9 45 alkyl 19 Spraying very good silicate Inv. Example 2755 6.54 0.40 10.2 52 polyester 8 Spraying very good resin (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 124 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg MgZn₂, Average Intermetallic Mg₂Zn₁₁, Fracture Mean Value of Compounds on Mg₂Zn₃, Mg Facet &/or Size Aspect Al Si Surface of MgZn, or # of (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₇Zn₃ facets Inv. Example 2756 8.57 FC 4.99 1.02 1.2 0.6 Existence No 2 Inv. Example 2757 5.8 FC 6.4 1.06 0.5 0 Existence Existence 6 Inv. Example 2758 4.59 FC 3.09 1.07 1.5 0.9 Existence No 6 Inv. Example 2759 9.88 FC 4.66 1.42 0 1.2 Existence No 7 Inv. Example 2760 4.55 FC 4.09 1.38 0 0.6 Existence Existence 7 Inv. Example 2761 2.36 FC 3.99 1.22 0 0.01 Existence No 6 Inv. Example 2762 0.05 FC 7.72 1.38 1.5 0 Existence Existence 7 Inv. Example 2763 0.04 FC 8.32 1.22 5.5 1.6 Existence Existence 2 Inv. Example 2764 2.64 FC 4.55 1.11 4.5 0 Existence No 2 Inv. Example 2765 0.06 FC 10.6 1.13 0 0.1 Existence No 6 Inv. Example 2766 0.18 FC 5.7 1.02 0.01 0 Existence Existence 7 Inv. Example 2767 6.31 FC 3.52 1.27 3.2 0.9 Existence No 6 Inv. Example 2768 5.22 FC 3.55 1.12 0 0.5 Existence No 2 Inv. Example 2769 28.5 FC 2.64 1.23 0.2 0.1 Existence Existence 2 Inv. Example 2770 3.52 FC 3.15 1.36 1.2 0.6 Existence Existence 7 Inv. Example 2771 9.5 FC 5.2 1.33 0.5 0 Existence Existence 6 Inv. Example 2772 0.04 FC 1.9 1.27 1.5 0.9 Existence No 7 Inv. Example 2773 0.06 FC 10.5 1.12 0 1.2 Existence Existence 7 Inv. Example 2774 0.05 FC 12.5 1.23 0 0.6 Existence Existence 6 Inv. Example 2775 5.6 FC 18.5 1.36 0 0.01 Existence Existence 2 Inv. Example 2776 0.01 FC 11.5 1.11 1.5 0 Existence No 7 Inv. Example 2777 0.08 FC 9.6 1.07 5.5 1.6 Existence Existence 2 Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in Coat Result of particle Metal Particle Dry Coat Thickness Corrosion (μm) Particle) (mass %) (mass %) Base Resin (μm) Coating Method Test Inv. Example 2756 16.5 0.07 120.5 61 polyester 16 Spraying very good resin Inv. Example 2757 7.8 0.05 2.5 77 alkyl 20 Spraying very good silicate Inv. Example 2758 16.5 0.72 6.4 49 alkyl 22 Spraying very good silicate Inv. Example 2759 6.54 0.48 20.4 79 alkyl 18 Spraying very good silicate Inv. Example 2760 8.45 0.54 8.5 76 alkyl 18 Spraying very good silicate Inv. Example 2761 8.5 2.36 1 80 alkyl 21 Spraying very good silicate Inv. Example 2762 13.6 0.71 0.07 36 alkyl 19 Brushing very good silicate Inv. Example 2763 12.33 0.04 1.1 32 alkyl 24 Spraying very good silicate Inv. Example 2764 16.5 0.59 4.5 43 alkyl 5 Spraying very good silicate Inv. Example 2765 7.9 0.12 0.5 67 alkyl 7 Spraying very good silicate Inv. Example 2766 10.5 0.26 0.7 72 epoxy-based 100 Spraying very good resin Inv. Example 2767 16.5 12.62 0.5 51 alkyl 21 Spraying very good silicate Inv. Example 2768 10.64 2.09 2.5 55 alkyl 19 Spraying very good silicate Inv. Example 2769 10.5 0.93 30.5 40 alkyl 8 Spraying very good silicate Inv. Example 2770 20.59 14.08 0.25 51 alkyl 16 Spraying very good silicate Inv. Example 2771 8.5 5.00 2.4 53 alkyl 20 Brushing very good silicate Inv. Example 2772 0.5 0.01 7.5 60 polyester 200 Brushing very good resin Inv. Example 2773 10.5 0.02 3.5 77 alkyl 25 Spraying very good silicate Inv. Example 2774 11.5 0.01 3.9 43 alkali 14 Spraying very good silicate Inv. Example 2775 36.5 0.09 2.5 52 urethane- 112 Spraying very good based resin Inv. Example 2776 1.5 0.01 0.7 66 alkali 24 Spraying very good silicate Inv. Example 2777 8.7 0.04 1.9 72 urethane- 150 Spraying very good based resin (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

TABLE 125 Zn-Alloy Particle Properties Mg Solid-Solution Phase & Zn—Mg MgZn₂, Average Intermetallic Mg₂Zn₁₁, Fracture Mean Value of Compounds on Mg₂Zn₃, Mg Facet &/or Size Aspect Al Si Surface of MgZn, or # of (mass %) Cracks (*1) (μm) Ratio (mass %) (mass %) Particles Mg₇Zn₃ facets Inv. Example 2778 0.03 FC 8.5 1.42 4.5 0 Existence Existence 2 Inv. Example 2779 4.25 FC 2.36 1.33 0 0.1 Existence Existence 7 Inv. Example 2780 0.04 FC 23.5 1.42 0.01 0 Existence No 2 Inv. Example 2781 0.06 FC 101.5 1.38 3.2 0.9 Existence Existence 7 Inv. Example 2782 0.06 FC 55.4 1.38 0 0.5 Existence Existence 2 Inv. Example 2783 0.07 FC 10.5 1.12 0.2 0.1 Existence No 6 Inv. Example 2784 0.01 FC 12.5 1.23 1.2 0.6 Existence Existence 6 Inv. Example 2785 0.08 FC 18.5 1.36 0.5 0 Existence No 7 Inv. Example 2786 0.09 FC 11.5 1.11 1.5 0.9 Existence Existence 6 Inv. Example 2787 0.05 FC 9.6 1.07 0.5 0 Existence No 2 Inv. Example 2788 0.06 FC 10.05 1.14 1.5 0.9 Existence Existence 2 Inv. Example 2789 29.9 FC 10.5 1.36 0 0 Existence Existence 2 Inv. Example 2790 16.5 FC 7.5 1.11 0.01 0 Existence Existence 7 Inv. Example 2791 12.5 FC 2.6 1.07 3.2 0.9 Existence No 2 Inv. Example 2792 9.8 FC 3.5 1.42 0 0.5 Existence Existence 6 Inv. Example 2793 9.6 FC 4.5 1.33 0.2 0.1 Existence No 6 Inv. Example 2794 7.5 FC 1.6 1.42 0 0.5 Existence Existence 2 Inv. Example 2795 4.6 FC 2.5 1.12 5.8 0.1 Existence Existence 7 Inv. Example 2796 3.8 FC 23.5 1.23 1.2 0.6 Existence Existence 6 Inv. Example 2797 0.05 FC 9.8 1.27 15.5 0 Existence Existence 6 Coat Properties Mean Size Blend Ratio Mg Contents Ratio of of Zn (Zn Alloy to Total Metal Metallic particle:Zn Metal Particle in particle Metal Particle Dry Coat Coat Thickness Coating Result of (μm) Particle) (mass %) (mass %) Base Resin (μm) Method Corrosion Test Inv. Example 2778 7.8 0.01 4.5 40 alkali 18 Spraying very good silicate Inv. Example 2779 5.96 14.17 0.3 44 alkyl 18 Spraying very good silicate Inv. Example 2780 0.06 0.50 0.08 44 alkali 38 Spraying very good silicate Inv. Example 2781 0.9 1.20 0.05 36 alkyl 18 Spraying very good silicate Inv. Example 2782 3.6 12.00 0.005 76 alkyl 10 Spraying very good silicate Inv. Example 2783 10.5 0.03 2.8 77 alkyl 37 Spraying very good silicate Inv. Example 2784 0.05 0.02 0.6 43 alkali 2 Spraying good silicate Inv. Example 2785 2.32 0.08 1 52 alkyl 160 Brushing very good silicate Inv. Example 2786 20.4 1.00 0.09 66 alkali 5 Brushing very good silicate Inv. Example 2787 7.34 0.01 3.4 72 alkyl 56 Brushing very good silicate Inv. Example 2788 9.4 0.04 1.5 53 urethane- 99 Spraying very good based resin Inv. Example 2789 16.5 0.15 200 55 urethane- 700 Spraying very good based resin Inv. Example 2790 7.9 1.10 15 47 alkyl 554 Spraying very good silicate Inv. Example 2791 10.5 2.50 5 79 urethane- 688 Brushing very good based resin Inv. Example 2792 16.5 6.53 1.5 42 urethane- 421 Spraying very good based resin Inv. Example 2793 8.5 0.12 78 36 urethane- 651 Spraying very good based resin Inv. Example 2794 10.5 1.50 5 53 urethane- 402 Brushing very good based resin Inv. Example 2795 5.8 0.44 10.5 55 alkali 354 Spraying very good silicate Inv. Example 2796 1.2 1.52 2.5 42 urethane- 504 Brushing very good based resin Inv. Example 2797 15.5 0.05 1 76 urethane- 666 Spraying very good based resin (*1) F: Fracture facets existing, FC: Fracture facets and/or cracks existing, NO: No fracture facet and/or crack

Example 9

Table 126 shows a method of production of Zn alloy particles. The primary particles were prepared by the gas atomization method. Furthermore, in accordance with the present invention, Zn alloy particles were made to impact each other or Zn alloy particles were made to impact a solid to prepare secondary particles. Further, Zn alloy particles were added to toluene or xylene with a moisture content of 0.3% or less to make slurry and the method of making the particles impact each other or impact a solid was used to prepare secondary particles.

The methods of measurement of the average particle size of the Zn alloy particles and the average value of the aspect ratio are the same as in Example 1. Further, the methods of identification of the Mg solid solution phase and Zn—Mg intermetallic compounds are the same as in Example 3. The method of identification of MgZn₂, Mg₂Zn₁₁, Mg₂Zn₃, MgZn, and Mg₇Zn₃ and the method of measurement of the number of facets are the same as in Example 4.

From Table 126, it is learned that Zn alloy particles of the range of the present invention are prepared.

TABLE 126 Diameter of Primary Particle Mg Al Si (μm) (mass %) (mass %) (mass %) Fructure Method Slurry & Solvent Inv. Method 1 125 0.1 0.05 0.03 Impact each other No of alloy particles Inv. Method 2 3 12.3 0.1 0.07 Impact each other Exisitence of alloy particles (Solvent:toluene) Inv. Method 3 340 19.3 0.05 0.05 Impact with solid Exisitence (Solvent:xylene) Inv. Method 4 60 2.7 0.05 0.05 Impact No Inv. Method 5 1000 16.7 4.32 0.03 Impact Exisitence (Solvent:toluene) Inv. Method 6 30 3.5 5.43 0.65 Impact with solid Exisitence (Solvent:xylene) Inv. Method 7 80 7.5 0.05 0.05 Impact with solid No Inv. Method 8 230 21.5 11.05 0.23 Impact Exisitence (Solvent:toluene) Inv. Method 9 500 2.3 0.03 2.4 Impact Exisitence (Solvent:xylene) Inv. Method 1 125 0.1 0.05 0.03 Impact each other No of alloy particles Inv. Method 2 3 12.3 0.1 0.07 Impact each other Exisitence of alloy particles (Solvent:toluene) Inv. Method 3 340 19.3 0.05 0.05 Impact with solid Exisitence (Solvent:xylene) Inv. Method 4 60 2.7 0.05 0.05 Impact No Inv. Method 5 1000 16.7 4.32 0.03 Impact Exisitence (Solvent:toluene) Inv. Method 6 30 3.5 5.43 0.65 Impact with solid Exisitence (Solvent:xylene) Inv. Method 7 80 7.5 0.05 0.05 Impact with-solid No Inv. Method 8 230 21.5 11.05 0.23 Impact Exisitence (Solvent:toluene) Inv. Method 9 500 2.3 0.03 2.4 Impact Exisitence (Solvent:xylene) Comp. Method 1 300 0.6 0.02 0.03 Ball mill No Comp. Method 2 70 4.5 11.05 0.25 Ball mill Exisitence (Solvent:toluene) Comp. Method 3 500 12.5 0.03 2.45 Ball mill Exisitence (Solvent:xylene) Comp. Method 4 60 2.7 0.05 0.05 Ball mill No Comp. Method 5 800 16.7 4.32 0.03 Ball mill Exisitence (Solvent:toluene) Comp. Method 6 30 3.5 5.43 0.65 Beads mill Exisitence (Solvent:xylene) Comp. Method 7 80 7.5 0.05 0.05 Beads mill No Comp. Method 8 230 21.5 11.05 0.23 Beads mill Exisitence (Solvent:toluene) Comp. Method 9 500 2.3 0.03 2.4 Beads mill Exisitence (Solvent:xylene) Mean Value of Mg Solid-Solution Mean Diameter of Aspect Ratio Phase & Zn—Mg After-Treated (Max. D/Min. D) Intermetallic Min. # Alloy Particle of After-treated Compounds on Surface MgZn₂ or of (μm) Alloy Particle of Particles Mg₂Zn₁₁ facets Inv. Method 1 10.81 1.50 No No 4 Inv. Method 2 0.02 1.05 Exisitence Exisitence 4 Inv. Method 3 33.57 1.04 Exisitence Exisitence 6 Inv. Method 4 4.12 1.21 Exisitence Exisitence 6 Inv. Method 5 194.23 1.27 Exisitence Exisitence 6 Inv. Method 6 3.04 1.02 Exisitence Exisitence 6 Inv. Method 7 5.07 1.42 Exisitence Exisitence 6 Inv. Method 8 19.54 1.06 Exisitence Exisitence 6 Inv. Method 9 147.23 1.35 Exisitence Exisitence 6 Inv. Method 1 10.81 1.50 No No 4 Inv. Method 2 0.02 1.05 Exisitence Exisitence 4 Inv. Method 3 33.57 1.04 Exisitence Exisitence 6 Inv. Method 4 4.12 1.21 Exisitence Exisitence 6 Inv. Method 5 194.23 1.27 Exisitence Exisitence 6 Inv. Method 6 3.04 1.02 Exisitence Exisitence 6 Inv. Method 7 5.07 1.42 Exisitence Exisitence 6 Inv. Method 8 19.54 1.06 Exisitence Exisitence 6 Inv. Method 9 147.23 1.35 Exisitence Exisitence 6 Comp. Method 1 35.45 4.3 Exisitence Exisitence 6 Comp. Method 2 6.54 5.6 Exisitence Exisitence 6 Comp. Method 3 194.35 2.7 No No 6 Comp. Method 4 15.78 5.7 Exisitence Exisitence 6 Comp. Method 5 187.54 2.3 No No 6 Comp. Method 6 7.45 6.2 Exisitence Exisitence 6 Comp. Method 7 6.87 6.3 Exisitence Exisitence 6 Comp. Method 8 28.74 4.1 Exisitence No 6 Comp. Method 9 168.74 2.1 No No 6

INDUSTRIAL APPLICABILITY

If coating the high corrosion resistance rust prevention paint containing Zn alloy particles having physical fracture facets and/or cracks of the present invention, it is possible to impart to a ferrous metal material etc. an unprecedented long-lasting, superior corrosion resistance and rust prevention without impairing the coatability and economy. Further, as a result, it is possible to provide a high corrosion resistance ferrous metal material and steel structure enabling the maintenance cycles to be greatly extended.

According, the present invention has high applicability in the ferrous metal industry. 

1. Zn alloy particles for high corrosion resistance rust prevention paint containing, by mass %, Mg: 0.01 to 30% and having a balance of Zn and unavoidable impurities, having physical fracture facets and/or cracks of a length of 0.01 μm or more or cracks of a depth of 0.01 μm or more, having an average particle size of 0.05 to 200 μm, and having an aspect ratio of maximum size and minimum size (maximum size/minimum size) of an average value of 1 to 1.5.
 2. Zn alloy particles for high corrosion resistance rust prevention paint as set forth in claim 1, characterized in that said Zn alloy particles further contain, by mass %, one or both of Al: 0.01 to 30% and Si: 0.01 to 3%
 3. Zn alloy particles for high corrosion resistance rust prevention paint as set forth in 1, characterized by having an Mg solid solution phase and Zn—Mg intermetallic compounds on the surface of said Zn alloy particles.
 4. Zn alloy particles for high corrosion resistance rust prevention paint as set forth in claim 3, characterized in that said Zn—Mg intermetallic compounds include at least one type of compound of MgZn₂, Mg₂Zn₁₁, Mg₂Zn₃, MgZn, and Mg₇Zn₃.
 5. Zn alloy particles for high corrosion resistance rust prevention paint as set forth in claim 1, characterized in that said Zn alloy particles are shaped as aspherical polyhedrons with two or more facets.
 6. A method of production of Zn alloy particles for high corrosion resistance rust prevention paint as set forth in claim 1, said method of production of Zn alloy particles for high corrosion resistance rust prevention paint characterized by making primary particles comprised of the composition of ingredients as described in claim 1 and having an average particle size of 0.05 to 1000 μm impact each other or making said primary particles impact a solid to fracture said primary particles to produce Zn alloy particles having physical fracture facets and/or cracks.
 7. A method of production of Zn alloy particles for high corrosion resistance rust prevention paint as set forth in claim 6 characterized by making said primary particles disperse in an organic solvent to make a slurry, then making the slurry impact itself or making said slurry impact a solid to fracture the primary particles.
 8. A high corrosion resistance rust prevention paint characterized by containing Zn alloy particles for high corrosion resistance rust protection paint as set forth in claim 1 in 30 mass % or more converted to dry coat.
 9. A high corrosion resistance rust prevention paint as set forth in claim 8 characterized by comprising a high corrosion resistance rust prevention paint containing, in addition to said Zn alloy particles, Zn metal particles having an average particle size of 0.05 to 50 μm comprised of Zn and unavoidable impurities and by having an x of 300.0 or less when defining, by mass %, (mass % of said Zn alloy particles):(mass % of said Zn metal particles) as 1/x.
 10. A high corrosion resistance rust prevention paint as set forth in claim 8 characterized by having, by mass %, a content of Mg of 0.01 to less than 30% when the total of said Zn alloy particles and said Zn metal particles is defined as 100%.
 11. A high corrosion resistance rust prevention paint as set forth in claim 8 characterized in that a binder of said high corrosion resistance rust protection paint is an inorganic binder or organic binder.
 12. A ferrous metal material coated with a high corrosion resistance rust prevention paint as set forth in claim 8 on its surface, said high corrosion resistance ferrous metal material characterized in that a coating thickness is 2 to 700 μm and in that Zn alloy particles, or Zn alloy particles and Zn metal particles, are dispersed in the coat.
 13. A steel structure characterized by being provided with a high corrosion resistance ferrous metal material as set forth in claim 12 as part or all of the same. 